N-Butyl Bromide or 1-Bromobutane Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of N-Butyl Bromide or 1-Bromobutane, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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N-Butyl Bromide or 1-Bromobutane: CAS Number: 109-65-9, EINECS EC Number: 203-691-9, Molecular Formula: CH3CH2CH2CH2Br or C4H9Br, Molecular Weight: 137.02, HS Code ---**

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for N-Butyl Bromide or 1-Bromobutane.

N-Butyl Bromide or 1-Bromobutane is the organobromine compound with the formula CH3(CH2)3Br. It is a colorless liquid, although impure samples appear yellowish. It is insoluble in water, but soluble in organic solvents. It is a primarily used as a source of the butyl group in organic synthesis. It is one of several isomers of butyl bromide. N-Butyl Bromide or 1-Bromobutane is used in refrigerant, pharmaceuticals, insecticides, flavors and fragrances, quaternary ammonium compounds

Specification of N-Butyl Bromide or 1-Bromobutane:
Formula: CH3CH2CH2CH2Br or C4H9Br
CAS number: 109-65-9
EINECS EC number: 203-691-9
Molecular weight: 137.02
Description: Colorless Liquid
Relative density: 1.27
Solubility: Insoluble in water, soluble in alcohol ether
Melting point: -112C to -113C.
Boiling point: 101C
Assay: 99% minimum
Moisture Content: 0.2% maximum
Other Impurities: NMT 1% maximum.

We manufacture and supply the entire range of bromine based organic chemicals and inorganic bromide chemicals:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30

USA, Canada, Mexico and other American
neighbouring buyers may
e-mail: us@mubychem.com
Call toll-free 1-877-682-9243 (1-877-MUBYCHEM)

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N-Butyl Bromide or 1-Bromobutane SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 08-Nov-20

Product Name & Other Names: N-Butyl Bromide or 1-Bromobutane
CAS No.: 109-65-9
EINECS EC Number: 203-691-9
Molecular Formula: CH3CH2CH2CH2Br or C4H9Br
Molecular Weight: 137.02
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Supplier: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Flammable liquids Category 2 H225
Skin corrosion/irritation Category 2 H315
Serious eye damage/eye irritation Category 1 H319
Specific target organ toxicity, single exposure; Respiratory tract irritation Category 3 H335
Chronic aquatic toxicity, Category 2, H411

Hazard statements:
H225 Highly flammable liquid and vapor.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H412 Toxic to aquatic life with long lasting effects.

Precautionary statements:
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/light/…/equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P262: Do not get in eyes, on skin, or on clothing.
P264 Wash skin thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P314: Get Medical advice/attention if you feel unwell.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P391: Collect spillage.
P403+235: Store in a well-ventilated place. Keep cool.
P404: Store in a closed container.
P405: Store locked up.
P501 Dispose of contents/ container to an approved waste disposal plant.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
F = Flammable.
Xi = Irritant.
N = Dangerous for the environment.
Risk Phrases:
R11 Highly flammable
R36/37/38 Irritating to eyes, respiratory system and skin
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Product Name & Other Names: N-Butyl Bromide or 1-Bromobutane
CAS No.: 109-65-9
EINECS EC Number: 203-691-9

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.
Ingestion: If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Advice to physician: Treat symptomatically.

Fire Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide. Avoid solid water jet.
Special hazards arising from the substance or mixture: Toxic fumes, Carbon oxides, Hydrogen bromide gas.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.
Further information: Use water spray to cool unopened containers.

Personal precautions, protective equipment, and emergency procedures: Ventilate area of leak or spill. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. Prevent further leakage or spillage if safe to do so.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, strong bases, magnesium, sodium/sodium oxides, potassium. Keep away from sources of ignition - No smoking. Take measures to prevent the buildup of electrostatic charge.

Airborne Exposure Limits: This product does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, a full face piece respirator with dust/mist filter may be worn. For emergencies or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice.

Appearance: Colorless Liquid.
Odor: Aromatic.
Odor threshold: Not available.
pH: Not available.
Relative density: 1.27
Boiling Point: 101C
Melting Point: -112C to -113C.
Flash point: 10C.
Auto-ignition temperature: 265C.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Insoluble in water, soluble in alcohol ether.
Viscosity: Not available.
Molecular Formula: CH3-CHBr-CH2CH3 or C4H9Br
Molecular Weight: 137.02

Stability: It is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: When heated to decomposition it emits Toxic fumes, Carbon oxides, Hydrogen bromide gas.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, Strong bases, Magnesium, Sodium/sodium oxides, Potassium.
Conditions to Avoid: Heat, flames, sparks. extreme temperatures, direct sunlight, incompatibles.

LD50 Oral - Rat: 2761 mg/kg.
LC50 Inhalation - Rat : 47000 mg/m3 2 h
Carcinogenic Effects: Not a reported carcinogen as per IARC, ACGIH, NTP & OSHA.
Reproductive toxicity: Not available.
Germ cell mutagenicity: Not available.
Teratogenicity: Not available.

Toxicity to fish: LC50: = 36.7 mg/L, 96h flow-through (Pimephales promelas)
Toxicity to daphnia and other aquatic invertebrates: Not available.
Toxicity to algae: EC50 - Algae - 20.87 mg/l - 96 h.
Environmental Toxicity: Harmful to aquatic organisms.
Mobility in soil: Not available.
Results of PBT and vPvB assessment: Not available.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with legal requirements.

DOT USA, TDG Canada & ADR/RID Europe
Proper Shipping Name: 1-BROMOBUTANE.
UN/NA: UN1126; Hazard Class: 3; Packing Group: II
International (Water, I.M.O.), IMDG and IATA
Proper Shipping Name: 1-BROMOBUTANE.
UN/NA: UN1126; Hazard Class: 3; Packing Group: II

SARA 302: Not listed.
SARA 313: Not listed.
SARA 311/312 Hazards: Fire Hazard, Immediate Health Hazard. See section 2.
California Prop. 65 Components: Not listed.

European Labeling in Accordance with EC Directives:
H225 Highly flammable liquid and vapor.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H412 Toxic to aquatic life with long lasting effects.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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