Diiodomethane or Methylene Iodide Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Diiodomethane or Methylene Iodide, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Diiodomethane or Methylene Iodide: CAS Number: 75-11-6, EINECS EC Number: 200-841-5, Molecular Formula: CH2I2, Molecular Weight: 267.84, HS Code ---**

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Diiodomethane or Methylene Iodide.

Diiodomethane or methylene iodide, commonly abbreviated "MI", is an organoiodine compound. Diiodomethane is a colorless liquid; however, it decomposes upon exposure to light liberating iodine, which colours samples brownish. It is slightly soluble in water, but soluble in organic solvents. Diiodomethane or Methylene Iodide is used in wide range of medicals industrial applications as well as in human and animal nutrition products such as antiseptics and disinfectants, pharmaceutical intermediates, polarizing films for liquid crystal display [LCD] chemicals. Iodine derivatives are also used as organic building blocks, analytical reagents etc. Diiodomethane or Methylene Iodide appears like colorless liquid, and has boiling point of 181-182C.

Specifications of Diiodomethane or Methylene Iodide:
Appearance & Physical State: Colorless to light yellow liquid with chloroform-like odor.
Relative Density: Between 3.30 and 3.34
Boiling Point: 181C-182C
Melting Point: 6C
Flash Point: 181C
Assay: Minimum 98%
Water Solubility: 14 g/L @ 20C.
Stability: Stable. Incompatible with strong oxidizing agents, strong bases. Reacts violently with alkali metal salts. May discolour on exposure to light.

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Diiodomethane or Methylene Iodide SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 16-Oct-20

Product Name & Other Names: Diiodomethane or Methylene Iodide
CAS No.: 75-11-6
EINECS EC Code: 200-841-5
Molecular Weight: 267.84
Chemical Formula: CH2I2
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Oral (Category 3) H301
Acute toxicity, Dermal (Category 3) H311
Skin corrosion (Category 1B) H315
Eye irritation (Category 2) H319
Acute toxicity, Inhalation (Category 4) H332
Respiratory sensitization (Category 1) H335

Hazard Statements:
H301: Toxic if swallowed
H311: Toxic in contact with skin.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause allergy or asthma symptoms or breathing difficulties if inhaled.

Precautionary Statements
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash ... thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P272: Contaminated work clothing should not be allowed out of the workplace
P280-Wear protective gloves/protective clothing/eye protection/face protection.
P284 Wear respiratory protection.
P301+P310+330: IF SWALLOWED: Rinse mouth and immediately call a POISON CENTER or doctor/physician.
P302+P352: IF ON SKIN: Wash with soap and water.
P303 + P361 + P352 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P304 + P341 + P311 IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P314: Get Medical advice/attention if you feel unwell.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
T = Toxic
Xi = Irritant
Xn Harmful
Risk Phrase:
R20 Harmful by inhalation
R23/24 Toxic by inhalation and in contact with skin
R36/37/38 = Irritating to eyes, respiratory system and skin.

Product Name/Synonyms: Diiodomethane or Methylene Iodide
CAS No.: 75-11-6
EINECS EC Code: 200-841-5

Inhalation: Harmful if inhaled. If inhaled, it will cause irritation and damage. Remove the victim to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Toxic if swallowed. It will cause irritation and burns to mouth, digestive tract and stomach. Contact medical center quickly. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Toxic and irritating on contact with skin. On contact, it can cause itching, pain, swelling and redness. Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: It can cause severe irritation and harm to eyes. Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Get medical attention.

Fire: Flash point: 181C 182C (literature, reported differently by some sources).
Toxic fumes, hydrogen iodide, carbon dioxide and carbon monoxide may be formed in fire.
Explosion: No data available
Fire Extinguishing Media: Dry chemical, foam or carbon dioxide and water spray jet.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage
Small Spills: Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spills: : Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

Toxic Liquids. Keep away from heat and source of fire preferably in a ventilated area.
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, strong bases, oxygen, metals.

Airborne Exposure Limits: Not established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to the substance is apparent and engineering controls are not feasible, consult an industrial hygienist. For emergencies, or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Colorless to light yellow liquid with chloroform-like odor.
Odor: Typical chloroform-like odor.
Odor threshold: Not available.
pH: Not available.
Relative density: Between 3.30 and 3.34
Boiling Point: 181C-182C
Melting Point: 6C.
Flash Point: 182C (literature, reported differently by some sources).
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: 14 g/L @ 20C literature.
Viscosity: Not available.
Molecular Weight: 267.84
Chemical Formula: CH2I2.

Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Toxic fumes, hydrogen iodide, carbon dioxide and carbon monoxide may be formed in fire.
Hazardous Polymerization: Not reported.
Incompatibilities: Strong oxidizing agents, Strong bases, Oxygen, Metals.
Conditions to Avoid: Heat, flames, moisture, light, ignition sources and incompatibles.

Oral rat LD50: 76 mg/kg
Carcinogenicity: Not reported as carcinogen by any agency.
Reproductive Toxicity: No information available.
Developmental Effects: No information available.
Teratogenicity: No information available.

Persistence and Degradability: Persistence is unlikely based on information available.
Bioaccumulation/ Accumulation: No information available.
Mobility: Will likely be mobile in the environment due to its volatility.
Results of PBT and vPvB assessment: No information available.
Environmental Toxicity: No information available.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state, and local requirements.

DOT USA & ADR/RID Europe
UN Number: UN 2810
Proper shipping name: TOXIC LIQUID, ORGANIC, N.O.S. (DIIODOMETHANE)
Class: 6.1, Packing group: III
IMDG
UN Number: UN 2810
Proper shipping name: TOXIC LIQUID, ORGANIC, N.O.S. (DIIODOMETHANE)
Class: 6.1, Packing group: III

USA:
SARA 313: Not applicable.
SARA 311/312: Acute & Chronic.
California Prop 65: Not applicable.

European Labeling in Accordance with EC Directives:
H301: Toxic if swallowed
H311: Toxic in contact with skin.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause allergy or asthma symptoms or breathing difficulties if inhaled.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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