Glacial Acetic Acid BP Ph Eur USP NF FCC Food Grade and 0.1N, 1N (Normal) or 0.1 & 1M (Molar) etc Analytical Reagent Grade Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Glacial Acetic Acid Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc.

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Glacial Acetic Acid: CAS Number: 64-19-7, EINECS EC Number: 200-580-7, Molecular Formula: CH3CO2H , Molecular Weight: 60.05 HS Code ---**

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Dilute Acetic Acid

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MSDS Sheet of Glacial Acetic Acid Manufacturers

Spanish Ácido acético glacial Fabricantes

Glacial Acetic Acid
0.1N, 1N (Normal) or 0.1 & 1M (Molar) etc Analytical Reagent Grade, Commercial Pure, BP Ph eur USP NF & FCC Food Grade Suppliers
Glacial Acetic Acid

Acetic systematically named ethanoic acid with the chemical formula CH3COOH. It is a colourless liquid that when undiluted is also called glacial acetic acid. Vinegar is roughly 3–9% acetic acid by volume, making acetic acid the main component of vinegar apart from water.

We offer all grades of Acetic Acid including 0.1 N or 1N (Normal), 0.1 N or 1N (Normal) or 0.1 & 1M (Molar) etc Analytical Reagent (Normal) or 0.1 & 1M (Molar) etc Laboratory Analytical Reagent Grade products.

Glacial Acetic Acid BP Ph Eur Grade
Ph Eur -- C2H4O2 -- 60.1 -- CAS 64-19-7

DEFINITION
Content:  99.0 per cent m/m to 100.5 per cent m/m.

CHARACTERS
Appearance:  Crystalline mass or clear, colourless, volatile liquid.
Solubility:  Miscible with water, with ethanol (96 per cent) and with methylene chloride.

IDENTIFICATION
A. A 100 g/L solution is strongly acid (2.2.4).
B. To 0.03 mL add 3 mL of water R and neutralise with dilute sodium hydroxide  solution R. The solution gives reaction (b) of acetates (2.3.1).

TESTS
Solution S: Dilute 20 mL to 100 mL with distilled water.
Appearance:  The substance to be examined is clear and colourless.
Freezing point:  Minimum 14.8 °C.
Reducing substances: To 5.0 mL add 10.0 mL of water and mix. To 5.0 mL of this solution add 6 mL of  sulfuric acid, cool and add 2.0 mL of 0.0167 M potassium dichromate. Allow to  stand for 1 min and add 25 mL of water and 1 mL of a freshly prepared 100 g/L  solution of potassium iodide. Titrate with 0.1 M sodium thiosulfate, using 1.0 mL of  starch solution as indicator. Not less than 1.0 mL of 0.1 M sodium thiosulfate  solution is required.
Chlorides: Maximum 25 mg/L.
Sulfates: Maximum 50 mg/L, determined on solution S.
Iron: Maximum 5 ppm.
Heavy metals:  Maximum 5 ppm.
Residue on evaporation: Maximum 0.01 per cent.
Evaporate 20 g to dryness on a water-bath and dry at 100-105 °C. The residue  weighs a maximum of 2.0 mg.
ASSAY: Weigh accurately a conical flask with a ground-glass stopper containing 25 mL of  water R. Add 1.0 mL of the substance to be examined and weigh again accurately.  Add 0.5 mL of phenolphthalein solution R and titrate with 1 M sodium hydroxide.
1 mL of 1 M sodium hydroxide is equivalent to 60.1 mg of C2H4O2.


Acetic Acid, Glacial FCC Food Grade
C2H4O2 Formula weight 60.05
INS: 260 CAS 64-19-7
FEMA: 2006

DESCRIPTION
Acetic Acid, Glacial, occurs as a clear, colorless liquid. It boils at about 118°. When well diluted with water (e.g., 1:100), it has a vinegar odor and taste. It is miscible with water, with alcohol, and with glycerin.
Function: Acidifier; flavoring agent.

REQUIREMENTS
Identification: A 1:3 aqueous solution gives positive tests for Acetate.
Assay: Not less than 99.5% and not more than 100.5%, by weight, of C2H4O2.
Lead: Not more than 0.5 mg/kg.
Nonvolatile Residue: Not more than 0.005%.
Readily Oxidizable Substances: Passes test.
Solidification Point: Not cooler than 15.6C.


Glacial Acetic Acid USP Grade Specifications:
C2H4O2 --- 60.05
Acetic acid CAS 64-19-7

DEFINITION
Glacial Acetic Acid contains NLT 99.5% and NMT 100.5%, by weight, of C2H4O2.

IDENTIFICATION
Identification Tests—General, Acetate: Meets the requirements
Limit of Nonvolatile Residue: Evaporate 20 mL in a tared dish, and dry at 105° for 1 h: the weight of the residue does not exceed 1.0 mg.
Chloride and Sulfate, Chloride:
Sample solution: Dilute 1.0 mL with 20 mL of water.
Analysis: Add 5 drops of silver nitrate TS.
Acceptance criteria: No opalescence is produced.
Chloride and Sulfate, Sulfate:
Sample solution: Dilute 1.0 mL with 10 mL of water.
Analysis: Add 1 mL of barium chloride TS.
Acceptance criteria: No turbidity is produced.
Readily Oxidizable Substances:
Sample solution: Dilute 2.0 mL in a glass-stoppered vessel with 10 mL of water.
Analysis: Add 0.10 mL of 0.10 N potassium permanganate.
Acceptance criteria: The pink color is not changed to brown within 2 h.
Congealing Temperature: NLT 15.6C


Acetic Acid Solution NF Grade:
Acetic acid;
Acetic acid CAS 64-19-7

DEFINITION
Acetic Acid is a solution containing NLT 36.0% and NMT 37.0%, by weight, of C2H4O2.

IDENTIFICATION
A. Identification Tests—General, Acetate: Meets the requirements

Nonvolatile Residue:
Analysis: Evaporate 20 mL in a tared porcelain dish on a steam bath, and dry at 105C for 1 h.
Acceptance criteria: The weight of the residue does not exceed 1.0 mg (0.005%).
Chloride:
Sample solution: Acetic acid (1 in 10) in water
Analysis: To 10 mL of the Sample solution add 5 drops of silver nitrate TS.
Acceptance criteria: No opalescence is produced.
Sulfate:
Sample solution: Acetic acid (1 in 10) in water.
Analysis: To 10 mL of the Sample solution add 5 drops of barium chloride TS.
Acceptance criteria: No turbidity is produced.
Readily Oxidizable Substances:
Analysis: Dilute 4.0 mL in a glass-stoppered vessel with 20 mL of water, and add 0.30 mL of 0.10 N potassium permanganate.
Acceptance criteria: The pink color is not changed to brown at once, and the liquid does not become entirely brown or free from a pink tint in less than 30s.

Acetic Acid, Glacial Analytical Reagent Grade:
CH3COOH --- Formula Weight 60.05
CAS Number 64-19-7

REQUIREMENTS
Assay: 99.7% CH3COOH

MAXIMUM ALLOWABLE
Color (APHA): 10
Dilution test: Passes test
Residue after evaporation: 0.001%
Acetic anhydride [(CH3CO)2O]: 0.01%
Chloride (Cl): 1 ppm
Sulfate (SO4): 1 ppm
Heavy metals (as Pb): 0.5 ppm
Iron (Fe): 0.2 ppm
Substances reducing dichromate: Passes test
Substances reducing permanganate: Passes test
Titrable base: 0.0004 meq/g.


Acetic Acid, Ultratrace Analytical Reagent Grade:
(suitable for use in ultratrace elemental analysis)
CH3COOH --- Formula Weight 60.05
CAS Number 64-19-7

NOTE. Reagent must be packaged in a preleached Teflon bottle and used in a clean environment to maintain purity

REQUIREMENTS
Appearance: Clear
Assay: 90% minimum

MAXIMUM ALLOWABLE
Chloride (Cl): 1 ppm
Sulfate (SO4): 1 ppm
Aluminum (Al): 1 ppb
Barium (Ba): 1 ppb
Boron (B): 5 ppb
Cadmium (Cd): 1 ppb
Calcium (Ca): 1 ppb
Chromium (Cr): 1 ppb
Cobalt (Co): 1 ppb
Copper (Cu): 1 ppb
Iron (Fe): 5 ppb
Lead (Pb): 1 ppb
Lithium (Li): 1 ppb
Magnesium (Mg): 1 ppb
Manganese (Mn): 1 ppb
Molybdenum (Mo): 1 ppb
Mercury (Hg): 1 ppb
Potassium (K): 1 ppb
Silicon (Si): 5 ppb
Sodium (Na): 5 ppb
Strontium (Sr): 1 ppb
Tin (Sn): 1 ppb
Titanium (Ti): 1 ppb
Vanadium (V): 1 ppb
Zinc (Zn): 1 ppb
Zirconium (Zr): 1 ppb.

For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.

We manufacture and supply 0.1N, 1N (Normal) or 0.1 & 1M (Molar) etc Laboratory Analytical Reagent Grade products like:

Acetic Acid

Acetyl Chloride

Hydrochloric Acid

Nitric Acid

Phosphoric Acid

Sulfuric Acid

Potassium Hydroxide

Sodium Hydroxide

Calcium Acetate

Magnesium Acetate

Potassium Acetate

Sodium Acetate

Sodium Diacetate

Strontium Acetate Carbonate Fluoride Nitrate Sulfate

Manufacturers:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) 91-22-23770100, 23726950
Current Date Time in India GMT+5:30

e-mail: info@mubychem.com

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neighbouring buyers may
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Last 26 August, 2022

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Glacial Acetic Acid SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet
22-Oct-20

Section 1 - Chemical Product and Company Identification

Product Name & Other Names: Glacial Acetic Acid or Acetic Acid or Ethanoic acid or Ethylic acid or Methanecarboxylic acid or Vinegar.
CAS#: 64-19-7
EINECS EC Number: 200-580-7
Molecular Formula
: CH3COOH
Molecular Weight
: 60.05
Relevant uses and uses advised against (if any)
: Industrial Manufacturing.
Suppliers: As per letterhead.

Section 2 - Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Flammable liquids (Category 3) H227
Skin corrosion/irritation (Category 1A, B, C) H314
Acute aquatic toxicity (Category 3) H402

Labeling according to GHS & Regulation (EC) No 1272/2008

GHS Label Elements
Combustible Liquid
Combustible Liquid

GHS Label Elements
Corrosive
Corrosive

Signal Words (GHS-USA): Danger

Hazard statements (GHS-USA):
H227: Combustible liquid.
H314: Causes severe skin burns and eye damage.
H402: Harmful to aquatic life.

Precautionary statements (GHS-USA):
P210: Keep away from heat, sparks, open flames, hot surfaces. - No smoking.
P260: Do not breathe mist, vapors, spray.
P264: Wash exposed skin thoroughly after handling.
P280: Wear protective clothing, protective gloves, eye protection, face protection.
P301+P330+P331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303+P361+P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340: IF INHALED: remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P337+ P313: If eye irritation persists: Get medical advice/ attention.
P370+P378: In case of fire: Use carbon dioxide (CO2), powder, alcohol-resistant foam for extinction.
P403+P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P273: Avoid release to the environment.
P501: Dispose of contents/container to comply with local, state, and federal regulations.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
C = Corrosive
Risk Phrases:
R10 = Flammable.
R35 = Causes severe burns.
R41 Risk of serious damage to eyes.
R52 Harmful to aquatic organisms.

Section 3 - Composition/Information on Ingredients

Product Name & Other Names: Glacial Acetic Acid or Acetic Acid or Ethanoic acid or Ethylic acid or Methanecarboxylic acid or Vinegar.
CAS#: 64-19-7
EINECS EC Number: 200-580-7
Percent
: 99-100% on dry basis. Dilution is always with water.

Section 4 - First Aid Measures

Always consult a physician after the first aid is given.

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Do NOT allow victim to rub or keep eyes closed.
Skin: Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion: Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Flammability: Flammable. Explosive in presence of oxidizing materials.
Flash Point: 40C 104F
Auto Ignition Temperature: 463C 865F
Extinguishing Media: Use DRY chemical powder, alcohol foam, water spray or fog. Cool containing vessels with water jet to prevent pressure build-up, auto-ignition, or explosion.

Section 6 - Accidental Release Measures

Personal precautions, protective equipment, and emergency procedures: Ventilate area of leak or spill. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law. Remove all ignition sources and ventilate area. Neutralize with sodium bicarbonate or calcium hydroxide or dry soda ash or calcium carbonate and deposit in a sealed bag or container. Use water spray to dilute spill to a non-flammable mixture. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation.

Section 7 - Handling and Storage

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, strong alkalis, and metals. Store protected from heat and flames.

Section 8 - Exposure Controls, Personal Protection

Airborne Exposure Limits: Airborne Exposure Limits:
OSHA Permissible Exposure Limit (PEL): 10 ppm (TWA).
ACGIH Threshold Limit Value (TLV): 10 ppm (TWA); 15 ppm (STEL).
NIOSH 10ppm TWA; 25 mg/m3 TWA 50ppm IDLH
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area of Acetic acid.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Section 9 - Physical and Chemical Properties

Appearance: Clear Liquid
Odor: Vinegar odor
Odor threshold: Not available.
pH: 2 for 1% solution, 2.4 (1.0M solution)
Relative density: around 1.05
Boiling Point: 118C (244.5F)
Melting Point:
16.6C (61.9F).
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Soluble in water
Viscosity: Not available.
Molecular Formula: C2H4O2
Molecular Weight: 60.05

Section 10 - Stability and Reactivity

Chemical Stability: Stable under normal temperatures and pressures. It is hygroscopic.
Conditions to Avoid: Incompatible materials, dust generation, moisture, exposure to heat, spark, moist air or water.
Incompatibilities with Other Materials: Oxidizing agents, strong alkalis and metals.
Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information

Acute oral toxicity (LD50): 3310 mg/kg [Rat].
Acute dermal toxicity (LD50): 1060 mg/kg [Rabbit].
Acute toxicity of the vapor (LC50): 5620 1 hours [Mouse].
LC50 Inhalation - rat - 4 h - 11.4 mg/l 4 hours
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

Section 12 - Ecological Information

Persistence and Degradability: The material will readily biodegrade.
Mobility: Mobile due to water solubility
Bioaccumulation/ Accumulation: Unlikely to bioaccumulate
Results of PBT and vPvB assessment: No data available for assessment.
Toxicity:
(LC50): 423 mg/l 24 hours [Fish (Goldfish)]. 88 ppm 96 hours [Fish (fathead minnow)]. 75 ppm 96 hours [Fish (bluegill sunfish)]. >100 ppm - 96 hours [Daphnia].

Section 13 - Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container of Acetic acid and unused contents in accordance with local requirements.

Section 14 - Transport Information

DOT USA and ADR/RID Europe
UN number: 2789
Class: 8 (3)
Packing group: II
Proper shipping name: Acetic acid, glacial
Reportable Quantity (RQ): 5000 lbs
Marine pollutant: No
Poison Inhalation Hazard: No
IMDG
UN number: 2789
Class: 8 (3)
Packing group: II
Proper shipping name: Acetic acid, glacial
Reportable Quantity (RQ): 5000 lbs
Marine pollutant: No
IATA
UN number: 2789
Class: 8 (3)
Packing group: II
Proper shipping name: Acetic acid, glacial.

Section 15 - Regulatory Information

USA:
OSHA
: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
Section 313: No chemicals are reportable under Section 313.
SARA 311/312 Hazards: Acute Health Hazard, Chronic Health Hazard. See section 2.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

Section 16 - Additional Information

European Labeling in Accordance with EC Directives:
H227 = Combustible liquid.
H314 = Causes severe skin burns and eye damage.
H402 = Harmful to aquatic life.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
C = Corrosive
Risk Phrases:
R10 = Flammable.
R35 = Causes severe burns.
R41 Risk of serious damage to eyes.
R52 Harmful to aquatic organisms.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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