Iodine crystals and prills USP BP Ph Eur Analytical Reagent Grade Manufacturers, with SDS GHS MSDS Sheet
Supplier, Manufacturer, Exporter of Iodine, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.
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Iodine crystals and prills: CAS Number: 7553-56-2, EINECS EC Number: 231-442-4, Molecular Formula: I2, Molecular Weight: 253.81, HS Code ---**
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SDS MSDS Sheet of Iodine crystals and prills ManufacturersIodine
Crystals and Prills Pure Suppliers
Properties and General Specifications of Iodine crystals and prills:
Appearance: Purple-black lustrous solid.
Assay: 99.8% minimum.
Non-volatile residue: 0.05% maximum.
Chloride and Bromide (as chloride): 0.028% maximum.
pH: 5.4 in saturated water solution.
Melting point: 113C literature.
Boiling point: 184 C literature.
Relative density: 4.9
Specifications of Iodine USP Grade:
Identification:
I2 --- 253.81 --- 7553-56-2.
Iodine contains not less than 99.8 percent and not more than 100.5 percent of I.
Packaging and storage: Preserve in tight containers.
A: Solutions (1 in 1000) in chloroform and in carbon disulfide have a violet color.
B: To a saturated solution add starch-potassium iodide: a blue color is produced. When the mixture is boiled, the color vanishes but reappears as the mixture cools, unless it has been subjected to prolonged boiling.
Limit of nonvolatile residue: Place 5.0 g in a tared porcelain dish, heat on a steam bath until the iodine has been driven off, and dry at 105 for 1 hour: not more than 0.05% of residue remains.
Chloride or bromide: Triturate 250 mg of finely powdered Iodine with 10 mL of water, and filter the solution. Add, dropwise, sulfurous acid (free from chloride), previously diluted with several volumes of water, until the iodine color just disappears. Add 5 mL of 6 N ammonium hydroxide, followed by 5 mL of silver nitrate in small portions. Filter, and acidify the filtrate with nitric acid: the resulting liquid is not more turbid than a control made with the same quantities of the same reagents to which 0.10 mL of 0.020 N hydrochloric acid has been added, the sulfurous acid being omitted (0.028% as chloride).
Assay: Place about 500 mg of powdered Iodine in a tared, glass-stoppered flask, insert the stopper, weigh accurately, and add 1 g of potassium iodide dissolved in 5 mL of water. Dilute with water to about 50 mL, add 1 mL of 3 N hydrochloric acid, and titrate with 0.1 N sodium thiosulfate, adding 3 mL of starch as the endpoint is approached. Each mL of 0.1 N sodium thiosulfate is equivalent to 12.69 mg of I.
Specifications of Iodine BP, Ph Eur Grade:
I2 --- 253.8 --- 7553-56-2
Action and use: Antiseptic; antithyroid.DEFINITION
Content: 99.5 per cent to 100.5 per cent of I.CHARACTERS
Appearance: Greyish-violet, brittle plates or fine crystals with a metallic sheen.
Solubility: Very slightly soluble in water, very soluble in concentrated solutions of iodides, soluble in ethanol (96 per cent), slightly soluble in glycerol. It volatilises slowly at room temperature.IDENTIFICATION
A Heat a few fragments in a test-tube. Violet vapour is evolved and a bluish-black crystalline sublimate is formed.
B To a saturated solution add starch solution. A blue colour is produced. Heat until decolourised. On cooling, the colour reappears.TESTS
ASSAY
Solution S: Triturate 3.0 g with 20 mL of water, filter, wash the filter with water and dilute the filtrate to 30 mL with the same solvent. To the solution add 1 g of zinc powder. When the solution is decolourised, filter, wash the filter with water and dilute to 40 mL with the same solvent.
Bromides and chlorides: Maximum 250 ppm.
Non-volatile substances: Maximum 0.1 per cent.
Introduce 0.200 g into a flask containing 1 g of potassium iodide and 2 mL of water and add 1 mL of dilute acetic acid. When dissolution is complete, add 50 mL of water and titrate with 0.1 M sodium thiosulfate, using starch solution as indicator.
1 mL of 0.1 M sodium thiosulfate is equivalent to 12.69 mg of I.
Specifications of Iodine Analytical Reagent Grade:
I2 --- Formula Weight 253.81
CAS Number 7553-56-2REQUIREMENTS
Assay: 99.8%MAXIMUM ALLOWABLE
Nonvolatile matter: 0.01%
Chlorine and bromine (as Cl): 0.005%For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.
We manufacture and supply iodine chemicals or derivatives a under:
Iodoquinol or Diiodohydroxyquinoline
5-Iodoanthranilic acid or 2-Amino-5-Iodobenzoic acid
Methyltriphenylphosphonium Iodide
Manufacturers:
MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
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Last 28 April, 2024
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Iodine SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 23-Oct-201. Product Identification
Product Name & Other Names: Iodine
CAS No.: 7553-56-2
EINECS EC Number: 231-442-4
Molecular Formula: I2
Molecular Weight: 253.81
Relevant uses and uses advised against (if any): Laboratory and Industrial Use.
Supplier: As per letterhead.2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, dermal Category 4 - H312
Acute toxicity, inhalation Category 4 - H332
Skin corrosion/irritation Category 2 - H315
Serious eye damage/eye irritation Category 2A - H319
Specific target organ toxicity - single exposure Category 3, Respiratory system - H335
Specific target organ toxicity - repeated exposure, Oral Category 1, Thyroid - H372
Acute aquatic toxicity Category 1 - H400
Labeling according GHS USA & Regulation (EC) No 1272/2008
GHS Label Elements
IrritantGHS Label Elements
Aquatic ToxicityGHS Label Elements
Health HazardSignal Words: Danger
Hazard Statements:
H312 + H332: Harmful in contact with skin or if inhaled
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H372: Causes damage to organs (Thyroid) through prolonged or repeated exposure if swallowed.
H400: Very toxic to aquatic life.Precautionary Statements:
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash contaminated parts thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P301+P310: IF SWALLOWED: Immediately call a POSION CENTER or doctor/physician.
P302+352: IF ON SKIN: Wash with plenty of soap and water.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P333+313: If skin irritation or a rash occurs: Get medical advice/attention.
P403+233+235: Store in a well-ventilated place. Keep container tightly closed. Keep cool.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/national regulation.Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
Xn Harmful
Xi Irritant
N Dangerous for the environment.
Risk Phrases:
R20/22 Harmful by inhalation and if swallowed
R36/37/38 Irritating to eyes, respiratory system and skin
R48 Danger of serious damage to health by prolonged exposure
R51 Toxic to aquatic organisms.3. Composition/Information on Ingredients
Product Name & Other Names: Iodine
CAS No.: 7553-56-2
EINECS EC Number: 231-442-44. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do not use mouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Get medical attention.
Ingestion: Rinse mouth. Do not induce vomiting without medical advice. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Never give anything by mouth to a victim who is unconscious or is having convulsions. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Use a mild soap if available. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. For minor skin contact, avoid spreading material on unaffected skin.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.5. Fire Fighting Measures
Fire Extinguishing Media: Water fog. Alcohol foam. Dry chemical. Polymer foam. Dry chemical powder. Carbon dioxide (CO2). Do not use a solid water stream as it may scatter and spread fire. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes.
Special Information: Fire may produce irritating, corrosive and/or toxic gases. In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.
Products of Combustion: Complex iodine compounds.6. Accidental Release Measures
Personal precautions, protective equipment and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Ensure adequate ventilation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material. Keep out of low areas.
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container.7. Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid contact with skin, eyes and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Avoid prolonged exposure. Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials.8. Exposure Controls/Personal Protection
Airborne Exposure Limits:
USA ACGIH TLV: TWA: 0.01 ppm and STEL: 0.1 ppm
OSHA PEL: Ceiling: 1 mg/m3
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.9. Physical and Chemical Properties
Physical state: Purple-black lustrous solid.
Odor: odorless.
Odor threshold: Not available.
pH: 5.4 in saturated water solution.
Relative density: 4.9
Melting point/freezing point: 113C literature.
Initial boiling point and boiling range: 184 C literature.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Very slightly soluble in water, very soluble in concentrated solutions of iodides, soluble in ethanol (96 per cent), slightly soluble in glycerol.
Viscosity: Not available.
Molecular Formula: I2
Molecular Weight: 253.8110. Stability and Reactivity
Stability: It is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits iodine compounds and toxic fumes when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Oxidizing agents, rubber, plastics, sulfur compounds, magnesium, zinc, aluminum, metals, alkalis, antimony salts, arsenites, bromides, chlorides, iodides, thiocyanates, hypophosphites, morphine salts, oils, creosote, phosphates, tannins, tartrates, etc. A violent reaction occurs between iodine and acetaldehyde., acetylene, acetaldehyde, strong oxidizing agents.
Conditions to Avoid: Avoid heat and contact with incompatible materials.11. Toxicological Information
Toxicity data:
LD50 Oral - Rat – 14000 mg/kg.
Carcinogenicity: Not a carcinogenic as per IARC, NTP, OSHA and ACGIG.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.12. Ecological Information
Toxicity to fish: LC50 - Oncorhynchus mykiss (rainbow trout) - 1,7 mg/l - 96,0 h.
Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna (Water flea) - 0,2 mg/l - 48 h.
Ecotoxicity: Components of this product have been identified as having potential environmental concerns.
Aquatic toxicity: May cause long-term adverse effects in the aquatic environment.
Persistence and degradability: No data available
Mobility in soil: No data available13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.
14. Transport Information
DOT USA, TDG Canada & ADR/RID Europe:
UN number: 3495; Class: 8 (6.1); Packing group: III
Proper shipping name: Iodine.
IMDG & IMO
UN number: 3495; Class: 8 (6.1); Packing group: III
Proper shipping name: Iodine.
IATA
UN number: 3495; Class: 8 (6.1); Packing group: III
Proper shipping name: Iodine.15. Regulatory Information
USA:
SARA 302 Components: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components: Listed.
SARA 311/312 Hazards: Acute Health Hazard, Chronic Health Hazard
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.Section 16 - Additional Information
European Labeling in Accordance with EC Directives:
H312 + H332: Harmful in contact with skin or if inhaled
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H372: Causes damage to organs (Thyroid) through prolonged or repeated exposure if swallowed.
H400: Very toxic to aquatic life.Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
Xn Harmful
Xi Irritant
N Dangerous for the environment.
Risk Phrases:
R20/22 Harmful by inhalation and if swallowed
R36/37/38: Irritating to eyes, respiratory system and skin
R48 Danger of serious damage to health by prolonged exposure
R51: Toxic to aquatic organisms.Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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