Phosphorus Tribromide or Phosphorus (III) bromide Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Phosphorus Tribromide or Phosphorus (III) bromide, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Phosphorus Tribromide or Phosphorus (III) bromide: CAS Number: 7789-60-8, EINECS EC Number: 232-178-2, Molecular Formula: PBr3, Molecular Weight: 270.69, HS Code ---**

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Phosphorus Tribromide or Phosphorus (III) bromide.

Phosphorus tribromide or Phosphorus (III) bromide is a colorless liquid with the formula PBr3. It is a colorless liquid that fumes in moist air due to hydrolysis and has a penetrating odor. It is used in the laboratory for the conversion of alcohols to alkyl bromides. Phosphorus tribromide is used in preparing of pharmaceuticals like Fenoprofen, Methohexital etc. Phosphorus tribromide, has both properties of a Lewis base and a Lewis acid.

Specifications of Phosphorus Tribromide or Phosphorus (III) bromide:
CAS Number: 7789-60-8
Molecular formula: PBr3
Formula weight: 270.7
Appearance: Colorless to pale yellow fuming liquid.
Solubility: Soluble in Alcohol, Chloroform. Reacts with water, ethanol.
Relative density: 2.86
Melting point: -41 to -42C literature.
Boiling point: 170C to 175C literature.
Residue: 0.5% maximum
Assay: 99% minimum.

We manufacture and supply the entire range of bromine based organic chemicals and inorganic bromide chemicals:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30

USA, Canada, Mexico and other American
neighbouring buyers may
e-mail: us@mubychem.com
Call toll-free 1-877-682-9243 (1-877-MUBYCHEM)

Exporters to USA Canada UAE Europe South Africa Tanzania Kenya Uganda Egypt Nigeria Turkey Mexico Brazil Argentina Chile Dubai etc.

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Phosphorus Tribromide SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 12-Nov-20

Product Name & Other Names: Phosphorus Tribromide or Phosphorus (III) bromide.
CAS No.: 7789-60-8
EINECS EC Number: 232-178-2
Molecular Weight: 270.69
Chemical Formula: PBr3
Relevant uses and uses advised against (if any) : Laboratory chemicals, Manufacture of substances. For Industrial use.
Details of the supplier of the safety data sheet: As per letter head.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Skin corrosion/irritation Category 1A, B, C H314
Specific target organ toxicity - single exposure Category 3, Respiratory system, H335

Hazard statements:
H314: Causes severe skin burns and eye damage.
H335: May cause respiratory irritation.
EUH014: Reacts violently with water.

Precautionary statements:
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P362: Take off contaminated clothing and wash before reuse.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P501: Dispose of contents/container to authorized agents only.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
C Corrosive
Risk Phrases:
R35 Causes severe burns.
R37 Irritating to respiratory system.

Product Name/Synonyms: Phosphorus Tribromide or Phosphorus (III) bromide.
CAS No.: 7789-60-8
EINECS EC Number: 232-178-2

Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eye with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Call a physician, immediately. Wash clothing before reuse.
Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to and unconscious person. Loosen tight clothing such as a collar, tie, belt, or waistband. Get medical attention immediately.
Inhaled: If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
Medical Conditions generally Aggravated by Exposure: Repeated exposure of the eyes can produce eye irritation. Inhalation can produce respiratory irritation or sensitization.
Notes to Physician: Treat symptomatically.

Flash Point: NA
Fire Extinguishing Media: Adapt extinguishing media to the environment. Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide.
Special Fire Fighting Procedures: Wear self contained breathing apparatus for firefighting if necessary. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. In case of fire in the surroundings: Remove movable containers if safe to do so.
Hazardous combustion products: Hydrogen bromide, phosphorous compounds, and toxic fumes.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Steps to be Taken in Case Material is Released or Spilled: Evacuate the area of all unnecessary personnel. Wear suitable protective equipment. Avoid breathing vapors, mist, or gas. Ensure adequate ventilation. Contain the release and eliminate its source if this can be done without risk. Take up and containerize for proper disposal. Comply with local, state, and federal regulations on reporting releases.
Methods for cleaning up: Take up liquid spill into absorbent material, e.g.: dry sand/earth or powdered limestone. Scoop absorbed substance into closing containers. Carefully collect the spill/leftovers. Small quantities of liquid spill may be neutralize with alkali solution. Wash away neutralized product with plentiful water. Clean contaminated surfaces with an excess of water. Take collected spill to manufacturer/competent authority. Wash clothing and equipment after handling.
Waste Disposal Methods: Do not let product enter drains. Dispose of waste according to Federal, State and Local Regulations.

Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Keep in a tightly closed original container. Protect from physical damage. Store in a cool, dry, ventilated area away from sources of heat and incompatibilities. Containers may be hazardous when empty since they retain product residues; observe all warnings and precautions listed for the product. Air sensitive.

Components with workplace control parameters: Contains no substances with occupational exposure limit values.
Engineering Controls Ventilation required: It should be handled or transferred in an approved fume hood or with adequate ventilation.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance and Physical State: Colorless to pale yellow fuming liquid.
Odor (threshold): Penetrating or pungent odor.
Odor threshold: Not available.
pH: Not available.
Relative density: about 2.86
Melting point/freezing point: Not available.
Boiling Point: 170C to 175C literature.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Soluble in Alcohol, Chloroform. Reacts with water, ethanol.
Viscosity: Not available.
Molecular Weight: 270.69
Chemical Formula: PBr3

Stability: It is stable under ordinary conditions of use and storage.
Reactivity: Reacts with water. Extremely reactive or incompatible with alkalis, moisture.
Materials to Avoid (Incompatibility): Strong oxidizing agents, Alkalis, Acids, Metals, Alcohols, Organic materials. Air sensitive. Heat sensitive.
Hazardous Decomposition Products: Thermal decomposition may produce hydrogen bromide, phosphorous compounds, and toxic fumes.
Hazardous Polymerization: Will not occur.

Results of component toxicity test: Not available.
Carcinogenicity: This product is not classifiable as to its carcinogenicity based on its IARC, ACGIH, NTP, or EPA classification.
Mutagenic Effects: No information available.
Reproductive Effects: No information available.
Developmental Effects: No information available.
Teratogenicity: No information available.

Toxicity to fish: Not available.
The product may affect the acidity (pH-factor) in water with risk of harmful effects to aquatic organisms.
Bioaccumulation/ Accumulation: No information available.
Mobility: Will likely be mobile in the environment due to its water solubility.
Results of PBT and vPvB assessment: No information available.

State and local laws governing disposal of materials can differ. Ensure proper disposal compliance with proper authorities before disposal.

DOT USA, TDG Canada & ADR/RID Europe :
Proper shipping name: PHOSPHORUS TRIBROMIDE
Hazard Class: 8
Packaging group: II
UN Number: UN1808
IATA & IMO/IMDG:
Proper shipping name: PHOSPHORUS TRIBROMIDE
Hazard Class: 8
Packaging group: II
UN Number: UN1808

USA:
SARA Section 311/312 Hazard Classes: Immediate (acute) health hazard
SARA 302 Extremely Hazardous Substance: None present or none present in regulated quantities.
SARA 313: None present or none present in regulated quantities.
California Proposition 65: None

European Labeling in Accordance with EC Directives:
H314: Causes severe skin burns and eye damage.
H335: May cause respiratory irritation.
EUH014: Reacts violently with water.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
C Corrosive
Risk Phrases:
R35 Causes severe burns.
R37 Irritating to respiratory system.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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