2,2-Diphenyl-1-Picrylhydrazyl or 1,1-Diphenyl-2-Picrylhydrazyl or DPPH Radical or 2,2-Diphenyl-1-(2,4,6-trinitrophenyl)hydrazyl Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of 2,2-Diphenyl-1-Picrylhydrazyl or 1,1-Diphenyl-2-Picrylhydrazyl or DPPH Radical or 2,2-Diphenyl-1-(2,4,6-trinitrophenyl)hydrazyl, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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2,2-Diphenyl-1-Picrylhydrazyl or 1,1-Diphenyl-2-Picrylhydrazyl or DPPH Radical or 2,2-Diphenyl-1-(2,4,6-trinitrophenyl)hydrazyl CAS Number 1898-66-4, EINECS EC Number: 217-591-8, Molecular Formula: C18H12N5O6, Molecular Weight: 394.32, HS Code 29280090

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SDS MSDS Sheet of 2,2-Diphenyl-1-Picrylhydrazyl or 1,1-Diphenyl-2-Picrylhydrazyl or DPPH Radical or 2,2-Diphenyl-1-(2,4,6-trinitrophenyl)hydrazyl Manufacturers

2,2-Diphenyl-1-Picrylhydrazyl
1,1-Diphenyl-2-Picrylhydrazyl or DPPH Radical or 2,2-Diphenyl-1-(2,4,6-trinitrophenyl)hydrazyl Suppliers
2,2-Diphenyl-1-Picrylhydrazyl or DPPH Radical

2 2-Diphenyl-1-Picrylhydrazyl or 1,1-Diphenyl-2-picrylhydrazyl radical or DPPH Radical or 2,2-Diphenyl-1-(2,4,6-trinitrophenyl)hydrazyl is a free radical, which shows hydrogen acceptor ability towards antioxidants. DPPH Radical or 2,2-Diphenyl-1-picrylhydrazyl is a stable free radical that can be used to measure the radical scavenging activity of antioxidants.

General Properties and Specifications of 2 2-Diphenyl-1-Picrylhydrazyl or 1,1-Diphenyl-2-picrylhydrazyl radical or 2,2-Diphenyl-1-(2,4,6-trinitrophenyl)hydrazyl or DPPH Radical:
Appearance: Green to Very Dark Green or Purple Black Powder.
Assay: 95% minimum.
Melting point: about 128C to 137C literature, decomposes.
Relative density: about 1.4
Solubility: Insoluble in water. Soluble in methanol.
Storage: Refrigerate.

We also manufacture and supply as under:

2,2-Diphenyl-1-Picrylhydrazyl

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Alkyl Diphenyl Oxide Sulfonate

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Decabromodiphenyl oxide

Diphenylacetonitrile

Hydrazine Hydrate

Meta Nitro Para Toluidine

4-Nitrophenyl phosphate disodium salt hexahydrate

Nitromethane

Manufacturers:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30

e-mail: info@mubychem.com

USA, Canada, Mexico and other American
neighbouring buyers may
e-mail: us@mubychem.com
Call toll-free 1-877-682-9243 (1-877-MUBYCHEM)

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Last 30 March, 2024

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2 2-Diphenyl-1-Picrylhydrazyl or 1,1-Diphenyl-2-picrylhydrazyl radical or DPPH Radical or 2,2-Diphenyl-1-(2,4,6-trinitrophenyl)hydrazyl SDS or Safety Data Sheet
Material Safety Data Sheet
23-July-23

1. Product Identification

Product Name & Other Names: 2 2-Diphenyl-1-Picrylhydrazyl or 1,1-Diphenyl-2-picrylhydrazyl radical or DPPH Radical or 2,2-Diphenyl-1-(2,4,6-trinitrophenyl)hydrazyl.
CAS No.: 1898-66-4
EINECS EC Number: 217-591-8
Molecular Formula: C18H12N5O6
Molecular Weight: 394.32
Relevant uses and uses advised against (if any): Industrial use only.
Supplier: As per letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Skin sensitization, Category 1, H317
Sensitization, respiratory Category 1 - H334

Labeling according to GHS & Regulation (EC) No 1272/2008

GHS Label Elements
Health Hazard
Health Hazard

Signal Word: Danger

Hazard statements
H317 May cause an allergic skin reaction.
H335-May cause respiratory irritation.

Precautionary statements Prevention
P261 -Avoid breathing dust/fumes.
P271 -Use only outdoors or in a well-ventilated area.
P285: In case of inadequate ventilation wear respiratory protection.
P280 -Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary statements Response
P304+341: IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338- IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313- If eye irritation persists: Get medical advice/attention.
P302+P352 -IF ON SKIN: Wash with plenty of water and soap.
P332+P313 -If skin irritation occurs: Get medical advice/attention.
Precautionary statements Storage
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
Precautionary statements Disposal
P501 Dispose of contents/container in accordance with local regulations.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xn = Harmful
Risk Phrases:
R43 = May cause sensitization by skin contact.
R42 May cause sensitization by inhalation.

3. Composition/Information on Ingredients

Product Name & Other Names: 2 2-Diphenyl-1-Picrylhydrazyl or 1,1-Diphenyl-2-picrylhydrazyl radical or DPPH Radical or 2,2-Diphenyl-1-(2,4,6-trinitrophenyl)hydrazyl.
CAS No.: 1898-66-4
EINECS EC Number: 217-591-8

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Eye Contact: Wash out immediately with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. Seek medical attention without delay; if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
Skin Contact: Immediately remove all contaminated clothing, including footwear. Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation.
Inhalation: Lay patient down. Keep warm and in rest. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary. Transport to hospital, or doctor, without delay.
Ingestion: If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness i.e., becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Seek medical advice.
Indication of any medical attention and special treatment needed: Treat symptomatically.

5. Fire Fighting Measures

Extinguishing media: Water spray or fog, Foam, Dry chemical powder, BCF (where regulations permit), Carbon dioxide.
Fire Fighting: Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water courses. Use water delivered as a fine spray to control fire and cool adjacent area. DO NOT approach containers suspected to be hot. Cool fire exposed containers with water spray from a protected location. If safe to do so, remove containers from path of fire.
Fire/Explosion Hazard: Combustible solid which burns; it is estimated that most organic dusts are combustible - according to the circumstances under which the combustion process occurs, such materials may cause fires and / or dust explosions. Avoid generating dust, particularly clouds of dust in a confined or unventilated space as dusts may form an explosive mixture with air, and any source of ignition, i.e., flame or spark, will cause fire or explosion.
Combustion products: Carbon monoxide (CO), carbon dioxide (CO2) and nitrogen compounds. May emit poisonous and corrosive fumes.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and a suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

6. Accidental Release Measures

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Ensure adequate ventilation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage:
Minor Spills: Remove all ignition sources. Clean up all spills immediately. Avoid contact with skin and eyes. Control personal contact with the substance, by using protective equipment. Use dry clean up procedures and avoid generating dust. Place in a suitable, labeled container for waste disposal.
Major Spills: Alert Emergency Services and tell them location and nature of hazard. Control personal contact by wearing protective clothing. Recover product wherever possible. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g., sand, earth, diatomaceous earth, vermiculite).
IF DRY: Use dry clean up procedures and avoid generating dust. Collect residues and place in sealed plastic bags or other containers for disposal.
IF WET: Vacuum/shovel up and place in labelled containers for disposal.
ALWAYS: Wash area with water and prevent runoff into drains.

7. Handling and Storage

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Store protected from heat, sparks and ignition sources and incompatible materials like oxidizers. Recommended storage temperature 2C. Short term shipping may be at room temperature. Light sensitive.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: This product does not contain any hazardous materials with occupational exposure limits established by the region-specific regulatory bodies.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, a full-face piece respirator with dust/mist filter may be worn. For emergencies or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron, or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: Green to Very Dark Green or Purple Black Powder.
Odor: Not available.
Odor threshold: Not available.
pH: Not available.
Relative density: 1.4
Melting point / freezing point (°C): about 128C to 137C literature, decomposes.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility in water (g/L): Insoluble in water. Soluble in methanol.
Viscosity: Not available.
Molecular Formula: C18H12N5O6
Molecular Weight: 394.32

10. Stability and Reactivity

Chemical stability:
Product is considered stable. Unstable in the presence of incompatible materials.
Hazardous polymerization: Will not occur.
Conditions to avoid- Heat sparks flame moisture and incompatibilities.
Incompatible materials- Oxidizing agents
Hazardous decomposition products- Carbon monoxide (CO), carbon dioxide (CO2) and nitrogen compounds. May emit poisonous and corrosive fumes.

11. Toxicological Information

Toxicity to Animals: Data Not Available.
Mutagenicity: Data Not Available to make classification
Carcinogenicity: Not a reported carcinogen as per IARC, ACGIH, NTP & OSHA.
Reproductivity: Data Not Available to make classification.

12. Ecological Information

DO NOT discharge into sewer or waterways.
Toxicity:
Persistence and Degradability: No information available.
Mobility: No information available.
Bioaccumulation/ Accumulation: No information available.
Mobility in soil: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

13. Disposal Considerations

Return empty containers to supplier for reuse/ recycling if possible. Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws operating in their area. In some areas, certain wastes must be tracked. Dispose according to law.
In all cases disposal to sewer may be subject to local laws and regulations and follow the same.

14. Transport Information

DOT USA, TDG Canada & ADR/RID Europe: Not Regulated.
IMDG/IMO: Not Regulated.
IATA: Not Regulated.

15. Regulatory Information

SARA 311/312 Hazards: Acute Health Hazard. See section 2.
California Prop. 65 Components: This product does not contain any chemicals known to the State of California to cause cancer, birth defects, or any other reproductive harm.

16. Other Information

European Labeling in Accordance with EC Directives:
H317 May cause an allergic skin reaction.
H335-May cause respiratory irritation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xn = Harmful
Risk Phrases:
R43 = May cause sensitization by skin contact.
R42 May cause sensitization by inhalation.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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