Hydrazine Hydrate Pure Grade Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Hydrazine Hydrate, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc.

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Hydrazine Hydrate: CAS Number: 10217-52-4 (7803-57-8), EINECS EC Number: 206-114-9, Molecular Formula: NH2NH2-xH2O , Molecular Weight: 32.05 (anhydrous basis), HS Code ---**
Chemical Names: Hydrazine hydrate, Hydrazine monohydrate, 10217-52-4

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SDS MSDS Sheet of Hydrazine Hydrate Manufacturers

Hydrazine Hydrate
Pure Grade Suppliers
Hydrazine hydrate

Hydrazine hydrate is used for the deproteination of the enamel samples in a study. It may be used as a reducing agent in preparation of silver nano-particles, transformation of mono-substituted nitrobenzene derivatives to the corresponding anilines and along with graphite for the conversion of nitro compounds to the amino compounds. Hydrazine derivatives are used in the manufacture of herbicides and fungicides, as well as plant growth regulators. From tranquilizers to the primary drug for controlling tuberculosis, hydrazine derivatives have proven to be effective ingredients for a number of pharmaceuticals. Hydrazine solution strength is usually given as the percent contained hydrazine. However, when hydrazine and water are mixed, a monohydrate (N2H4.H20) is formed through hydrogen bonding. Therefore, the amount of hydrazine in a solution can also be designated as the percentage of hydrazine monohydrate. Hydrazine hydrate is a colorless, fuming and basic solution with a peculiar bad smell, soluble in water and alcohol, insoluble in chloroform and ethyl ether.

Specifications of Hydrazine Hydrate
Content% Hydrazine Hydrate 50% or 80% or as desired by the buyer
N2H4·H2O% ≥ 80% or as required by the buyer
Fe ≤ 0.5 ppm
SO4≤ 0.5 ppm
Sodium≤ 0.5 ppm
Chloride≤ 0.5 ppm
Nonvolatile matters≤ 20 ppm

Manufacturers:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30

e-mail: info@mubychem.com

USA, Canada, Mexico and other American
neighbouring buyers may
e-mail: us@mubychem.com
Call toll-free 1-844-682-9243 (1-844-MUBYCHEM)

Manufacturers india
Copyright and Usual Disclaimer is Applicable.
Last 26 August, 2022

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Hydrazine Hydrate 80% Solution SDS Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 23-Oct-20

1. Product Identification

Product Name & Other Names: Hydrazine hydrate, Hydrazine monohydrate, 10217-52-4
CAS No.: 10217-52-4
EINECS EC Code: 206-114-9
Molecular Weight: 32.05 (anhydrous basis)
Chemical Formula: NH2NH2-xH2O
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Oral (Category 3), H301
Acute toxicity, Inhalation (Category 3), H331
Acute toxicity, Dermal (Category 3), H311
Skin corrosion (Category 1B), H314
Serious eye damage (Category 1), H318
Skin sensitization (Category 1), H317
Carcinogenicity (Category 1B), H350
Chronic aquatic toxicity (Category 1), H410

Labeling according to GHS USA & Regulation (EC) No 1272/2008

GHS Label Elements
Toxic
Toxic

GHS Label Elements
Corrosive
Corrosive

GHS Label Elements
Health Hazard
Health Hazard

GHS Label Elements
Aquatic Toxicity
Aquatic Toxicity

Signal Word: Danger

Hazard Statements:
H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H350 May cause cancer.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements
P202: Do not handle until all safety precautions have been read and understood.
P220: Keep/Store away from clothing/other combustible materials.
P221: Take any precaution to avoid mixing with combustibles.
P234 Keep only in original container.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash ... thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P272: Contaminated work clothing should not be allowed out of the workplace
P273 Avoid release to the environment.
P280-Wear protective gloves/protective clothing/eye protection/face protection.
P284 Wear respiratory protection.
P301+P310+330: IF SWALLOWED: Rinse mouth and immediately call a POISON CENTER or doctor/physician.
P302+P352: IF ON SKIN: Wash with soap and water.
P303 + P361 + P352 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P304 + P341 + P311 IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P310 Immediately call a POISON CENTER or doctor/physician.
P314: Get Medical advice/attention if you feel unwell.
P330: If swallowed, rinse mouth.
P308+313: IF exposed or concerned: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P363: Wash contaminated clothing before reuse.
P390 Absorb spillage to prevent material damage.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
T Toxic
Xi Irritant
C Corrosive
N Dangerous for the environment.
Risk Phrase:
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed
R36/37/38 Irritating to eyes, respiratory system and skin.
R34 Causes burns.
R41 Risk of serious damage to eyes.
R43 May cause sensitization by skin contact.
R45 May cause cancer.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

3. Composition/Information on Ingredients

Ingredient: Hydrazine hydrate 40-580% in water.
CAS No.: 10217-52-4
EINECS EC Code: 206-114-9

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: If Hydrazine hydrate is inhaled, it will cause irritation and damage to nose and throat. It can cause headache, bleeding from nose coughing and chest discomfort. Remove the victim to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: It will cause irritation and burns to mouth, digestive tract and stomach. It may lead to pain, nausea, vomiting, and even collapse. Contact medical center quickly. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: On contact, it can cause itching, pain, swelling and redness. Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: It can cause severe damage to eyes. Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Get medical attention.

5. Fire Fighting Measures

Fire: Flash point: NA.
Toxic fumes, carbon dioxide, carbon monoxide and nitrogen oxides may be formed in fire.
Fire Extinguishing Media: Dry chemical, foam or carbon dioxide and water spray jet.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.

6. Accidental Release Measures

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental  precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Mop and pick up the material and place in an appropriate waste disposal container. Soak up with inert absorbent material and dispose of as hazardous waste. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Avoid mist formation. Wear full protective equipment and ensure proper ventilation. Keep away from heat. Keep away from sources of ignition. Provide ventilation. Vacuum or sweep up and remove to an approved disposal container. Contact Environment Agency.

7. Handling and Storage

Precautions for safe handling: Keep away from heat and source of fire preferably in a ventilated area. Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Keep locked up in tightly closed container. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Do not ingest. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like oxidizing agents etc. Containers may be hazardous when empty since they retain product residues. Do not store near food items.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits:
TWA: 0.01 ppm USA. ACGIH Threshold Limit Values (TLV).
TWA: 1 ppm USA. Occupational Exposure Limits (OSHA)
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to the substance is apparent and engineering controls are not feasible, consult an industrial hygienist. For emergencies, or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: Clear colorless  liquid.
Odor: Typical smell.
Odor threshold: Not available.
pH: Not available.
Relative density: 1.03
Melting point/freezing point: Not available.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Miscible with water
Viscosity: Not available.
Molecular Weight: 32.05 (anhydrous basis)
Chemical Formula: NH2NH2-xH2O

10. Stability and Reactivity

Stability: Hydrazine hydrate is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Carbon dioxide, carbon monoxide, nitrogen oxides (NOx) and toxic fumes may form when heated to decomposition.
Hazardous Polymerization: Not reported.
Incompatibilities: Zinc, Oxidizing agents, Organic materials, Oxygen, Copper etc.
Conditions to Avoid: Heat, flames, ignition sources and incompatibles.

11. Toxicological Information

4-HOUR EXPOSURE.
Acute oral toxicity (LD50): 83 mg/kg [Mouse].
Acute toxicity of the vapor (LC50): 570 ppm 4 hour(s) [Rat].
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Teratogenic Effects: Not available.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.
Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin.

12. Ecological Information

Environmental Toxicity: Toxic to fish and aquatic life.
Persistence and Degradability: No information available.
Mobility: No information available.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state, and local requirements.

14. Transport Information

DOT USA, TDG Canada & ADR/RID Europe
UN Number: 2030
Proper shipping name: Hydrazine aqueous solution
Class: 8 (6.1), Packing group: II
IMDG & IATA
UN Number: 2030
Proper shipping name: Hydrazine aqueous solution
Class: 8 (6.1), Packing group: II

15. Regulatory Information

USA:
California Prop 65
: WARNING! This product contains a chemical known to the State of California to cause cancer. CAS-No.: 10217-52-4
SARA 302 Components: The following components are subject to reporting levels established by SARA Title III, Section 302: Hydrazine hydrate CAS-No.:10217-52-4
SARA 313 Components: The following components are subject to reporting levels established by SARA Title III, Section 313: Hydrazine hydrate CAS-No.:10217-52-4
SARA 311/312 Hazards: Acute Health Hazard, Chronic Health Hazard. See section 2.

Section 16 - Additional Information

European Labeling in Accordance with EC Directives:
H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H350 May cause cancer.
H410 Very toxic to aquatic life with long lasting effects.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
T Toxic
Xi Irritant
C Corrosive
N Dangerous for the environment.
Risk Phrase:
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed
R36/37/38 Irritating to eyes, respiratory system and skin.
R34 Causes burns.
R41 Risk of serious damage to eyes.
R43 May cause sensitization by skin contact.
R45 May cause cancer.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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