Toluene diisocyanate or TDI Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Toluene diisocyanate or TDI, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc.

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Toluene-2,4-diisocyanate TDI CAS Number: 584-84-9, EINECS EC Number: 209-544-5, Molecular Formula: C9H6N2O2 or CH3C6H3(NCO)2, Molecular Weight: 174.16, HS Code ---**

Toluene-2,6-diisocyanate TDI CAS Number: 91-08-7, EINECS EC Number: 202-039-0, Molecular Formula: C9H6N2O2 or CH3C6H3(NCO)2, Molecular Weight: 174.16, HS Code ---**

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SDS MSDS Sheet of Toluene diisocyanate or TDI Manufacturers

Toluene diisocyanate
TDI Pure Suppliers
Toluene diisocyanate or TDI

Toluene diisocyanate (TDI) is an organic compound with the formula CH3C6H3(NCO)2. Two of the six possible isomers are commercially important: 2,4-TDI (CAS: 584-84-9) and 2,6-TDI (CAS: 91-08-7). 2,4-TDI is produced in the pure state. Generally, commercial material comes as a mixture of the two isomers.

SPECIFICATIONS OF TOLUENE DI- ISOCYANATE (TDI 80:20)
CAS Number: 584-84-9
Apperance: Clear liquid.
APHA color: 25 maximum.
Specific Gravity (at 20C / 20C): 1.22 ± 0.02
Purity: 99.7% minimum.
Isomer Content (% by wt.):
2,4 TDI: 80 ± 1
2,6 TDI: 20 ± 1
Total Acidity: 40 ppm minimum.
Hydrolyzable Chlorine: 80 ppm maximum.
Total Chlorine: 700 ppm maximum.

We can also supply Toluene-2,4-diisocyanate CAS Number 584-84-9 and Toluene-2,6-diisocyanate CAS Number 91-08-7.

We also manufacture and supply as under:

Butylated Hydroxy Toluene

4-Iodotoluene

Para Bromotoluene

Toluene Diisocyanate

para-Toluenesulfonyl Chloride

Benzene

Toluene

Manufacturers:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30

e-mail: info@mubychem.com

USA, Canada, Mexico and other American
neighbouring buyers may
e-mail: us@mubychem.com
Call toll-free 1-844-682-9243 (1-844-MUBYCHEM)

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Last 28 August, 2022

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Toluene diisocyanate or TDI SDS Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet
21-Nov-20

Section 1. Product Information

Product Name & Other Names: Toluene diisocyanate or TDI.
CAS No.: Toluene-2,4-diisocyanate TDI: CAS Number: 584-84-9 & Toluene-2,6-diisocyanate TDI: CAS Number: 91-08-7.
EINECS EC Number: Toluene-2,4-diisocyanate TDI 209-544-5 & Toluene-2,6-diisocyanate TDI 202-039-0.
Chemical Formula: C9H6N2O2 or CH3C6H3(NCO)2
Molecular Weight: 174.16
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

Section 2: Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Skin irritation (Category 2), H315
Skin sensitization (Category 1), H317
Eye irritation (Category 2), H319
Acute toxicity, Inhalation (Category 2), H330
Respiratory sensitization (Category 1), H334
Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335
Specific target organ toxicity - repeated exposure (Category 2), H373
Long-term (chronic) aquatic hazard (Category 1), H410
Chronic aquatic toxicity (Category 3), H412

Labeling according GHS & Regulation (EC) No 1272/2008

GHS Label Elements
toxic.png
Toxic

GHS Label Elements
healthhazard.png
Health Hazard

Signal Words: Danger

Hazard statements:
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H330 Fatal if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H373 May causes damage to organs through prolonged or repeated exposure.
H412 Harmful to aquatic life with long lasting effects.

Precautionary statements:
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P272: Contaminated work clothing should not be allowed out of the workplace.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P314: Get medical advice/attention if you feel unwell.
P330: Rinse mouth.
P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P333+313: If skin irritation or a rash occurs: Get medical advice/attention.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P391: Collect spillage.
P405: Store locked up.
P403+233: Store in a well-ventilated place. Keep container tightly closed.
P501: Dispose of contents/container in accordance with local/regional/national/international regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
T = Toxic
Xi = Irritant
Risk Phrases:
R23 = Toxic by inhalation.
R36/37/38 Irritating to eyes, respiratory system and skin.
R42 May cause sensitization by inhalation.
R43 May cause sensitization by skin contact.
R48 Danger of serious damage to health by prolonged exposure.
R53 May cause long-term adverse effects in the aquatic environment.

Section 3: Composition and Information on Ingredients

Product Name & Other Names: Toluene diisocyanate or TDI.
CAS No.: Toluene-2,4-diisocyanate TDI: CAS Number: 584-84-9 & Toluene-2,6-diisocyanate TDI: CAS Number: 91-08-7.
EINECS EC Number: Toluene-2,4-diisocyanate TDI 209-544-5 & Toluene-2,6-diisocyanate TDI 202-039-0.

Section 4. First Aid & Procedure

Always get medical attention after the first aid is over.

Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes. Remove and wash contaminated clothing and shoes before reuse. Get medical attention if irritation develops.
Eyes:
Immediately flush eyes with plenty of water for 15 minutes, occasionally lifting upper and lower eyelids. Hold eyelids apart during irrigation. Get medical attention.
Inhalation:
Remove person to fresh air. If breathing is difficult, give oxygen. If not breathing administer artificial respiration. Get medical attention.

Section 5. Fire Fighting Measures

Fire/Explosion: Not considered to be a fire and explosion hazard.
Extinguishing Medium:
Water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance/ mixture: Nitrogen oxides (NOx), carbon oxides, fumes.
Fire Fighting Instructions: Use suitable protective equipment for surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Section 6. Spills and Disposals

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

Section 7. Handling and Storage

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, alcohols, strong bases, amines, acids. Light and moisture sensitive.

Section 8. Exposure Controls & Personal Protection

Exposure Limits:
ACGIH TLV(TWA): 0.001 ppm (skin)
ACGIH TLV(STEL): 0.005 ppm (skin).
Engineering Controls: Use adequate exhaust ventilation to keep airborne concentrations below the allowable exposure limit. Install a closed system or local exhaust. Also install safety shower and eye bath.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Section 9. Physical & Chemical Data

Appearance: Clear and colorless to slightly yellow liquid.
Odor: Pungent.
Odor threshold: Not available.
pH: Not available.
Relative density: about 1.2
Melting point/freezing point: 20C-22C literature.
Initial boiling point and boiling range: 115C  - 120C for Toluene-2,4-diisocyanate & 129C to 133C Toluene-2,6-diisocyanate.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility(ies): Not available.
Viscosity: Not available.
Chemical Formula: C9H6N2O2 or CH3C6H3(NCO)2
Molecular Weight: 174.16

Section 10. Stability and Reactivity

Chemical Stability: Stable under normal temperatures and pressures.
Incompatibility (Materials to Avoid):
Alcohols, Strong bases, Amines, acids, Strong oxidizing agents.
Conditions to Avoid: Incompatible materials, exposure to excessive heat, light and moisture.
Hazardous Decomposition Products: Nitrogen oxides (NOx), carbon oxides, fumes.
Hazardous Polymerization:
Will not occur.

Section 11. Toxicological Information

Toxicity to Animals:
LD50 Oral - Rat - male - 5,110 mg/kg(Toluene-2,4-di-isocyanate).
LC50 Inhalation - Rat - male and female - 1 h - 0.48 mg/l(Toluene-2,4-di-isocyanate)
LD50 Dermal - Rabbit - male and female - > 9,400 mg/kg(Toluene-2,4-di-isocyanate)
Carcinogenicity: IARC: 2B - Group 2B: Possibly carcinogenic to humans.
Reproductive toxicity: No information available.
Developmental Effects: No information available.

Section 12. Ecological Information

Toxicity to fish: static test LC50 - Oncorhynchus mykiss (rainbow trout) - 133 mg/l - 96 h(Toluene-2,4-di-isocyanate).
Toxicity to daphnia and other aquatic invertebrates: static test EC50 - Daphnia magna (Water flea) - 12.5 mg/l - 48 h(Toluene-2,4-di-isocyanate)
Ecotoxicity: Harmful to aquatic life with long lasting effects. DO NOT DISCHARGE into drains and rivers.
Bioaccumulative potential: no data available
Mobility in soil: no data available
PBT and vPvB assessment: no data available.

Section 13. Disposal Suggestions

Dispose of in accordance with all applicable local, state, and federal regulations at an approved waste disposal facility.

Section 14. Transport and Label Information

DOT USA, TDG Canada & ADR/RID Europe:
UN-No UN 2078, Proper Shipping Name: TOLUENE DIISOCYANATE
Hazard Class 6.1; Packing Group II
IMDG/IMO
UN-No UN 2078, Proper Shipping Name: TOLUENE DIISOCYANATE
Hazard Class 6.1; Packing Group II
IATA:
UN-No UN 2078, Proper Shipping Name: TOLUENE DIISOCYANATE
Hazard Class 6.1; Packing Group II

Section 15. Regulatory Information

USA:
SARA 311/312 Hazards
: Acute Health Hazard, Chronic Health Hazard
California Prop. 65 Components: California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer.

Section 16. Other Information

European Labeling in Accordance with EC Directives:
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H330 Fatal if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H373 May causes damage to organs through prolonged or repeated exposure.
H412 Harmful to aquatic life with long lasting effects.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
T = Toxic
Xi = Irritant
Risk Phrase:
R23 = Toxic by inhalation.
R36/37/38 Irritating to eyes, respiratory system and skin.
R42 May cause sensitization by inhalation.
R43 May cause sensitization by skin contact.
R48 Danger of serious damage to health by prolonged exposure.
R53 May cause long-term adverse effects in the aquatic environment.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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