Orange Oil Manufacturers, SDS MSDS Sheet

Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Orange Oil: CAS Number: 8008-57-9, EINECS EC Number: 232-433-8, Molecular Formula: yyyyy, Molecular Weight: yyyyy, FEMA Number: 2825, HS Code ---**

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Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail prices, Uses etc available on these pages for Contract Manufacturing for Orange Oil:.

Orange oil is an essential oil produced by cells within the rind of an orange fruit (Citrus sinensis fruit). In contrast to most essential oils, it is extracted as a by-product of orange juice production by centrifugation, producing a cold-pressed oil. This oil is widely used in aromatherapy for complete relaxation. It is rich in essential nutrients and hence, it is used in ingredient for creams, lotions and conditioners.

General Properties and Specifications of Orange oil:
Appearance: Yellow-orange clear liquid.
Odor: Citric, fresh, juicy, sweet.
Extraction Method: Cold Pressed.
Relative density: around 0.84
Refractive index @ 20C: 1.470 - 1.475

DEFINITION
Orange Oil is the volatile oil obtained by expression from the fresh peel of the ripe fruit of Citrus sinensis (L.) Osbeck (Fam. Rutaceae). The total aldehyde content, calculated as decanal (C10H20O), is NLT 1.2% and NMT 2.5%. It may contain a suitable antioxidant.
[Note— Do not use Orange Oil that has a terebinthine odor. ]

ASSAY
Total Aldehyde Content: To pass the test.
Acceptance criteria: 1.2%–2.5%

Specific Gravity: 0.842–0.846
Optical Rotation, Angular Rotation: +94° to +99°
Refractive Index: 1.472–1.474 at 20C
Ultraviolet Absorbance: To pass the test.
Foreign Oils: To pass the test.
Packaging and Storage: Preserve in well-filled, tight containers, and avoid exposure to excessive heat.

DEFINITION
Orange Oil is obtained by mechanical means from the fresh peel of the sweet orange, Citrus sinensis (L.) Osbeck.

CHARACTERISTICS
A yellow to yellowish brown liquid, visibly free from water; odour, that of orange.

TESTS
Optical rotation: +94° to +99°. On distillation, the first 10% of the distillate has an optical rotation the same as, or only slightly lower than, the original oil.
Refractive index: 1.472 to 1.476,
Residue on evaporation: 1.0 to 5.0% when determined by the method for residue on evaporation of volatile oils, Use 2 g and heat for 4 hours.
Solubility in ethanol: Soluble at 20C, in 7 parts of ethanol (90%) A bright solution is rarely obtained due to the presence of waxy non-volatile substances.
Weight per mL: 0.842 to 0.848
Content of aldehydes: Not less than 1.0% w/w, calculated as decanal, C10H20O.
STORAGE
Orange Oil should be kept in a well-filled container and protected from light.

DEFINITION
Essential oil obtained without heating, by suitable mechanical treatment from the fresh peel of the fruit of Citrus sinensis (L.) Osbeck (Citrus aurantium L. var. dulcis L.). A suitable antioxidant may be added.

CHARACTERS
Appearance: Clear, pale yellow or orange, mobile liquid, which may become cloudy when chilled.
Characteristic odour of fresh orange peel.

IDENTIFICATION
First identification: B
Second identification: A
A. Thin-layer chromatography. To pass the test.
B. Examine the chromatograms obtained in the test for chromatographic profile. To pass the test.

TESTS
Relative density: 0.842 to 0.850.
Refractive index: 1.470 to 1.476.
Optical rotation: + 94° to + 99°.
Peroxide value: Maximum 20
Fatty oils and resinified essential oils: To pass the test.
Bergapten: To pass the test. By Thin-layer chromatography.
Chromatographic profile:
To pass the test. The limits are within the following ranges:
— α-pinene: 0.4 per cent to 0.6 per cent,
— β-pinene: 0.02 per cent to 0.3 per cent,
— sabinene: 0.2 per cent to 1.1 per cent,
— β-myrcene: 1.7 per cent to 2.5 per cent,
— limonene: 92.0 per cent to 97.0 per cent,
— octanal: 0.1 per cent to 0.4 per cent,
— decanal: 0.1 per cent to 0.4 per cent,
— linalol: 0.2 per cent to 0.7 per cent,
— neral: 0.02 per cent to 0.10 per cent,
— valencene: 0.02 per cent to 0.5 per cent,
— geranial: 0.03 per cent to 0.20 per cent.
Residue on evaporation: 1.0 per cent to 5.0 per cent.
Evaporate 5.0 g to dryness on a water-bath and dry at 100-105 °C for 4 h.

DESCRIPTION
Orange Oil, Bitter, Cold-pressed, occurs as a pale yellow or yellow-brown liquid with the characteristic aromatic odor of the Seville orange and an aromatic, somewhat bitter taste. It is the volatile oil obtained by expression, without the use of heat, from the fresh peel of the fruit of Citrus aurantium L. (Fam. Rutaceae). It is miscible with absolute alcohol and with an equal volume of glacial acetic acid. It is soluble in fixed oils and in mineral oil. It is slightly soluble in propylene glycol, but it is relatively insoluble in glycerin. It is affected by light, and its alcohol solutions are neutral to litmus. It may contain a suitable antioxidant.
Function: Flavoring agent.

For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30

USA, Canada, Mexico and other American
neighbouring buyers may
e-mail: us@mubychem.com
Call toll-free 1-877-682-9243 (1-877-MUBYCHEM)

Exporters to USA Canada UAE Europe South Africa Tanzania Kenya Uganda Egypt Nigeria Turkey Mexico Brazil Argentina Chile Dubai etc.

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Product Name & Other Names: Orange Oil.
CAS Number: 8008-57-9
EINECS EC Number: 232-433-8
FEMA Number: 2825
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Hazard statements (GHS-USA):
H226: Flammable liquid and vapor.
H315: Causes skin irritation.

Precautionary statements (GHS-USA):
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P264: Wash … thoroughly after handling.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P363: Wash contaminated clothing before reuse.
P302+352: IF ON SKIN: Wash with soap and water.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.
P370+378: In case of fire: Use CO2, foam, dry chemicals for extinction.
P403+235: Store in a well-ventilated place. Keep cool.
P501: Dispose of contents/container to authorized agents only.

Classification according to directive 67/548/EEC or Directive 1999/45/EC:
Hazard Symbols:
F Flammable
Xi Irritant
Risk Phrases:
R10 Flammable
R38 Irritating to skin.

Product Name & Other Names: Orange Oil.
CAS Number: 8008-57-9
EINECS EC Number: 232-433-8

Eye contact: Rinse immediately with plenty of water for 10 minutes at least. Contact a physician if symptoms persist.
Skin contact: Wash thoroughly with soap and water; flush with plenty of water. Take off spoilt clothes. Contact physician if symptoms persist.
Ingestion: Wash the mouth with water; seek medical advice immediately.
Inhalation: Remove from exposure site to fresh air and keep at rest. Obtain medical advice.

Extinguishing media recommended: CO2, foam, dry chemicals.
Non-recommended: Do not use direct water jet on burning material.
Extinguishing procedures: Closed containers may build up pressure at elevated temperatures. If possible, containers should be cooled with a water spray. For large fires, apply water from as far as possible. Use large quantities of water applied as a mist or spray.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Personal precautions, protective equipment, and emergency procedures: Ventilate area of leak or spill. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Clean-up procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g., sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container. Avoid open flames or other sources of ignition.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, acids, and alkalis. Keep air contact to a minimum. Keep away from ignition sources and naked flame.

Exposure limit values: Contains no substances with occupational exposure limit values.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): If the exposure limit is exceeded and engineering controls are not feasible, a full face piece particulate respirator (NIOSH type N100 filters) may be worn for up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. If oil particles (e.g., lubricants, cutting fluids. glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron, or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Yellow-orange clear liquid.
Odor: Citric, fresh, juicy, sweet.
Odor threshold: Not available.
pH: Not available.
Relative density: around 0.84
Melting point/freezing point: Not available.
Initial boiling point and boiling range: Not available.
Flash point: 54C literature.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility(ies): Insoluble in water. Soluble at 20C, in 7 parts of ethanol (90%).
Viscosity: Not available.

Reactivity: It presents no significant reactivity hazards, by itself or in contact with water. Avoid contact with strong acids, alkali, or oxidizing agents.
Decomposition: Carbon monoxide and unidentified organic compounds may be formed during combustion.
Hazardous Polymerization: Will not occur.
Conditions to avoid: Heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials.

LD 50 ORAL/RAT (mg/Kg): >5000 mg/kg
LD 50 DERMAL/RABBIT (mg/Kg) >5000 mg/kg.
Carcinogenic Effects: Not a reported carcinogen by IARC, NTP, ACGIH, OSHA.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

Toxicity to Animals: Not available.
Persistence and Degradability: No information available.
Mobility: No information available.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

In accordance with local environmental laws. Avoid disposing into drainage systems.

DOT USA, TDG Canada & ADR/RID Europe:
UN Number: 1993
Proper shipping name: Flammable liquids, n.o.s. (Orange oil)
Class: 3
Packing Group: III
IMDG/IMO:
UN Number: 1993
Proper shipping name: Flammable liquids, n.o.s. (Orange oil)
Class: 3
Packing Group: III
IATA/ICAO:
UN Number: 1993
Proper shipping name: Flammable liquids, n.o.s. (Orange oil)
Class: 3
Packing Group: III.

SARA 311/312 Hazards: Fire Hazard, Acute Health Hazard. See section 2.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

European Labeling in Accordance with EC Directives:
H226 Flammable liquid and vapor.
H315 Causes skin irritation.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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