Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance & Flavor chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc. The products are offered as per required specifications and in correct shape and size in mm or meshs or microns as specified by the buyer.
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Ammonium Bifluoride Manufacturers, SDS GHS MSDS Sheet

For SDS MSDS Sheet Click
SDS MSDS Sheet of Ammonium Bifluoride Manufacturers

Spanish Bifluoruro de amonio

Ammonium Bifluoride
Fracturing Chemical
Ammonium Bifluoride

In the USA, UAE, Iran Iraq, Kuwait, Saudi Arabia and other oil producing areas, several hundred chemical compounds are used in hydraulic fracturing also called fracking, fracing or frac. In some areas like UK only 'Non-Hazardous' chemicals are permitted for fracturing fluids by the Environment Agency. All chemicals have to be declared publicly and increasingly, food additive based chemicals are available to allow fracking to take place safely.

Mubychem is an internationally preferred source for Stimulation Chemicals and Hydraulic Fracturing Chemicals. We serve various oil and shale gas producing countries like USA UAE, Kuwait, Iran, Iraq, Saudi Arabia, UK, Europe India etc. We are never too far from your well-site with multiple 24/7 company owned or rented warehouses in the India, USA and across the globe. With customers in several countries, we sell almost all the fracturing chemicals.

Specifications of Ammonium Bifluoride:

PARAMETERS TYPICAL ANALYSIS
NH4HF2, % 96.0 minimum
NH4F, % 4.0 maximum
F % 65.0 minimum
Fe, ppm 10 maximum
SO4, ppm 100 maximum
SiO2, ppm 100 maximum
Cl, ppm 30 maximum
AS, ppm 10 maximum
Pb, ppm 5.0 maximum
Ni, ppm 10 maximum
Cu, ppm 30 maximum
Sb, ppm 10 maximum
H2O, ppm 1000 maximum

Manufacturers:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) 91-22-23770100, 23726950
Current Date Time in India GMT+5:30

e-mail: info@mubychem.com

USA & Canadian Customers may
e-mail: usa@mubychem.com
Call toll-free 1-844-682-9243 (1-844-MUBYCHEM)

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Copyright and Usual Disclaimer is Applicable.
Last : 11 April, 2017

Shale Gas Hydraulic Fracturing Chemicals
Acetic Acid Solution Ammonium Persulfate or Persulphate
Acid Viscosifier Acid Emulsifier
ATMP Phosphonate, Amino tris (methylene phosphonic acid) Ammonium Bifluoride
Barium Sulfate Remover BHMT or BHMTPMPA Biocide Solution
Boron & Zirconium based Guar Cross Linker BME Iron Reducer or Dissolver
Calcium Chloride Anhydrous & Solution Cement Defoamer
Citric Acid Solution Clay Stabilizer
Corrosion Inhibitors DETA Phosphonate or DTPMP Phosphonate
Didecyl Dimethyl Ammonium Chloride Solution Diverting Agent
Encapsulated Citric Acid Encapsulated Gel Breaker
Fe46 Liquid Iron Control Blend Friction Reducer
Flow Back Aid, Water Recovery Surfactant Foam or Finofoam 810
Foam 418 Heavy Crude Defoamer Gel Sweep
Glycerin Solution Glutaraldehyde Solution
HP HT Lube Hydroxy ethylidene diphosphonic acid, HEDP phosphonate
Hydrogen Sulfide Scavenger Potassium Chloride
KI (Stabilised) & Initiator KCl Substitute or Potassium Chloride Substitute
Non Emulsifier Paraffin Dispersant
Potassium Hydroxy Ethylidene,1-Diphosphonic Acid, HEDP-Kx Phthalic Acid, EDTA, BPA based Diverting Agents
Scale Inhibitor Chemicals Sodium Chlorite Solution
Sodium Glutaraldehyde Bisulfite Bisulphite

Extended Release Solids - Scale Paraffin Asphaltene Inhibitor

Tetrakis Hydroxymethyl Phosphonium Sulfate THPS Xanthan Gum Slurry
Zinc Chloride  

Exporter & ImporterBy Air ExportsExporters & ImprotersAmmonium Bifluoride Manufacturers

Exporters to USA Canada UAE Europe South Africa Tanzania Kenya Uganda Egypt Nigeria Turkey Mexico Brazil Argentina Chile Dubai etc.

Global or International Suppliers, Exporters, Importers, Manufacturers

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Ammonium Bifluoride SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet

1. Product Identification

Synonyms: Ammonium hydrogen difluoride
CAS No.: 1341-49-7
EINECS: EC Number: 215-676-4
Molecular Weight: 57.04
Chemical Formula: NH4HF2
Relevant Uses: Fracturing and Industrial use only.

SUPPLIER
Company: Finoric LLC
Address: 8115 Loop 540, Beasley, Texas, 77417 USA

In case of emergency contact:
InfoTrac
US: 1-800-535-5053 
International: 352-323-3500

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Oral: Category 3
Skin corrosion/irritation Category 1A, B, C
Serious eye damage/eye irritation Category 1
Specific target organ toxicity, repeated exposure Category 2

Labeling according GHS USA & Regulation (EC) No 1272/2008

GHS Label Elements
Toxic
Toxic

GHS Label Elements
Health Hazard
Health Hazard

GHS Label Elements
Corrosive
Corrosive

Signal Words: Danger

Hazard Statements:
H301: Toxic if swallowed.
H314: Causes severe skin burns and eye damage.
H318: Causes serious eye damage.
H373: Causes damage to organs through prolonged or repeated exposure.

Precautionary Statements:
P301+P310: IF SWALLOWED: Immediately call a POSION CENTER or doctor/physician.
P273: Avoid release to the environment.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P271: Use only outdoors or in a well-ventilated area.
P264: Wash contaminated parts thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P:273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P314: Get medical advice/attention if you feel unwell.
P302+352: IF ON SKIN: Wash with plenty of soap and water.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. P337+P313: If eye irritation persists get medical advice/attention.
Remove contact lenses if present and easy to do – continue rinsing.
P330: Rinse mouth.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P403+P404: Store in well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/national regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
T Toxic, Xn Harmful
R20,  R25, R41, R48
For the full text of the S-statement & R-phrases mentioned in this Section, see Section 16.

3. Composition/Information on Ingredients

Ingredient: Ammonium Bifluoride
CAS No.: 1341-49-7
EINECS: EC Number: 215-676-4
Percent: 95 - 100%

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

5. Fire Fighting Measures

Flammability of the Product: Non-flammable.
Products of Combustion: Ammonia, Nitrogen oxides, Hydrofluoric acid and fumes.
Fire: Ammonium Bifluoride is not considered to be a fire hazard.
Explosion: Ammonium Bifluoride is not considered to be an explosion hazard.
Fire Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Use means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes.

6. Accidental Release Measures

Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Ammonium Bifluoride is a poisonous solid. Avoid touching the spilled material. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Do not contaminate the environment.

7. Handling and Storage

Toxic! Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment.
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Wash hands thoroughly after handling. Provide appropriate exhaust ventilation at places where dust is formed. If you feel unwell, seek medical attention.
Keep Ammonium Bifluoride in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Moist Ammonium Bifluoride and concentrated solutions can corrode steel.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits:
2.5 mg/m3 USA (OSHA) - Table Z-1 Limits for Air Contaminants
(Vacated) TWA: 2.5 mg/m3 OSHA PEL
TWA 2.5 mg/m3 ACGIH TLV
TWA: 2.5 mg/m3 NIOSH IDLH
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: Ammonium Bifluoride is white crystals, powder or granules.
Odor: Pungent.
Solubility: It is freely soluble in water.
pH: 3.5.
Density: 1.5 g/mL
Molecular Weight
: 57.04
Chemical Formula: NH4HF2
% Volatiles by volume @ 21C (70F): NA
Boiling Point: 240C
Melting Point: 125C

10. Stability and Reactivity

Stability: Ammonium Bifluoride  is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits toxic hydrogen fluoride fumes when heated to decomposition. It may form Ammonia, Nitrogen oxides and Hydrogen fluoride and Fluorine.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, strong acids and bases.
Conditions to Avoid
: Incompatibles and direct sunlight and moisture..

11. Toxicological Information

Acute toxicity
Toxic, and may be fatal, if swallowed. Chronic exposure may cause damage to a variety of body organs. Harmful if inhaled. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Cough, Shortness of breath, Headache, Nausea
Toxicity data
ORL-RAT LD50 130 mg kg-1
LD50 Intraperitoneal – rat – 31 mg/kg
LC50 – mouse – 342 mg/kg – 1 hour
Carcinogenic Effects: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.

12. Ecological Information

Toxicity to fish: Not available.
Toxicity to daphnia and other aquatic invertebrates: Not available.
Environmental Toxicity: Not available.
Toxicity of the Products of Biodegradation: Not available..

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information

USA DOT, IMDG & Canada TDG Classification:
UN-Number: 1727 CLASS 8: Packing group: II
Identification: AMMONIUM HYDROGENDIFLUORIDE, SOLID
IATA/ICAO
UN-Number: 1727 CLASS 8: Packing group: II
Identification: AMMONIUM HYDROGENDIFLUORIDE, SOLID

15. Regulatory Information

USA:
TSCA 12(b): Not applicable
SARA 302 Components: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazardous Categorization: Acute Health Hazard
Clean Water Act: Listed. Reportable Quantity 100 pounds.
Clean Air Act: Not applicable
CERCLA: Reportable Quantity 100 pounds.
California Proposition 65: This product does not contain any Proposition 65 chemicals
Listed by State Right to Know: Massachusetts, Pennsylvania, New Jersey Right

Canada WHMIS Hazard Class: D1B Toxic materials, E Corrosive material
Canadian Ingredient Disclosure List: listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

EINECS: EC Number: 215-676-4
European Labeling in Accordance with EC Directives:
H301: Toxic if swallowed.
H314: Causes severe skin burns and eye damage.
H318: Causes serious eye damage.
H373: Causes damage to organs through prolonged or repeated exposure.
Hazard Symbols: T = Toxic; Xn = Harmful
Risk Phrases: R 25 = Toxic if swallowed. R 20 Harmful by inhalation. R41 Risk of serious damage to eyes. R48 Danger of serious damage to health by prolonged exposure.
Safety Phrases: S 45 In case of accident or if you feel unwell, seek medical advice immediately. S28- After contact with skin, wash immediately with plenty of water. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S46- If swallowed, seek medical advice immediately.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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