Methacrylic acid or MAA or 2-Methacrylic acid or 2-Methylpropenoic acid Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Methacrylic acid or 2-Methylacrylic acid, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc.

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Methacrylic acid or 2-Methylacrylic acid or MAA or 2-Methacrylic acid or 2-Methylpropenoic acid: CAS Number: 79-41-4, EINECS EC Number: 201-204-4, Molecular Formula: C4H6O2 or H2C=C(CH3)COOH, Molecular Weight: 86.09, HS Code 2916 13 00

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Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Methacrylic acid or 2-Methylacrylic acid or MAA or 2-Methacrylic acid or 2-Methylpropenoic acid.

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SDS MSDS Sheet of Methacrylic acid or MAA or 2-Methacrylic acid or 2-Methylpropenoic acid Manufacturers

Methacrylic acid
2-Methylacrylic acid or MAA or 2-Methacrylic acid or 2-Methylpropenoic acid Pure Suppliers
Methacrylic acid

Methacrylic acid or MAA or 2-Methylpropenoic acid is an organic compound. This colorless, viscous liquid has an acrid unpleasant odor. Methacrylic acid is used in some nail primers to help acrylic nails adhere to the nail plate.

General Properties and Specifications of Methacrylic acid or 2-Methylacrylic acid or MAA or 2-Methacrylic acid or 2-Methylpropenoic acid:
Appearance: Colorless viscous liquid.
Color (apha): 30 maximum.
Odor: Acrid unpleasant odor.
Assay: 99% minimum.
Water (by KF): 0.3% minimum.
Inhibitors (mehq): 230~270 ppm.
Relative density: about 1.01 to 1.02
Melting point: 14 C to 15C literature.
Boiling point: 163C literature.
Flash point: 76C.
Auto-ignition temperature: 400C.
Solubility: Soluble in water. Soluble in chloroform. Miscible with ethanol, ether.

We also manufacture and supply as under:

Acrylic Acid

Acrylamide

n-Butyl Methacrylate

Ethyl Acrylate

2 Ethylhexyl Acrylate

2-Hydroxyethyl Methacrylate

Methyl Acrylate

Methacrylic Acid

Methyl Methacrylate.

Manufacturers:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30

e-mail: info@mubychem.com

USA, Canada, Mexico and other American
neighbouring buyers may
e-mail: us@mubychem.com
Call toll-free 1-844-682-9243 (1-844-MUBYCHEM)

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Copyright and Usual Disclaimer is Applicable.
Last 27 August, 2022

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Methacrylic acid or 2-Methylacrylic acid or MAA or 2-Methacrylic acid or 2-Methylpropenoic acid SDS GHS, Material Safety Data Sheet
MSDS GHS, Material Safety Data Sheet
17-Mar-21

1. Product Identification

Product Name & Other Names: Methacrylic acid or 2-Methylacrylic acid or MAA or 2-Methacrylic acid or 2-Methylpropenoic acid.
CAS No.: 79-41-4
EINECS EC No.: 201-204-4
Molecular Formula: C4H6O2 or H2C=C(CH3)COOH
Molecular Weight: 86.09
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP)
:

Flammable liquids (Category 4) H227
Acute toxicity, Oral (Category 4) H302
Acute toxicity, Dermal (Category 3) H311
Skin corrosion (Sub-category 1B) H314
Acute toxicity, Inhalation (Category 4), H332
Specific target organ toxicity - single exposure (Category 3), H335
Long-term (chronic) aquatic hazard (Category 3) H412

Labeling according Regulation (EC) No 1272/2008

GHS Label Elements
Toxic
Toxic

GHS Label Elements
Corrosive
Corrosive

Signal Words: Danger

Hazard statements:
H227: Combustible liquid.
H302 + H332 Harmful if swallowed or if inhaled.
H311: Toxic in contact with skin.
H314: Causes severe skin burns and eye damage.
H335 May cause respiratory irritation.

Precautionary statements:
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/light/…/equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P330: Rinse mouth.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+352: IF ON SKIN: Wash with soap and water.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P403+233+235: Store in a well-ventilated place. Keep container tightly closed. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to authorized agents only.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard symbols:
T = Toxic
C= Corrosive.
R-phrases:
R7 May cause fire.
R20/22 Harmful by inhalation and if swallowed.
R24 Toxic in contact with skin.
R35 Causes severe burns
R41 Risk of serious damage to eyes.
R37 Irritating to respiratory system.

3. Composition/Information on Ingredients

Product Name & Other Names: Methacrylic acid or 2-Methylacrylic acid or MAA or 2-Methacrylic acid or 2-Methylpropenoic acid.
CAS No.: 79-41-4
EINECS EC No.: 201-204-4

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

5. Fire Fighting Measures

Flammability of the Product: Combustible.
Flash Points: 76C.
Products of Combustion: Carbon oxides and fumes. Flash back possible over considerable distance., Container explosion may occur under fire conditions. Vapors may form explosive mixture with air.
Fire Extinguishing Media: Use water spray or fog. Flammable liquid and vapor. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas. Never direct a water jet in the container to prevent any splashing of the product which could cause spreading of the fire. Cool containing vessels with water jet to prevent pressure build-up, auto-ignition, or explosion.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

6. Accidental Release Measures

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental  precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep up and remove to an approved disposal container.
Small Spill: Avoid mist formation. Avoid breathing mist. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Remove all sources of ignition. Provide proper ventilation. Absorb the material on a porous, inert material such as earth, sand, or vermiculite. If solid/powder - carefully sweep up the material without causing dust. Dispose of in accordance with local regulations.

7. Handling and Storage

Precautions for safe handling: Keep away from sources of ignition - No smoking. Take measures to prevent the build-up of electrostatic charge. Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, strong acids, strong bases, amines, peroxides. Keep the product in its original container well sealed, in a dry and ventilated area, away from potential sources of ignition and protected from light. Store away from oxidizing agents.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits:
USA ACGIH TLV: TWA: 20 ppm; OSHA PEL: (Vacated) TWA: 20 ppm.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: Colorless viscous liquid.
Odor: Acrid unpleasant odor.
Odor threshold: Not available.
pH: Not available.
Relative Density: about 1.01 to 1.02
Boiling Point
: 218C to 222C literature.
Melting Point: 163C literature.
Flash point: 76C.
Auto-ignition temperature: 400C.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor Pressure (mm Hg): Not available.
Vapor Density (Air=1): Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Soluble in water. Soluble in chloroform. Miscible with ethanol, ether.
Viscosity: Not available.
Molecular Formula: C4H6O2 or H2C=C(CH3)COOH
Molecular Weight: 86.09

10. Stability and Reactivity

Stability: Stable under ordinary conditions of use and storage. Vapour/air-mixtures are explosive at intense warming.
Risk of explosion with furfuryl alcohol, hydrochloric acid. Violent reactions possible with: Amines, azides, Aldehydes, Acid anhydrides, Acid chlorides, alkaline earth hydroxides, alkali hydroxides, bases, Ether, Heavy metal salts, Heavy metals, Ketones, metallic hydroxides, mineral acids, Nitric acid, Nitro compounds, nitrates, nitrites, Reducing agents, Strong oxidizing agents, Strong acids.
Hazardous Decomposition Products: It emits Carbon oxides and fumes.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, strong acids, strong bases, amines, peroxides.
Conditions to Avoid: Incompatibles, Air, Moisture, Heat, flames, and sparks & light.

11. Toxicological Information

LD50 Oral Rat: 1320 mg/kg.
LD50 Dermal Rabbit: 500 to 1000 mg/kg.
LC50 Inhalation Rat: 7.1 mg/l; 4 h ; dust/mist.
Carcinogenicity: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology: No information found
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: No information found
Neurotoxicity: No information found.

12. Ecological Information

Toxicity to fish: flow-through test LC50 - Oncorhynchus mykiss (rainbow trout) - 85 mg/l - 96 h.
Toxicity to daphnia and other aquatic invertebrates: flow-through test EC50 - Daphnia magna (Water flea) - > 130 mg/l - 48 h.
Persistence and Degradability: Persistence is unlikely due to its water solubility.
Mobility: Will likely be mobile in the environment due to its water solubility.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state, and local requirements.

14. Transport Information

DOT USA, TDG Canada & ADR/RID Europe:
UN Number: UN 2831
Shipping Name: METHACRYLIC ACID, STABILIZED
Hazard Class: 8; Packing Group: II.
IMDG/IMO:
UN Number: UN 2831
Shipping Name: METHACRYLIC ACID, STABILIZED
Hazard Class: 8; Packing Group: II.
IATA/ICAO:
UN Number: UN 2831
Shipping Name: METHACRYLIC ACID, STABILIZED
Hazard Class: 8; Packing Group: II.

15. Regulatory Information

USA:
SARA 313 Components
: No chemicals are reportable under Section 313.
SARA 311/312 Hazards: Fire Hazard: Immediate Health Hazard: Acute Yes, Chronic Health Hazard.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

16. Other Information

European Labeling in Accordance with EC Directives:
H227: Combustible liquid.
H302 + H332 Harmful if swallowed or if inhaled.
H311: Toxic in contact with skin.
H314: Causes severe skin burns and eye damage.
H335 May cause respiratory irritation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard symbols:
T = Toxic
C= Corrosive.
R-phrases:
R7 May cause fire.
R20/22 Harmful by inhalation and if swallowed.
R24 Toxic in contact with skin.
R35 Causes severe burns
R41 Risk of serious damage to eyes.
R37 Irritating to respiratory system.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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