Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance & Flavor chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc. The products are offered as per required specifications and in correct shape and size in mm or meshs or microns as specified by the buyer. The participating units have one or more accreditations like FDA - GMP approval; ISO-9001:2008 Certified; "REACH" Pre-registered; ISO-14001, ISO-22000:2005, FSSC 22000; ISO OHSAS 18001; Kosher Certified; Halal Certified; HACCP, FSSAI. We offer Commercial Pure & IP BP USP FCC Food Grade ACS AR Analytical Reagent Grades of Chemicals
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Fumaric Acid USP NF, Pure Reagent FCC Food Grade Manufacturers
Fumaric Acid CAS Number 110-17-8, EINECS EC Number 203-743-0, HS Code ---**; Molecular Weight 116.07, Molecular Formula: HOOCCH=CHCOOH
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MSDS Sheet of Fumaric Acid Manufacturers
Fumaric acid or trans-butenedioic acid is the chemical compound with the formula HO2CCH=CHCO2H. This white crystalline compound is one of two isomeric unsaturated dicarboxylic acids, the other being maleic acid. Fumaric acid has a fruit-like taste. As a food additive, it is used as an acidity regulator and is denoted by the E number E297. It is generally used in beverages and baking powders for which requirements are placed on purity. We offer Commercial pure, USP NF and FCC Food grade.
Fumaric Acid USP NF
C4H4O4 --- 116.07
2-Butenedioic acid, E-.
Fumaric acid [110-17-8].
Fumaric Acid contains not less than 99.5 percent and not more than 100.5 percent of C4H4O4, calculated on the anhydrous basis.
Identification: Dissolve about 10 mg in 25 mL of water, and to this solution add 1 mL of a solution prepared by mixing 20 mL of copper sulfate solution (1 in 5) and 8 mL of pyridine: a precipitate is formed in the blue solution within 1 minute.
Residue: not more than 0.1%.
Heavy metals: 0.001%.
Limit of maleic acid: To pass the test. Not more than 0.1% of maleic acid is found.
Organic volatile impurities: meets the requirements.
Assay: Transfer about 1 g of Fumaric Acid, accurately weighed, to a conical flask, add 50 mL of methanol, and warm gently on a steam bath to effect solution. Cool, add phenolphthalein TS, and titrate with 0.5 N sodium hydroxide VS to the first appearance of a pink color that persists for not less than 30 seconds. Perform a blank titration, and make any necessary correction. Each mL of 0.5 N sodium hydroxide is equivalent to 29.02 mg of C4H4O4.
Fumaric Acid FCC Food Grade
(E)-Butenedioic Acid; trans-1,2-Ethylenedicarboxylic Acid
C4H4O4 Formula weight 116.07
INS: 297 CAS: [110-17-8]
Fumaric Acid occurs as white granules or as a crystalline powder. A 1:30 aqueous solution has a pH of 2.0 to 2.5. It is soluble in alcohol, slightly soluble in water and in ether, and very slightly soluble in chloroform.
Function: Acidifier; flavoring agent.
Identification: The infrared absorption spectrum.
Assay: Not less than 99.5% and not more than 100.5% of C4H4O4, calculated on the anhydrous basis.
Lead: Not more than 2 mg/kg.
Maleic Acid: Not more than 0.1%.
Residue on Ignition: Not more than 0.1%.
Water: Not more than 0.5%.
For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.
We also offer Coated or Encapsulated Fumaric Acid for breads, tortilas and other food products.
Ambernath Mumbai, Ankleshwar Gujarat, India
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Last 14 August, 2017
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Fumaric Acid GHS SDS, MSDS Sheet, Material Safety Data Sheet
1. Product Identification
Synonyms: 2-Butenedioic acid; Boletic acid
CAS No.: 110-17-8
EINICS EC-No.: 203-743-0
Molecular Weight: 116.07
Chemical Formula: HOOCCH=CHCOOH
Recommended usage: Industrial Manufacturing.
Suppliers: As per letterhead.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Serious eye damage/eye irritation Category 2A
Labeling according GHS & Regulation (EC) No 1272/2008
GHS Label Elements
Signal Words: Warning
H319: Causes serious eye irritation.
P264: Wash skin thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P305+ P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/ attention.
Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Symbol: Xi Irritant.
Risk Phrases: R36 – Irritating to eyes.
HMIS (Perceived): Health hazard: 1, Flammability: 1, Physical hazards: 0
NFPA (Perceived): Health hazard: 2, Fire: 1, Reactivity Hazard: 0
3. Composition/Information on Ingredients
Ingredient: Fumaric Acid
EINICS EC-No.: 203-743-0
CAS No.: 110-17-8
4. First Aid Measures
Always get medical attention after the first aid is over.
Inhalation: If Fumaric Acid is inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen and get medical attention immediately.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing and shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
5. Fire Fighting Measures
Fire: As with most organic solids, fire is possible at elevated temperatures or by contact with an ignition source.
Explosion: Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard.
Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.
6. Accidental Release Measures
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill: Corrosive solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources.
7. Handling and Storage
Keep Fumaric Acid in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Containers of Fumaric Acid may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product. Avoid dust formation and control ignition sources. Employ grounding, venting and explosion relief provisions in accord with accepted engineering practices in any process capable of generating dust and/or static electricity. Empty only into inert or non-flammable atmosphere. Emptying contents into a non-inert atmosphere where flammable vapors may be present could cause a flash fire or explosion due to electrostatic discharge.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
9. Physical and Chemical Properties
Appearance: Fumaric Acid is white to off-white crystals or powder.
Odor: Faint odor.
Solubility: Soluble in water.
Density: 1,63 g/cm3 at 20 °C
pH: Approximately 2, Acidic.
% Volatile by volume @ 21C (70F): 0
Molecular Weight: 116.07
Chemical Formula: HOOCCH=CHCOOH
Melting Point: 298 - 300°C - lit.
10. Stability and Reactivity
Stability: Fumaric Acid is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Excessive heat, Strong oxidizers.
Conditions to Avoid: Heat, dusting and incompatibles.
11. Toxicological Information
LD50 Oral - Rat - female: 9.300 mg/kg
LD50 Dermal - Rabbit - female: 20.000 mg/kg
LD50 Intraperitoneal - Mouse: 100 mg/kg
------------------------- NTP Carcinogen---
Ingredient -------------- Known -- Anticipated -- IARC Category
------------------------- -------- ----------- -------------
Fumaric Acid (110-16-7) --- No ----- No -------- -- None
12. Ecological Information Toxicity
Toxicity to fish daphnia and bacteria:
Toxicity to fish mortality: Danio rerio (zebra fish) - 245 mg/l - 48 h
Toxicity to fish semi-static test LC50: Danio rerio (zebra fish) - > 100 mg/l - 96 h
Toxicity to daphnia and other aquatic invertebrates Immobilization EC50: Daphnia magna (Water flea) - 212 mg/l - 48 h
Toxicity to algae Growth inhibition EC50: Pseudokirchneriella subcapitata - > 100 mg/l - 72 h
Toxicity to bacteria Respiration inhibition EC50: activated sludge - > 300 mg/l - 3 h
Bioaccumulative potential: No data available
Mobility in soil: No data available
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused Fumaric Acid in accordance with legal requirements.
14. Transport Information
DOT: Not regulated
TDG: Not regulated
IATA: Not regulated
IMDG/IMO: Not regulated
15. Regulatory Information
Comprehensive Environmental Response and Liability Act (CERCLA): This material is not subject to any special reporting under the requirements of the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA).
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
The reportable quantity (RQ) for this material is 5000 pounds. If appropriate, immediately report to the National Response Center (800/424-8802) as required by U.S.Federal Law. Also contact appropriate state and local regulatory agencies.
Toxic Substance Control Act (TSCA): All components of this product are listed on the TSCA inventory list.
SARA Section 311/312 (40 CFR 370) Hazard Categories: Acute Health Hazard, Chronic Health Hazard.
SARA Section 313 (40 CFR 372) Hazard Categories: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
Clean Water Act: None of the chemicals in this product are listed as Hazardous Substances under the CWA.
Clean Air Act: None of the chemicals in this product are listed as Hazardous Substances under the CCA.
California Prop 65: This product contains no chemical known by the State of California to cause cancer, birth defects or other reproductive harm.
Label elements according to Directive 67/548/EEC
Risk Phrases: R36 – Irritating to eyes.
S16 - Keep away from sources of ignition - No smoking.
S3 - Keep in a cool place.
S9 - Keep container in a well-ventilated place.
S13 - Keep away from food, drink and animal feeding stuffs
S24 - Avoid contact with skin.
S25 - Avoid contact with eyes.
S36 - Wear suitable protective clothing.
S37 - Wear suitable gloves
S29 - Do not empty into drains.
S45 - In case of accident or if you feel unwell, seek medical advice immediately.
S56 - Dispose of this material and its container to hazardous or special waste collection point.
16. Other Information
Our company provides this Fumaric Acid MSDS information sheet contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.