CAS Number 6419-19-8, Amino tris methylene phosphonic acid ATMP Phosphonate Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Amino tris methylene phosphonic acid ATMP, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Peru, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

The products are offered as per required specifications and in correct shape and size in mm or meshs or microns as specified by the buyer.

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Export to USA UAE Europe Africa Tanzania Kenya Egypt Turkey Jumbo Packing; Exports to USA UAE Europe Africa Tanzania Kenya Uganda Egypt Turkey Brazil Chile Argentina Dubai etc. Packing Palletized and Shrink Wrapped; 25kg or 50kg or 55 lbs HDPE laminated bags with an extra HMHDP liner Drum Packing for better transportation Drum Packing & Palletized Liquid Chemical Export Import Air Freighting

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail prices, Uses etc available on these pages for Amino tris methylene phosphonic acid or ATMP Phosphonate.

In the USA, UAE, Iran Iraq, Kuwait, Saudi Arabia and other oil producing areas, several hundred chemical compounds are used in hydraulic fracturing also called fracking, fracing or frac. In some areas like UK only 'Non-Hazardous' chemicals are permitted for fracturing fluids by the Environment Agency. All chemicals have to be declared publicly and increasingly, food additive based chemicals are available to allow fracking to take place safely.

Mubychem is an internationally preferred source for Stimulation Chemicals and Hydraulic Fracturing Chemicals. We serve various oil and shale gas producing countries like USA UAE, Kuwait, Iran, Iraq, Saudi Arabia, UK, Europe India etc. We are never too far from your well-site with multiple 24/7 company owned or rented warehouses in the India, USA and across the globe. With customers in several countries, we sell almost all the fracturing chemicals.

Specifications of ATMP Phosphonate Amino tris (methylene phosphonic acid) CAS Number: 6419-19-8

ATMP or aminotris(methylenephosphonic acid) is a phosphonic acid with chemical formula N(CH2PO3H2)3. It has chelating properties. ATMP has better antiscale performance than that of polyphosphate through its excellent chelating ability, low threshold inhibition and lattice distortion process. It can prevent scale formation in water systems. ATMP is the phosphonate analog of nitrilotriacetic acid.

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30

USA, Canada, Mexico and other American
neighbouring buyers may
e-mail: us@mubychem.com
Call toll-free 1-877-682-9243 (1-877-MUBYCHEM)

Exporters to USA Canada UAE Europe South Africa Tanzania Kenya Uganda Egypt Nigeria Turkey Mexico Brazil Argentina Chile Dubai etc.

Global or International Suppliers, Exporters, Importers, Manufacturers

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B-2000 (ATMP based) SDS Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 29-Sep-20

Product Name: ATMP Phosphonate Mixture.
Relevant uses and uses advised against (if any): Oil & Gas Wells and Industrial Use.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Hazard Statements:
H290: May cause corrosion to metals
H319: Causes eye Irritation.

Precautionary Statements:
P234 Keep only in original container.
P264 Wash … thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 If IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P315: Get immediate medical advice/attention.
P336: Thaw frosted parts with lukewarm water. Do not rub affected areas.
P337+P313 If eye irritation persists: get medical advice/attention.
P406 Store in corrosive resistant/... container with a resistant inner liner.
P390 Absorb spillage to prevent material damage.
P403: Store in a well ventilated place.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xi Irritant
Risk Phrases:
R36: Irritating to eyes.

This product is hazardous as defined in 29 CFR 1910.1200. Based on the following composition:
1. Amino tris (methylene phosphonic acid): 48%-52%
CAS: 6419-19-8
EINECS EC Number: 229-146-5
2. Phosphonic acid: <4%
CAS: 13598-36-2
EINECS Number: 237-066-7
3. Phosphoric Acid: <1.5%
CAS: 7664-38-2
EINECS Number: 231-633-2

Eyes: Flush with water for at least 15 minutes. Provide medical assistance.
Skin: Remove contaminated clothes and rinse skin with plenty of water or shower.
Ingestion: Do NOT induce vomiting. If the person is conscious, give milk or water to dilute stomach contents. Repose. Medical attention. Do not attempt to give anything by mouth to an unconscious person.
If spontaneous vomiting occurs, keep head below hips to prevent aspiration and monitor respiration if there is difficulty.
Inhalation: If adverse exposure to vapors and / or aerosols, immediately remove the affected person from exposure and get immediate medical assistance victim. If breathing is difficult, give oxygen. If stops breathing, give artificial respiration.

Temperature Auto Ignition: Not available
Fire Fighting: Material will not burn. Containers can build up pressure if exposed to heat (fire). Use water spray to cool fire exposed surfaces and to protect personnel.
Special Information In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes.

Personal precautions, protective equipment, environmental precautions and emergency procedures: Use personal protective equipments. Do not get into eyes, skin, and clothing. Do not breath vapors.
Methods and materials used for containment Cleanup procedures and Storage:
Water Spill: Prevent additional discharge of material, if possible, without danger. Warn occupants and downstream and danger areas downwind of corrosive release and ask everyone to stay away. Since this material sinks and is soluble, probably not recoverable. Notify authorities.
Land Spill: Prevent additional discharge of material, if possible, without danger. Warn occupants and areas downwind of the dangers of releasing corrosive and ask everyone to stay away. For small spills implement cleanup procedures. For large spills, proceed with cleaning procedures and, if in public area, advise the authorities.
Contain spilled liquid with sand or earth. Recover by pumping or with suitable absorbent. Recycle or eliminate regulations of recovered materials in accordance with federal, state, and local laws.

Precautions for safe handling: Keep container closed. Open and handle container with care. Store in cool, well ventilated place away from incompatible materials.
DO NOT pressurize, cut, heat, or weld containers. Empty containers may contain product residue.
DO NOT reuse empty containers without commercial cleaning or reconditioning.
Conditions for safe storage, including any incompatibilities: Corrosive to most metals including carbon steel, aluminum alloys and copper and copper alloys. Avoid contact with strong alkalis, lead to violent reactions with the evolution of heat. Avoid contact with strong alkalis, metal salts of sulfides and sulfites, which could release toxic gases. Also avoid contact with strong oxidizing agents.
Temperature of Storage: Environmental
Storage Pressure: Atmospheric.

USA OSHA PEL: TWA 1 mg/m3; STEL 3 mg/m3.
USA ACGIH TLV: TWA 1 mg/m3; STEL 3 mg/m3.
We recommend that exposure lower levels are observed as reasonable worker protection.
Engineering Controls: Ventilation should be provided to control exposure of workers and prevent health risks, and if necessary to reduce, prevent and control the generation of aerosols.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Clear Pale-yellow Liquid.
Odor: Odorless
Odor threshold: Not available.
pH: <2
Relative density: 1.33
Boiling Point: 226 ° F 108 ° C
Freezing Point: <10 ° F 12 ° C
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation Rate: <1 (n-butyl acetate = 1)
Flammability (solid, gas): Not available.
Percent Volatile: 50 @ 77 ° F
Partition coefficient: n-octanol/water: Not available.
Solubility in Water: Soluble
Viscosity: Not available.

Stable: Yes
Hazardous Polymerization: Will not occur.
Conditions to Avoid: Contact with common metals produces flammable hydrogen gas.
Hazardous Decomposition Products: phosphines, CO, CO2 and nitrogen oxides
Incompatible Materials: Avoid contact with strong alkalis, lead to violent reactions with the evolution of heat. Avoid contact with metal salts of sulfides and sulfites, which could release toxic gases. Also avoid contact with strong oxidizing agents.

ATMP:
Acute toxicity
LD50 Oral - rat - 2.100 mg/kg
LD50 Dermal - rabbit - > 6.310 mg/kg
Toxicity for reproduction: ATMP acid is not toxic for reproduction, based on rats three generation study.
Genotoxicity / Mutagenicity: Not classified either for mutagenicity or genotoxicity.
Carcinogenicity: This product (or any component in it of 0.1% or greater) is not listed by NTP, IARC, OSHA OR THE DEPARTMENT OF THE ENVIRONMENT as a carcinogen.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

Environmental Toxicity:
Study results of similar item as represented by this MSDS material is as follows:
96 Hr Cl50 sunfish (Lepomis macrochirus)> 330 mg / l BOD5 = 150,000 mg/l
96 Hr LC50 Rainbow trout (Oncorhynchus mykiss)> 330 mg / l COD = 553,000 mg/l
48 Hr EC50 Water flea (Daphnia Magna) = 297 mg/l
Bioconcentration by Zahn-Wellens (OECD 3026) = 17% after 28 days
Persistence and Degradability: No information available.
Mobility: No information available.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

Empty Container: "Empty" containers retain product residue (liquid and / or vapor) and can be dangerous. Empty drums should be completely drained, properly cover, and send immediately to a drum re-conditioner or should duly divest.
General Comments: Discarded products, as sold, is considered a hazardous waste. This material must be disposed of in accordance with local, state, and federal laws that allow the treatment of hazardous chemical waste.

DOT USA & ADR/RID Europe:
Proper Shipping Name: Corrosive liquid acidic, organic, NOS
Technical Name: Contains Amino tris (methylene phosphonic acid)
Class ADR / RID: 8
UN / NA Number: 3265
Packaging: II

UNITED STATES
SARA Title III (Superfund Amendments and Reauthorization Act)
311/312 Hazard Category: Acute Health, Reactive. See section 2.
313 Reportable Ingredients: This product does not contain Reportable Ingredients according to Section 313.

European Labeling in Accordance with EC Directives:
H290 = May cause corrosion to metals
H319 = Causes eye Irritation

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xi Irritant
Risk Phrases:
R36: Irritating to eyes.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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Parameters	Limits
Appearance	Clear, Colorless to Pale Yellow
Active acid	48% min
Specific Gravity	1.30
Colour APHA (Hazen)	60 units max
Ca Sequestration	450 mg CaCO3/g min
Iron	10 ppm max
Chloride	2% max
pH value (1% solution)	2 max

Shale Gas Hydraulic Fracturing Chemicals
Acetic Acid Solution	Ammonium Persulfate or Persulphate
Acid Viscosifier	Acid Emulsifier
ATMP Phosphonate, Amino tris (methylene phosphonic acid)	Ammonium Bifluoride
Barium Sulfate Remover	BHMT or BHMTPMPA Biocide Solution
Boron & Zirconium based Guar Cross Linker	BME Iron Reducer or Dissolver
Calcium Chloride Anhydrous & Solution	Cement Defoamer
Citric Acid Solution	Clay Stabilizer
Corrosion Inhibitors	DETA Phosphonate or DTPMP Phosphonate
Didecyl Dimethyl Ammonium Chloride Solution	Diverting Agent
Encapsulated Citric Acid	Encapsulated Gel Breaker
Fe46 Liquid Iron Control Blend	Friction Reducer
Flow Back Aid, Water Recovery Surfactant	Foam or Finofoam 810
Foam 418 Heavy Crude Foamer	Gel Sweep
Glycerin Solution	Glutaraldehyde Solution
HP HT Lube	Hydroxy ethylidene diphosphonic acid, HEDP phosphonate
Hydrogen Sulfide Scavenger	Potassium Chloride
KI (Stabilised) & Initiator	KCl Substitute or Potassium Chloride Substitute
Non Emulsifier	Paraffin Dispersant
Potassium Hydroxy Ethylidene,1-Diphosphonic Acid, HEDP-Kx	Phthalic Acid, EDTA, BPA based Diverting Agents
Scale Inhibitor Chemicals	Sodium Chlorite Solution
Sodium Glutaraldehyde Bisulfite Bisulphite	Extended Release Solids - Scale Paraffin Asphaltene Inhibitor
Tetrakis Hydroxymethyl Phosphonium Sulfate THPS	Xanthan Gum Slurry
Zinc Chloride