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H2O2 Hydrogen Peroxide Commercial Pure & BP USP ACS Reagent FCC Food Grade Manufacturers Suppliers, SDS GHS MSDS Sheet

Hydrogen Peroxide: CAS Number: 7722-84-1, EINECS EC Number: 231-765-0, Molecular Formula: H2O2, Molecular Weight: 34.01, HS Code ---**

For SDS MSDS Sheet Click
SDS MSDS Sheet of Hydrogen Peroxide Manufacturers

Hydrogen Peroxide
Pure H2O2
Hydrogen Peroxide

Hydrogen peroxide is a chemical compound with the formula H2O2. In its pure form, it is a pale blue, clear liquid, slightly more viscous than water. Hydrogen peroxide is the simplest peroxide (a compound with an oxygen–oxygen single bond). It is used as an oxidizer, bleaching agent and antiseptic. It is the most friendly oxidizer, environmentally and chemically. Hydrogen peroxide is unstable and slowly decomposes in the presence of base or a catalyst. Hydrogen peroxide is most commonly available as a solution in water. For consumers, it is usually available from pharmacies at 3 and 6 wt% concentrations. The concentrations are sometimes described in terms of the volume of oxygen gas generated; one milliliter of a 20-volume solution generates twenty milliliters of oxygen gas when completely decomposed. For laboratory use, 30 wt% solutions are most common. Commercial grades from 70% to 98% are also available.
Specifications of Commercial Pure Hydrogen Peroxide

Specifications of Hydrogen Peroxide 35% 50%
Product diluted at sites 35.0-35.8 50.0-50.8
Stability, 24 hours @ 100C >96.0% >96.0%
Loss in % assay, 1 yr, 25C <0.7 <1.0
Active oxygen content, % 16.5 23.5
Specific gravity 1.13 1.20
Boiling point C 108 114
Freezing point C -33 -52
Specifications of Hydrogen Peroxide 60% 70%
Product diluted at sites 60.0-60.8 70.0-70.8
Stability, 24 hours @ 100C >96.0% >96.0%
Loss in % assay, 1 yr, 25C <1.2 <1.4
Active oxygen content, % 28.2 32.9
Specific gravity 1.24 1.29
Boiling point C 120 126
Freezing point C -46 -40

Hydrogen Peroxide Solution (30 per cent) BP Grade
Ph. Eur. --- 7722-84-1
Action and use: Antiseptic; deodorant.
When hydrogen peroxide is prescribed or demanded, Hydrogen Peroxide Solution (6  per cent) shall be dispensed or supplied.
DEFINITION
Content:  29.0 per cent m/m to 31.0 per cent m/m of H2O2.
1 volume of hydrogen peroxyde solution (30 per cent) corresponds to about 110  times its volume of oxygen. A suitable stabiliser may be added.
CHARACTERS
Appearance: Colourless, clear liquid.
IDENTIFICATION
A. To 1 mL add 0.2 mL of dilute sulfuric acid and 0.25 mL of 0.02 M potassium  permanganate. The solution becomes colourless with evolution of gas.
B. To 0.05 mL add 2 mL of dilute sulfuric acid, 2 mL of ether and 0.05 mL of  potassium chromate solution and shake. The ether layer is blue.
C. It complies with the requirement for the content of H2O2.
TESTS
Acidity: To 10 mL add 100 mL of water and 0.25 mL of methyl red solution. Not less than  0.05 mL and not more than 0.5 mL of 0.1 M sodium hydroxide is required to change  the colour of the indicator.
Organic stabilisers: Maximum 500 ppm.
Shake 20 mL with 10 mL of chloroform R and then with 2 quantities, each of 5 mL, of  chloroform R. Evaporate the combined chloroform layers under reduced pressure at a  temperature not exceeding 25 °C and dry in a desiccator. The residue weighs a  maximum of 10 mg.
Non-volatile residue: Maximum 2 g/L.
Allow 10 mL to stand in a platinum dish until all effervescence has ceased, cooling if  necessary. Evaporate to dryness on a water-bath and dry at 100-105C. The residue  weighs a maximum of 20 mg.
ASSAY
Dilute 1.00 g to 100.0 mL with water R. To 10.0 mL of this solution add 20 mL of  dilute sulfuric acid R. Titrate with 0.02 M potassium permanganate until a pink colour  is obtained. 1 mL of 0.02 M potassium permanganate is equivalent to 1.701 mg of H2O2 or 0.56  mL of oxygen.
Hydrogen Peroxide Topical Solution USP Grade
H2O2  --- 34.01 --- [7722-84-1].
Hydrogen Peroxide Topical Solution contains, in each 100 mL, not less than 2.5 g and not more than 3.5 g of H2O2. It contains not more than 0.05 percent of a suitable preservative or preservatives.
Packaging and storage: Preserve in tight, light-resistant containers, at controlled room temperature.
Identification: Shake 1 mL with 10 mL of water containing 1 drop of 2 N sulfuric acid, and add 2 mL of ether: the subsequent addition of a drop of potassium dichromate produces an evanescent blue color in the water layer which upon agitation and standing passes into the ether layer.
Acidity: To 25 mL add phenolphthalein, and titrate with 0.10 N sodium hydroxide: not more than 2.5 mL is required for neutralization.
Barium: To 10 mL add two drops of 2 N sulfuric acid: no turbidity or precipitate is produced within 10 minutes.
Heavy metals: Dilute 4 mL, previously shaken, with 20 mL of water, add 2 mL of 6 N ammonium hydroxide, and gently boil the solution until the volume is reduced to about 5 mL Dilute with water to 25 mL: the limit is 5 ppm.
Limit of nonvolatile residue: Evaporate 20 mL, previously shaken, on a steam bath to dryness, and dry the residue at 105C for 1 hour: the weight of the residue does not exceed 30 mg.
Limit of preservative: Extract 100 mL of well-mixed Topical Solution in a separator with a mixture of 3 volumes of chloroform and 2 volumes of ether, using 50 mL, 25 mL, and 25 mL, respectively. Evaporate the combined extracts at room temperature in a tared glass dish to dryness, and dry over silica gel for 2 hours: the residue, if any, weighs not more than 50 mg (0.05%).
Assay: Pipet 2 mL of Topical Solution into a suitable flask containing 20 mL of water. Add 20 mL of 2 N sulfuric acid, and titrate with 0.1 N potassium permanganate. Each mL of 0.1 N potassium permanganate is equivalent to 1.701 mg of H2O2.
Hydrogen Peroxide Concentrate USP Grade
H2O2 --- 34.01 --- [7722-84-1].
Hydrogen Peroxide Concentrate contains not less than 29.0 percent and not more than 32.0 percent, by weight, of H2O2. It contains not more than 0.05 percent of a suitable preservative or preservatives.
Packaging and storage: Preserve in partially-filled containers having a small vent in the closure, and store in a cool place.
Labeling
: Label it to indicate the name and amount of any added preservative. The label states that this article is not intended for direct administration to humans or animals.
Acidity
: Dilute 25 g with water to 250 mL, and mix thoroughly. Take 25 mL of the solution, add phenolphthalein, and titrate with 0.10 N sodium hydroxide: not more than 2.5 mL is required for neutralization.
Chloride: 1.5 g diluted with water to 25 mL shows no more chloride than 0.10 mL of 0.020 N hydrochloric acid (0.005%).
Other requirements: It responds to the Identification test and meets the requirements of the tests for Nonvolatile residue, Heavy metals, and Limit of preservative (90 mL of it being used) under Hydrogen Peroxide Topical Solution.
Assay: Accurately weigh about 1 mL of Concentrate in a tared 100-mL volumetric flask, dilute with water to volume, and mix. To 20.0 mL of this solution add 20 mL of 2 N sulfuric acid, and titrate with 0.1 N potassium permanganate VS. Each mL of 0.1 N potassium permanganate is equivalent to 1.701 mg of H2O2.
Hydrogen Peroxide FCC Food Grade
H2O2 --- Formula wt 34.01 --- CAS: [7722-84-1]
DESCRIPTION
Hydrogen Peroxide occurs as a clear, colorless liquid. The grades of Hydrogen Peroxide suitable for food use usually have a concentration between 30% and 50%. It is miscible with water.
Note: Although Hydrogen Peroxide undergoes exothermic decomposition in the presence of dirt and other foreign materials, it is safe and stable under recommended conditions of handling and storage. Information on safe handling and use may be obtained from the supplier.
Function: Bleaching, oxidizing agent; starch modifier; antimicrobial agent.
REQUIREMENTS
Identification: Shake 1 mL of sample with 10 mL of water containing 1 drop of 2 N sulfuric acid, and add 2 mL of ether. The subsequent addition of a drop of potassium dichromate produces an evanescent blue color in the water layer that upon agitation and standing passes into the ether layer.
Assay: Not less than the labeled concentration or within the range stated on the label.
Acidity: (as H2SO4) Not more than 0.03%.
Iron: Not more than 0.5 mg/kg.
Lead: Not more than 4 mg/kg.
Phosphate: Not more than 0.005%.
Residue on Evaporation: Not more than 0.006%.
Tin: Not more than 10 mg/kg.
Hydrogen Peroxide ACS Reagent Grade
H2O2 --- Formula Wt 34.01 --- CAS Number 7722-84-1
NOTE. This reagent should be stored in a cool place in containers with a vent in the stopper. The assay requirement applies to material stored properly for a reasonable time.

REQUIREMENTS
Assay: 29.0-32.0% H2O2
MAXIMUM ALLOWABLE
Color (APHA): 10
Residue after evaporation: 0.002%
Titrable acid: 0.0006 meq/g
Chloride (Cl): 3 ppm
Nitrate (NO3): 2 ppm
Phosphate (PO4): 2 ppm
Sulfate (SO4): 5 ppm
Ammonium (NH4): 5 ppm
Heavy metals (as Pb): 1 ppm
Iron (Fe): 0.5 ppm

For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.

Manufacturers:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
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e-mail: info@mubychem.com

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Last 10 March, 2018

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Hydrogen Peroxide SDS MSDS Sheet, Material Safety Data Sheet

Section 1. Product Information

Product Name/Trade Name: Hydrogen Peroxide
CAS No.: 7722-84-1
EINECS EC Number: 231-765-0
Chemical Formula: H2O2
Molecular Weight: 34.01
Recommended usage: Industrial Manufacturing.
Suppliers: As per letterhead.

Section 2: Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Oxidising liquids; oxidizing solids Category 3, H272
Acute toxicity, oral Category 3, H301
Skin corrosion/irritation Category 1A, B, C H314
Acute toxicity (inhalation) Category 4, H332
Specific target organ toxicity - single exposure, Category 3, H335
Chronic aquatic toxicity (Category 3), H412

Labeling according GHS & Regulation (EC) No 1272/2008

GHS Label Elements
Aquatic Toxicity
Aquatic Toxicity

GHS Label Elements
corrosive.png
Corrosive

GHS Label Elements
oxidizingsolid.png
Oxidizer

GHS Label Elements
toxic.png
Toxic

Signal Words: Danger

Hazard statements:
H272 May intensify fire; oxidizer
H301 Toxic if swallowed.
H314 Causes severe skin burns and eye damage.
H332 Harmful if if inhaled
H335 May cause respiratory irritation.
H412 Harmful to aquatic life with long lasting effects.

Precautionary statements:
P202: Do not handle until all safety precautions have been read and understood.
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P220: Keep/Store away from clothing/…/combustible materials.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P314: Get medical advice/attention if you feel unwell.
P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P332+313: If skin irritation occurs: Get medical advice/attention.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P391: Collect spillage.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/regional/national/international regulation.
Other Information: Keep container in a cool place out of direct sunlight. Store only in vented containers. Avoid storing on wooden pallets. Avoid contamination - Contamination could cause decomposition and generation of oxygen which may result in high pressure and possible container rupture. Empty drums should be triple rinsed with water before discarding.

Section 3: Composition and Information on Ingredients

Product Name/Trade Name: Hydrogen Peroxide
CAS No.: 7722-84-1
EINECS EC Number: 231-765-0
Percentage: >30% and <70%

Section 4. First Aid & Procedure

Always get medical attention after the first aid is over.

Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes. Remove and wash contaminated clothing and shoes before reuse. Get medical attention if irritation develops.
Eyes:
Immediately flush eyes with plenty of water for 15 minutes, occasionally lifting upper and lower eyelids. Hold eyelids apart during irrigation. Get medical attention.
Inhalation:
Remove person to fresh air. If breathing is difficult, give oxygen. If not breathing administer artificial respiration. Get medical attention.
Hydrogen peroxide is a strong oxidant. Direct contact with the eye is likely to cause corneal damage especially if not washed immediately. Careful opthalmologic evaluation is recommended and the possibility of local corticosteroid therapy should be considered. Because of the likelihood of corrosive effects on the gastrointestinal tract after ingestion, and the unlikelihood of systemic effects, attempts at evacuating the stomach via emesis induction or gastric lavage should be avoided.

Section 5. Fire Fighting Measures

Flash Point: N/A
Fire/Explosion:
The product is not combustible but it is an oxidizer.
Extinguishing Medium:
Water. Do not use any other substance.
Hazardous Combustion Products: On decomposition product releases oxygen which may intensify fire.
Fire Fighting Instructions: Use suitable protective equipment for surrounding fire.
In closed unventilated containers, risk of rupture due to the increased pressure from decomposition. Contact with combustible material may cause fire.

Section 6. Spills and Disposals

Dike to collect large liquid spills. Stop leak and contain spill if this can be done safely. Pick up and arrange disposal without creating mist/dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. Avoid mist formation. Avoid breathing vapors, dust/mist or gas. Ensure adequate ventilation. Don't touch or walk through this product. Stop leak if safe to do so. Prevent entry into waterways, drains, confined areas. Collect material and place it into loosely covered plastic containers for later disposal.
Combustible materials exposed to hydrogen peroxide should be immediately submerged in or rinsed with large amounts of water to ensure that all hydrogen peroxide is removed. Residual hydrogen peroxide that is allowed to dry (upon evaporation hydrogen peroxide can concentrate) on organic materials such as paper, fabrics, cotton, leather, wood or other combustibles can cause the material to ignite and result in fire.

Section 7. Handling and Storage

Toxic Hazardous material.
Handling: Wash hands before eating. Use with adequate ventilation. Avoid breathing dust. Avoid contacting skin, eyes and clothing. Avoid prolonged or repeated exposure.
Storage:
Keep in a tightly closed container and store in a cool, dry, well ventilated place. Protect against physical damage. Isolate from all combustibles and incompatible substances. Keep/Store away from clothing/ combustible materials. Wear personal protective. Hydrogen peroxide should be stored only in vented containers and transferred only in a prescribed manner.
Combustible materials, Strong reducing agents. Heavy metals, alkalis, reducing agents and organic matter may produce self-accelerated thermal decomposition.

Section 8. Exposure Controls & Personal Protection

Exposure Limits: ACGIH TLV: TWA: 1 ppm, OSHA PEL: TWA: 1 ppm & TWA: 1.4 mg/m3
Engineering Controls: Use adequate exhaust ventilation to keep airborne concentrations below the allowable exposure limit.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles.
Skin: Wear appropriate protective gloves.
Respiratory System: Approved or certified respirators.
Other Protective Equipments: Overalls or similar protective apparel, clean up facilities.
Don't eat, drink or smoke in work areas. Wash hands thoroughly after handling this material.
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.

Section 9. Physical & Chemical Data

Physical State: Liquid
Appearance: Clear Colorless.
Odor: None
pH: Varies with assay
Specific Gravity: Varies with assay
Melting Point:
Varies with assay
Solubility: Miscible in water.
Chemical Formula: H2O2
Molecular Weight: 34.01

Section 10. Stability and Reactivity

Chemical Stability: Stable under recommended temperatures and pressures. It is an oxidizer.
Incompatibility (Materials to Avoid):
Organic materials, Powdered metals, Strong reducing agents.
Conditions to Avoid: Incompatible materials, excessive heat and light.
Hazardous Decomposition Products: Oxygen that supports combustion.
Hazardous Polymerization:
Will not occur.

Section 11. Toxicological Information

Toxicity to Animals:
LD50 Oral 50% solution: LD50 > 225 mg/kg bw (rat)
LD50 Oral 35 % solution:LD50 1193 mg/kg bw (rat)
LD50 Oral 70 % solution: LD50 1026 mg/kg bw (rat)
Carcinogenicity: IARC: 3- Group 3: Not classifiable as to its carcinogenicity to humans (Hydrogen peroxide).
Mutagenicity: No data available
Reproductive toxicity: No data available

Section 12. Ecological Information

Ecotoxicity: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Toxicity to fish: LC50 semi-static test Pimephales promelas: 16.4 mg/l / 96 h.
Toxicity to daphnia and other aquatic invertebrates: EC50 semi-static test Daphnia pulex: 2.4 mg/l / 48 h
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Environmental Precautions: DO NOT DISCHARGE into drains and rivers.

Section 13. Disposal Suggestions

Dispose of in accordance with all applicable local, state and federal regulations at an approved waste disposal facility.

Section 14. Transport and Label Information

DOT (USA) & ADR/RID:
UN number: 2014 Class: 5.1 (8) Packing group: II
Proper shipping name: HYDROGEN PEROXIDE, AQUEOUS SOLUTION
IMDG/IMO
UN number: 2014 Class: 5.1 (8) Packing group: II
Proper shipping name: HYDROGEN PEROXIDE, AQUEOUS SOLUTION
IATA:
UN number: 2014 Class: 5.1 (8) Packing group: II
Proper shipping name: HYDROGEN PEROXIDE, AQUEOUS SOLUTION

Section 15. Regulatory Information

USA:
SARA 302
: Listed.
SARA 313 Components: This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
SARA 311/312: Hazardous Categorization: Acute Health Hazard; Fire Hazard.
California Prop.65: Not listed.

Section 16. Other Information

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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