BHT Butylated Hydroxytoluene Pure and EP BP Ph Eur USP NF FCC Food Grade Manufacturers, with SDS MSDS Sheet

Supplier, Manufacturer, Exporter of BHT Butylated hydroxytoluene EP BP Ph Eur USP NF FCC Food Grade, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Peru, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Butylated hydroxytoluene BHT CAS Number 128-37-0, EINECS EC Number 204-881-4, HS Code 290719** or 290712**, Molecular Weight 220.35, Molecular Formula: C15H24O

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail prices, Uses etc available on these pages for Butylated hydroxytoluene BHT.

Purity: 99.50% min
Appearance: White crystalline or powder
Water content: 0.1% max
Residue on ignition: 0.01% max
Sulfate: 0.002% max.
Heavy metal (as Pb): 0.0004% max.
Arsenic (as As): 0.0001% max
Free phenol: 0.02% max
Moisture: 0.1% max
Lead: 5 mg/Kg max
Mercury: 1 mg/Kg max
Packing will be 25-50kg or 55 lbs. in Double bags or in drums.

Butylated Hydroxytoluene BP Ph Eur Grade
Butylhydroxytoluene Ph Eur
C15H24O --- 220.4 --- CAS 128-37-0
Action and use: Antioxidant.

DEFINITION
Butylhydroxytoluene is 2,6-bis(1,1-dimethylethyl)-4-methylphenol.

CHARACTERS
A white or yellowish-white, crystalline powder, practically insoluble in water, very soluble in acetone, freely soluble in alcohol and in vegetable oils.

IDENTIFICATION
First identification A, C.
Second identification A, B, D.
A. It complies with the test for the freezing-point.
B. Dissolve 0.500 g in ethanol and dilute to 100.0 ml with the same solvent. Dilute 1.0 ml of this solution to 100.0 ml with ethanol. Examined between 230 nm and 300 nm, the solution shows an absorption maximum at 278 nm. The specific absorbance at the maximum is 80 to 90.
C. Examine by infrared absorption spectrophotometry and.
D. Dissolve about 10 mg in 2 ml of alcohol. Add 1 ml of a 1 g/l solution of testosterone
propionate in alcohol and 2 ml of dilute sodium hydroxide solution. Heat in a waterbath at 80C for 10 min and allow to cool. A blue colour develops.

TESTS
Appearance of solution: Dissolve 1.0 g in methanol and dilute to 10 ml with the same solvent. The solution is clear and not more intensely coloured than reference solution.
Freezing-point: 69C to 70C.
Related substances: To pass the test --- (0.5 per cent).
Sulphated ash: Not more than 0.1 per cent, determined on 1.0 g.

We also manufacture Butylated hydroxytoluene, BHT, Butylhydroxytoluene of EP Grade.

Butylated Hydroxytoluene USP NF Grade
C15H24O --- 220.35
Phenol, 2,6-bis(1,1-dimethylethyl)-4-methyl-.
2,6-Di-tert-butyl-p-cresol CAS 128-37-0.

Packaging and storage: Preserve in well-closed containers.
Identification: To 10 mL of a solution in methanol (1 in 100,000) add 10 mL of water, 2 mL of sodium nitrite solution (3 in 1000), and 5 mL of dianisidine dihydrochloride solution (1 in 500), prepared by dissolving 200 mg of dianisidine dihydrochloride in a mixture of 40 mL of methanol and 60 mL of 1 N hydrochloric acid: an orange-red color develops within 3 minutes. Add 5 mL of chloroform, and shake: the chloroform layer exhibits a purple or magenta color, which fades when exposed to light.
Congealing temperature: not lower than 69.2, corresponding to not less than 99.0% of C15H24O.
Residue on ignition: Transfer about 50 g, accurately weighed, to a tared crucible, ignite until thoroughly charred, and cool. Moisten the ash with 1 mL of sulfuric acid, and complete the ignition by heating at 800C ± 25C for 15-minute periods to constant weight: the limit is 0.002%.
Heavy metals: 0.001%.

BHT Butylated Hydroxytoluene, 2,6-Di-tert-butyl-p-cresol FCC Food Grade
C15H24O, Formula weight 220.35
INS: 321 CAS 128-37-0

DESCRIPTION
BHT occurs as a white, crystalline solid. It is freely soluble in alcohol, and insoluble in water and in propylene glycol.
Function: Antioxidant.

BHT Butylated Hydroxytoluene SDS GHS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 03-Oct-20

Product Name & Other Names: BHT; 2,6-Di-tertbutyl-p-cresol; 2,6-Bis(1,1-dimethylethyl)-4-methylphenol; 2,6-Di-tert-butyl-1-hydroxy-4-methylbenzene; 2,6-Di-tertbutyl-p-methylphenol; 3,5-Di-tert-butyl-4-hydroxytoluene; 4-Methyl-2,6-di-tert-butylphenol; Butylated hydroxytoluene; Butylhydroxytoluene, p-Cresol 2,6-di-tert-butyl-
CAS No.: 128-37-0, (126-37-0) **
EINECS: EC Number: 204-881-4
Molecular Weight: 220.35
Chemical Formula: C15H24O
Relevant uses and uses advised against (if any): Industrial use only.
Supplier: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute, oral Category 4, H302
Skin corrosion/irritation Category 2, H315
Serious eye damage/eye irritation Category 2A, H319
Specific target organ toxicity, single exposure; Respiratory tract irritation Category 3, H335
Hazardous to the aquatic environment, long-term hazard Category 1, H410

Hazard statements:
H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H410: Very Toxic to aquatic life with long lasting effects.

Precautionary statements:
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P264 Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P314: Get medical advice/attention if you feel unwell.
P330: Rinse mouth.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P362: Take off contaminated clothing and wash before reuse.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P337+P313: If eye irritation persists: Get medical advice/ attention.
P391: Collect spillage.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/regional/national/international regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
Xi Irritant
Xn Harmful
N Dangerous for the environment
Risk Phrases:
R22 - Harmful if swallowed
R36/37/38 - Irritating to eyes, respiratory system and skin
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Flammability of the Product: May be combustible at high temperature.
Auto-Ignition Temperature: 470C (878F).
Flash Points: CLOSED CUP: 118.3C (244.9F).
Products of Combustion: Carbon dioxide, Carbon monoxide, Hydrogen Chlorides, Fumes.
Fire: Flammable in the presence of open flame.
Explosion: Slightly explosive in presence of heat.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes. On decomposition it may emit hydrogen chloride. Containers may explode on heating.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Ensure adequate ventilation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Contain spilled material. Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Avoid touching the spilled material. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Do not contaminate the environment.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, reducing agents, metals, and acids.

Airborne Exposure Limits: Although up to 10mg/m3 is prescribed in some regulations, better limit it to 2mg/m3.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: It is a white solid.
Odor: It has faint typical odor.
Odor threshold: Not available.
pH: Not available.
Relative density: 1.03 - 1.05 g/mL at 20C.
Boiling Point: 265C, 509F
Melting Point: 70 C, 158F
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: It is slightly soluble in water.
Viscosity: Not available.
Molecular Weight: 220.2
Molecular Formula: C15H24O

Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits Carbon dioxide, Carbon monoxide, Hydrogen Chlorides & Fumes.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, reducing agents metals and acids.
Conditions to Avoid: Incompatibles and moisture.
Phenols are incompatible with strong reducing substances such as hydrides, nitrides, alkali metals, and sulfides.
Avoid use of aluminum, copper and brass alloys in storage and process equipment.
Heat is generated by the acid-base reaction between phenols and bases.
Phenols are sulfonated very readily (for example, by concentrated sulfuric acid at room temperature), these reactions generate heat.
Phenols are nitrated very rapidly, even by dilute nitric acid.
Nitrated phenols often explode when heated. Many of them form metal salts that tend toward detonation by rather mild shock.
Segregate from oleum, nitric acid and chlorosulfonic acid.

Toxicity data
ORL-RAT LD50 890 mg kg-1
ORL-MAM LD50 650 mg kg-1
Carcinogenic Effects: Not know as carcinogen.
Mutagenic Effects: Mutagenic for bacteria and/or yeast. Mutagenic for mammalian somatic cells. May cause damage to the following organs: blood, liver, central nervous system (CNS).
Teratogenic Effects: May cause adverse reproductive effects and birth defects.
Developmental Toxicity: Adverse reproductive effects have occurred in experimental animals.

Toxicity to fish: LC50 - Oryzias latipes - 5,3 mg/l - 48 h
Toxicity to daphnia and other aquatic invertebrates: static test EC50 - Daphnia magna (Water flea) - 0,48 mg/l - 48 h
Toxicity to bacteria: Growth inhibition EC50 - Protozoa - 1,7 mg/l - 24 h
Environmental Toxicity: Low aquatic toxicity is expected.
Persistence and Degradability: No information available.
Mobility: No information available.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state, and local requirements.

USA DOT & ADR/RID Europe Classification:
UN number: 3077
UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2,6-di-tert-Butyl-p-cresol)
Transport hazard class(es): 9
Packaging group: III
Canada TDG Classification:
UN number: 3077
UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2,6-di-tert-Butyl-p-cresol)
Transport hazard class(es): 9
Packaging group: III
IMDG & IATA
UN number: 3077
UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2,6-di-tert-Butyl-p-cresol)
Transport hazard class(es): 9
Packaging group: III.

USA:
SARA 302 Components : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components : No chemicals are reportable under Section 313.
SARA 311/312 Hazards: Immediate Health Hazard. See section 2.
California prop. 65:Contains no chemical subject to California Prop 65.

European Labeling in Accordance with EC Directives:
H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H410: Very Toxic to aquatic life with long lasting effects.

DISCLAIMER: The information and recommendations set forth herein are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30

USA, Canada, Mexico and other American
neighbouring buyers may
e-mail: us@mubychem.com
Call toll-free 1-877-682-9243 (1-877-MUBYCHEM)

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