Dess Martin Periodinane or 1,1,1-Triacetoxy-1,1-dihydro-1,2-benziodoxol-3(1H)-one or (Triacetoxyperiodinane,1,1,1-tris(acetyloxy)1,1-dihydro-1,2-benziodoxol-3-(1H)- one) Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Dess Martin Periodinane, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Dess Martin Periodinane or 1,1,1-Triacetoxy-1,1-dihydro-1,2-benziodoxol-3(1H)-one or (Triacetoxyperiodinane,1,1,1-tris(acetyloxy)1,1-dihydro-1,2-benziodoxol-3-(1H)- one): CAS Number: 87413-09-0, EINECS EC Number: 672-328-8 (to be rechecked), Molecular Formula: C13H13IO8, Molecular Weight: 424.14, HS Code ---**

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Dess Martin Periodinane or 1,1,1-Triacetoxy-1,1-dihydro-1,2-benziodoxol-3(1H)-one or (Triacetoxyperiodinane,1,1,1-tris(acetyloxy)1,1-dihydro-1,2-benziodoxol-3-(1H)- one).

Dess–Martin periodinane or DMP or (Triacetoxyperiodinane,1,1,1-tris(acetyloxy)1,1-dihydro-1,2-benziodoxol-3-(1H)- one) also called 3-Oxo-1,3-dihydro-1λ5,2-benziodoxole-1,1,1-triyl triacetate is a chemical reagent used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. This periodinane has several advantages over chromium- and DMSO-based oxidants that include milder conditions (room temperature, neutral pH), shorter reaction times, higher yields, simplified workups, high chemoselectivity, tolerance of sensitive functional groups, and a long shelf life.

Specifications of Dess Martin Periodinane:
CAS number: 87413-09-0
Molecular formula: C13H13IO8
Molecular weight: 424.15
Description: White crystalline moisture sensitive powder.
Melting point: Between 130C and 132C.
Relative density: 1.36
Assay: > 97%.

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Dess Martin Periodinane SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 14-Oct-20

Product Name & Other Names: Dess Martin Periodinane or 1,1,1-Triacetoxy-1,1-dihydro-1,2-benziodoxol-3(1H)-one or (Triacetoxyperiodinane,1,1,1-tris(acetyloxy)1,1-dihydro-1,2-benziodoxol-3-(1H)- one).
CAS No.: 87413-09-0
EINECS: EC Number: 672-328-8 (to be rechecked)
Molecular Weight: 424.14
Chemical Formula: C13H13IO8
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Supplier: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Oxidizing solids Category 3, H272
Acute toxicity, Oral Category 4, H302
Acute toxicity, Dermal (Category 4), H312
Skin irritation Category 2, H315
Eye irritation Category 2, H319
Acute toxicity, Inhalation Category 4, H332
Specific target organ toxicity - single exposure Category 3, Respiratory system, H335

Hazard Statements:
H272 - May intensify fire; oxidizer
H302 - Harmful if swallowed
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.

Precautionary Statements - Prevention
P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P220: Keep/Store away from clothing/combustible materials
P221: Take any precaution to avoid mixing with combustibles
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P264: Wash face, hands and any exposed skin thoroughly after handling
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection
Precautionary Statements - Response
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of water.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P333 + P313: If skin irritation or rash occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/ attention
P342+311: If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
P362: Take off contaminated clothing and wash before reuse.
P370 + P378: In case of fire: Use water spray for extinction
Precautionary Statements - Storage
P501: Dispose of contents/container in accordance with local, regional, national, international regulations.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
O Oxidizing
Xn Harmful
R 8 Contact with combustible material may cause fire.
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R36/37/38 Irritating to eyes, respiratory system and skin.
EUH044 Risk of explosion if heated under confinement.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to Physician: Symptomatic and supportive treatment is recommended.

Flammability of the Product: Non-flammable but it is an oxidizer. Contact with combustible/organic material or at high temperature, it may cause fire. May ignite combustibles (wood paper, oil, clothing, etc.).
Products of Combustion: It emits toxic Oxides of Iodine & Carbon, Hydrogen Iodide and fumes when heated to decomposition.
Fire: It is supporting fire as an oxidizer.
Explosion: Contact with oxidizable substances may cause explosion. Explosion risk in case of fire. Fight fire remotely due to the risk of explosion.
Fire Extinguishing Media: Use water spray or fog; do not use straight streams. Use means suitable for extinguishing surrounding fire. Water spray should be preferred.
Special Information: It is an oxidizer. In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Eliminate all sources of ignition. Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Eliminate all sources of ignition. Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

Precautions for safe handling: No smoking. Keep away from heat and sources of ignition. Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, strong reducing agents, combustibles. Air and moisture sensitive. Store at temperatures not exceeding -20C.

Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: White crystalline moisture sensitive powder.
Odor: Not available.
Odor threshold: Not available.
pH: Not available.
Relative density: about 1.36
Melting Point: 130C and 132C.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Soluble in Chloroform, Acetone and Acetonitrile.
Viscosity: Not available.
Molecular Weight: 424.14
Chemical Formula: C13H13IO8
Oxidizing properties: The substance or mixture is classified as oxidizing with the category 3.

Stability: It is stable under ordinary conditions of use and storage. It becomes unstable by heat.
Hazardous Decomposition Products: It emits toxic Oxides of Iodine & Carbon, Hydrogen Iodide and fumes when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Organic substances, Strong reducing agents, Combustibles, Acids, Oxidizers and Reducing agents. Air sensitive. Heat sensitive. Light sensitive. Moisture sensitive. In the presence of moisture, this compound may form iodoxybenzoic acid which has been reported to be explosive under excessive heating or impact.
Conditions to Avoid: Incompatibles.

Toxicity to Animals: NA.
Carcinogenic Effects: Not a reported carcinogen.
Teratogenic Effects: NA.
Germ cell mutagenicity: NA.
Chronic Effects on Humans: NA.

BOD5 and COD: Not available.
Toxicity to fish: Not available.
Persistence and degradability: Not available.
Bioaccumulative potential: Not available.
Mobility in soil: Not available.
Results of PBT and vPvB assessment: Not available.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state, and local requirements. Small amounts of this material may be suitable for sanitary sewer or trash disposal.

DOT USA & ADR/RID Europe
Shipping Name: OXIDIZING SOLID, N.O.S. (Dess-Martin periodinane)
Hazard Class: 5.1
UN Number: UN1479
Hazard Label: Oxidizer
Packing Group: III
IMDG
Shipping Name: OXIDIZING SOLID, N.O.S. (Dess-Martin periodinane)
Hazard Class: 5.1
UN Number: UN1479
Hazard Label: Oxidizer
Packing Group: III
IATA
Shipping Name: OXIDIZING SOLID, N.O.S. (Dess-Martin periodinane)
Hazard Class: 5.1
UN Number: UN1479
Hazard Label: Oxidizer
Packing Group: III

USA:
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
Section 313: No chemicals are reportable under Section 313.
SARA 311/312 Hazards: Reactivity Hazard, Acute Health Hazard, Chronic Health Hazard.
California Proposition 65: This product does not contain any Proposition 65 chemicals.

European Labeling in Accordance with EC Directives:
H272 - May intensify fire; oxidizer
H302 - Harmful if swallowed
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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