Polythylene Glycol Macrogols BP Grade Manufacturers, with SDS GHS MSDS Sheet
Supplier, Manufacturer, Exporter of Polythylene Glycol, Macrogols, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc.
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Polythylene Glycol, Macrogols: CAS Number: 25322-68-3, EINECS EC Number: yyyyy, Molecular Formula: H(OCH2CH2)nOH, Molecular Weight: -----, HS Code ---**
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SDS MSDS Sheet of Polythylene Glycol, Macrogols Manufacturers
Polythylene Glycol Pure BP Grade Suppliers
Action and use: Non-ionic surfactant.
Mixtures of polymers with the general formula H-(OCH2-CH2)n-OH where n represents the average number of oxyethylene groups. The type of macrogol is defined by a number that indicates the average relative molecular mass. A suitable stabiliser may be added.
A. It complies with the test for viscosity (see Tests).
B. To 1 g in a test-tube add 0.5 ml of sulphuric acid, close the test-tube with a stopper fitted with a bent delivery tube and heat until white fumes are evolved. Collect the fumes via the delivery tube into 1 ml of mercuric chloride solution. An abundant white, crystalline precipitate is formed.
C. To 0.1 g add 0.1 g of potassium thiocyanate and 0.1 g of cobalt nitrate and mix thoroughly with a glass rod. Add 5 ml of methylene chloride R and shake. The liquid phase becomes blue.
Appearance of solution: The solution is clear and not more intensely coloured than reference solution.
Dissolve 12.5 g in water and dilute to 50 ml with the same solvent.
Acidity or alkalinity: Dissolve 5.0 g in 50 ml of carbon dioxide-free water and add 0.15 ml of bromothymol blue solution. The solution is yellow or green. Not more than 0.1 ml of 0.1 M sodium hydroxide is required to change the colour of the indicator to blue.
Viscosity: The viscosity is calculated using a density given in Table 1444.-1.
For macrogols having a relative molecular mass greater than 400, determine the viscosity on a 50 per cent m/m solution of the substance to be examined.
Freezing point: See Table 1444.-2.
Hydroxyl value: Introduce m g (see Table 1444.-3) into a dry conical flask fitted with a reflux condenser. Add 25.0 ml of phthalic anhydride solution, swirl to dissolve and boil under a reflux condenser on a hot plate for 60 min. Allow to cool. Rinse the condenser first with 25 ml of pyridine and then with 25 ml of water, add 1.5 ml of phenolphthalein solution and titrate with 1 M sodium hydroxide until a faint pink colour is obtained (n1 ml). Carry out a blank test (n2 ml).
Calculate the hydroxyl value using the expression: [56.1x(n2-n1)]m
For macrogols having a relative molecular mass greater than 1000, if the water content is more than 0.5 per cent, dry a sample of suitable mass at 100-105C for 2 h and carry out the determination of the hydroxyl value on the dried sample.
Reducing substances: Dissolve 1 g in 1 ml of a 10 g/l solution of resorcinol and warm gently if necessary. Add 2 ml of hydrochloric acid. After 5 min the solution is not more intensely coloured than reference solution.
Formaldehyde: Maximum 30 ppm.
competent authority may impose a limit of not more than 15 ppm.
Ethylene glycol and diethylene glycol: LimitıMaximum 0.4 per cent, calculated as the sum of the contents of ethylene glycol and diethylene glycol.
Ethylene oxide and dioxan: Maximum 1 ppm of ethylene oxide and 10 ppm of dioxan.
Heavy metals: Maximum 20 ppm.
Water: Maximum 2.0 per cent for macrogol with a relative molecular mass not greater than 1000 and maximum 1.0 per cent for macrogol with a relative molecular mass greater than 1000, determined on 2.00 g.
Sulphated ash: Maximum 0.2 per cent, determined on 1.0 g.
In an airtight container .
The label states:
the type of macrogol;
the content of formaldehyde.
For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.
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Last 27 August, 2022
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Macrogols SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 26-Oct-20
Section 1 - Chemical Product and Company Identification
Product Name & Other Names: Macrogols or Polyethylene glycol.
Intended Use: Industrial Manufacturing.
Suppliers: As per letterhead.
Section 2 - Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.
Labeling according to GHS USA & Regulation (EC) No 1272/2008
GHS Label Elements
Signal Word: None
Hazards not otherwise classified (HNOC):
May cause mild skin irritation.
May causes mild eye irritation.
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.
Section 3 - Composition, Information on Ingredients
Product Name & Other Names: Macrogols or Polyethylene glycol.
EINECS EC code number: --
Percent: 95-100% (Dilution is with water, as required)
Section 4 - First Aid Measures
Always consult a physician after the first aid is given.
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Do NOT allow victim to rub or keep eyes closed.
Skin: Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion: Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician: Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Flammability: Combustible but not flammable.
Extinguishing Media: Use Water, dry chemical powder, alcohol foam, water spray or fog. Cool containing vessels with water jet to prevent pressure build-up, auto-ignition, or explosion.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.
Section 6 - Accidental Release Measures
Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Use proper personal protective equipment. Restrict unprotected personnel from the area. Remove all ignition sources and ventilate area. Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Neutralize with sodium bicarbonate or calcium hydroxide, and deposit in a sealed bag or container. Use a shovel to put the material into a convenient waste disposal container. Use water spray to dilute spill to a non-flammable mixture. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.
Section 7 - Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents.
Section 8 - Exposure Controls, Personal Protection
Airborne Exposure Limits: Not available.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.
Section 9 - Physical and Chemical Properties
Appearance: Clear viscous liquid
Odor: Nearly odorless.
Odor threshold: Not available.
Relative density: about 1.1
Melting point/freezing point: Not available.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Miscible in water
Viscosity: Not available.
Molecular Formula: H(OCH2CH2)nOH
Molecular Weight: Varies.
Section 10 - Stability and Reactivity
Chemical Stability: Macrogols is stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials, exposure to heat, spark.
Incompatibilities with Other Materials: Oxidizing agents, High temperature.
Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Will not occur.
Section 11 - Toxicological Information
Acute oral toxicity (LD50): >15000 mg/kg [Rat] 4 hours.
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Teratogenic Effects: Not available.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.
Section 12 - Ecological Information
Fish toxicity (Leuciscus idus): LC50 > 10 g/l/48h
Bacteria toxicity EC0 > 12,5 g/l
Persistence and Degradability: Unlikely to persist due to water solubility.
Mobility: Likely to be mobile due to water solubility.
Bioaccumulation/ Accumulation: The material will readily biodegrade.
Results of PBT and vPvB assessment: No data available for assessment.
Section 13 - Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container of and unused contents in accordance with local requirements.
Section 14 - Transport Information
DOT USA, TDG Canada & ADR/RID Europe: Not Regulated.
IMDG/IMO: Not Regulated.
IATA: Not Regulated.
Section 15 - Regulatory Information
USA:Section 16 - Additional Information
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.