Methyl Salicylate BP Wintergreen Oil USP NF IP JP BP Ph Eur EP FCC Food Grade Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Methyl Salicylate or Wintergreen Oil USP NF IP BP Ph Eur EP JP FCC Food Grade Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Methyl salicylate or Wintergreen oil: CAS Number: 119-36-8, EINECS EC Number: 204-317-7, FEMA Number: 2745, Molecular Formula: C8H8O3, Molecular Weight: 152.15, HS Code ---**

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Methyl salicylate or Wintergreen oil.

Methyl salicylate, oil of wintergreen or wintergreen oil is an ester naturally produced by many species of plants, particularly wintergreens. It is also synthetically produced, used as a fragrance, in foods and beverages, and in liniments. This compound is probably produced as an anti-herbivore defense. If the plant is infected with herbivorous insects, the release of methyl salicylate may function as an aid in the recruitment of beneficial insects to kill the herbivorous insects.
Uses: Analgesic and antiseptic, flavoring agent in chewing gum and mints, fragrance, bait for attracting male orchid bees, to lower the freezing point of glacial acetic acid for transport etc.

Methyl Salicylate BP Grade Specifications
Ph Eur
C8H8O3 -- 152.1 -- 119-36-860-7
Action and use: Counter-irritant.

DEFINITION
Methyl 2-hydroxybenzoate.
Content: 99.0 per cent m/m to 100.5 per cent m/m.

CHARACTERS
Appearance: Colourless or slightly yellow liquid.
Solubility: Very slightly soluble in water, miscible with ethanol (96 per cent) and with fatty and essential oils.

IDENTIFICATION
A. Heat 0.25 ml with 2 ml of dilute sodium hydroxide solution on a water-bath for 5 min. Add 3 ml of dilute sulphuric acid. A crystalline precipitate is formed. Filter. The precipitate washed with water and dried at 100C-105C, melts at 156C to 161C.
B. To 10 ml of a saturated solution add 0.05 ml of ferric chloride solution. A violet colour develops.

TESTS
Appearance of solution: The solution is clear and not more intensely coloured than reference solution.
To 2 ml add 10 ml of ethanol (96 per cent).
Acidity: Dissolve 5.0 g in a mixture of 0.2 ml of bromocresol green solution and 50 ml of ethanol (96 per cent) previously neutralised to a blue colour by addition of 0.1 M sodium hydroxide. Not more than 0.4 ml of 0.1 M sodium hydroxide is required to restore the blue colour.
Relative density: 1.180 to 1.186.
Refractive index: 1.535 to 1.538.

ASSAY
Dissolve 0.500 g in 25 ml of ethanol (96 per cent). Add 0.05 ml of phenol red solution and neutralise with 0.1 M sodium hydroxide. To the neutralised solution add 50.0 ml of 0.1 M sodium hydroxide and heat under a reflux condenser on a water-bath for 30 min. Cool and titrate with 0.1 M hydrochloric acid. Calculate the volume of 0.1 M sodium hydroxide used in the saponification. Carry out a blank titration.
1 ml of 0.1 M sodium hydroxide is equivalent to 15.21 mg of C8H8O3.

Methyl Salicylate USP NF Grade Specifications
C8H8O3 -- 152.15 --- CAS 119-36-8
Benzoic acid, 2-hydroxy-, methyl ester.

Methyl Salicylate is produced synthetically or is obtained by maceration and subsequent distillation with steam from the leaves of Gaultheria procumbens Linné (Fam. Ericaceae) or from the bark of Betula lenta Linné (Fam. Betulaceae). It contains not less than 98.0 percent and not more than 100.5 percent of C8H8O3.

Labeling: Label it to indicate whether it was made synthetically or distilled from either of the plants mentioned above.
Solubility in 70 percent alcohol: One volume of synthetic Methyl Salicylate dissolves in 7 volumes of 70 percent alcohol. One volume of natural Methyl Salicylate dissolves in 7 volumes of 70 percent alcohol, the solution having not more than a slight cloudiness.
Identification: Shake 1 drop with about 5 mL of water, and add 1 drop of ferric chloride: the resulting mixture has a deep violet color.
Specific gravity: between 1.180 and 1.185 for the synthetic variety; between 1.176 and 1.182 for the natural variety.
Angular rotation: Synthetic Methyl Salicylate and that from betula are optically inactive. Methyl Salicylate from gaultheria is slightly levorotatory, the angular rotation not exceeding 1.5 degree in a 100-mm tube.
Refractive index: between 1.535 and 1.538 at 20 .
Heavy metals: 20 microgm per g.
Assay: Place about 2 g of Methyl Salicylate, accurately weighed, in a flask, add 40.0 mL of 1 N sodium hydroxide and boil gently under a reflux condenser for 2 hours. Cool, rinse the condenser and the sides of the flask with a few mL of water, add PhPh and titrate the excess alkali with 1 N sulfuric acid. Perform a blank. Each mL of 1 N sodium hydroxide corresponds to 152.2 mg of C8H8O3.

Wintergreen Oil FCC Food and Flavoring Grade Specifications
Gaultheria Oil
CAS: [68917-75-9]

DESCRIPTION
Wintergreen Oil occurs as a colorless to yellow liquid withthe characteristic odor and taste of wintergreen. It is obtained by maceration and subsequent distillation with steam from the leaves of Gualtheria procumbens L. (Fam. Ericaceae) or from the bark of Betula lenta L. (Fam. Betulaceae). It boils, with decomposition, between 219C and 224C. It is soluble in alcohol and in glacial acetic acid, and it is very slightly soluble in water.
Function: Flavoring agent.

REQUIREMENTS
Identification:-
A. Shake 1 drop of sample with about 5 mL of water, and add 1 drop of ferric chloride. A deep violet color appears.
B. The infrared absorption spectrum of the sample exhibits relative maxima at the same wavelengths as those of a typical spectrum as shown in the section on Infrared Spectra, using the same test conditions as specified therein.
Assay: Not less than 98.0% and not more than 100.5% of methyl salicylate (C8H8O3).
Acid Value: Not more than 1.0.
Angular Rotation: Slightly levorotatory, exhibiting a rotation of not more than −1.5°.
Refractive Index: Between 1.535 and 1.538 at 20°.
Solubility in Alcohol: Passes test.
Specific Gravity: Between 1.176 and 1.182.

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Methyl Salicylate SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 06-Nov-20

Product Name & Other Names: Methyl Salicylate or 2-Hydroxybenzoic acid Methyl ester or Methyl 2-hydroxybenzoate or Oil of wintergreen or Methoxybenzoic Acid.
CAS No.: 119-36-8
EINECS EC Number: 204-317-7
Molecular Weight: 152.15
Chemical Formula: 2-(HO)C6H4CO2CH3
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, oral Category 4, H302
Serious eye damage/eye irritation Category 2A, H319

Hazard statements:
H302: Harmful if swallowed.
H319: Causes serious eye irritation.

Precautionary statements:
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P330: Rinse mouth.
P301+312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.
P501: Dispose of contents/container in accordance with local/regional/national/international regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xn Harmful
Xi Irritant
Risk Phrases:
R22 Harmful if swallowed.
R36 Irritating to eyes.

Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Flammability of the Product: Combustible at high temperature. Vapors can travel to a source of ignition and flash back.
Auto-Ignition Temperature: 454C.
Flash Points: 96C Closed Cup.
Flammable Limits: Not available.
Products of Combustion: Fumes, Carbon dioxide & Carbon Monoxide.
Fire: Methyl Salicylate is flammable on heating.
Explosion: Explosive on heating.
Fire Extinguishing Media: Use means suitable for extinguishing surrounding fire. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes. On decomposition it may emit carbon monoxide. Containers may explode on heating.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Absorb with an inert material and put the spilled material in an appropriate waste disposal.
Large Spill: Avoid touching the spilled material. Do not let the product enter drains. Avoid breathing vapors, mist, or gas. Ensure adequate ventilation. Contain spilled material. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow evacuating as per law.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, acids, and bases. Keep away from heat, sun light.

Airborne Exposure Limits: Not Specified.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Colorless to yellowish red liquid.
Odor: Strong typical wintergreen.
Odor threshold: Not available.
pH: Not available.
Relative density: Not available.
Boiling Point: 223C.
Melting Point: -8.6C.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: It is slightly soluble in water.
Viscosity: Not available.
Molecular Weight: 152.15
Molecular Formula: 2-(HO)C6H4CO2CH3

Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits carbon monoxide & fumes when heated to decomposition. It may form harmful gases.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, acids, strong bases.
Conditions to Avoid: Incompatible materials, light, dust generation, excess heat, exposure to moist air or water.

Toxicity data
ORAL-RAT LD50 887 mg kg-1
ORAL-Mouse LD50 1110 mg kg-1
Dermal-Rabbit LD50 > 5.000 mg/kg.
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Teratogenic Effects: Not available.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

Toxicity to fish: static test LC50 - Danio rerio (zebra fish) - > 100 mg/l - 96 h
Toxicity to algae: static test EC50 - Desmodesmus subspicatus (green algae) - 27 mg/l - 72 h
Environmental Fate: This substance is expected to have a high biological oxygen demand. It is readily biodegradable and has low bioconcentration potential.
BOD5 and COD: This substance is expected to have a high biological oxygen demand.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with law.

DOT USA, TDG Canada & ADR/RID Europe: Not regulated.
IMDG/IMO & IATA: Not regulated.

USA:
OSHA Hazards: Not classed as Highly Hazardous as per OSHA
SARA 302 Components: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components: No chemicals in this material are subject to the reporting requirements
SARA 311/312 Hazards: Acute Health Hazard
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

European Labeling in Accordance with EC Directives:
H302 = Harmful if swallowed.
H319 = Causes serious eye irritation.

DISCLAIMER: The information and recommendations set forth herein are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

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