Diethyl phthalate or DEP Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Diethyl phthalate or DEP, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc.

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Diethyl phthalate or DEP: CAS Number: 84-66-2, EINECS EC Number: 201-550-6, Molecular Formula: C12H14O4 or C6H4-1,2-(CO2C2H5)2, Molecular Weight: 222.24, HS Code ---**

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SDS MSDS Sheet of Diethyl phthalate or DEP Manufacturers

Diethyl phthalate
DEP Pure Suppliers
Diethyl phthalate or DEP

Diethyl phthalate or DEP or Diethyl phthalic acid or 1, 2-Benzenedicarboxylic acid diethyl ester or Diethyl benzene-1,2-dicarboxylate is a phthalate ester, namely the diethyl ester of phthalic acid. It is a clear substance that is liquid at room temperature. Diethyl phthalate DEP is commonly used as a solvent in cosmetics and as a plasticizer. It is often used to bind cosmetics and fragrances. Other industrial uses include plasticizers, detergent bases and aerosol sprays.

General Properties and Specifications of Diethyl phthalate or DEP:
Appearance: Clear, colorless or very slightly yellow, oily liquid without significant odor.
Assay: 99.5% minimum.
Moisture: 0.2% maximum.
Relative density: 1.12
Melting point: -4C literature.
Boiling point: 295C literature.
Flash point: 161C literature.
Solubility: Practically insoluble in water, miscible with ethanol (96 per cent).


Specifications of Diethyl Phthalate USP NF Grade:
C12H14O4 --- 222.24
1,2-Benzenedicarboxylic acid, diethyl ester;    
Diethyl phthalate --- [84-66-2].

DEFINITION
Diethyl Phthalate contains NLT 98.0% and NMT 102.0% of diethyl phthalate (C12H14O4), calculated on the anhydrous basis. [Caution— Avoid contact. ]

IDENTIFICATION
A.
Infrared Absorption: On undried specimen

ASSAY
Procedure:
Sample: 1.5 g
Titrimetric system 
Mode: Residual titration
Titrant: 0.5 N alcoholic potassium hydroxide
Back-titrant: 0.5 N hydrochloric acid
Endpoint detection: Visual
Analysis: Transfer the Sample to a flask, add 50.0 mL of the Titrant, and boil with a reflux condenser on a water bath for 1 h. Add 20 mL of water, then add phenolphthalein. Titrate the excess potassium hydroxide with the Back-titrant. Perform a blank determination. Each mL of 0.5 N potassium hydroxide is equivalent to 55.56 mg of diethyl phthalate (C12H14O4 ).
Acceptance criteria: 98.0%–102.0% on the anhydrous basis.

Residue on Ignition:
Sample: 10 g
Analysis: Gently heat the Sample until the liquid has evaporated, and ignite the residue to constant weight.
Acceptance criteria: NMT 0.02%
Specific Gravity: 1.118–1.122 at 20C
Refractive Index: 1.500–1.505 at 20C
Acidity:
Sample: 20.0 g
Analysis: Mix the Sample with 50 mL of alcohol that previously has been neutralized to a phenolphthalein endpoint, and titrate with 0.1 N sodium hydroxide to a phenolphthalein endpoint.
Acceptance criteria: NMT 0.50 mL is required for neutralization.
Water Determination, Method I: NMT 0.2%
Packaging and Storage: Preserve in tight containers.


Specifications of Diethyl Phthalate BP Ph Eur Grade:
C12H14O4 --- 222.2 --- 84-66-2 
Action and use: Excipient.

DEFINITION
Diethyl benzene-1,2-dicarboxylate.
Content: 99.0 per cent m/m to 101.0 per cent m/m.

CHARACTERS
Appearance: Clear, colourless or very slightly yellow, oily liquid.
Solubility: Practically insoluble in water, miscible with ethanol (96 per cent).

IDENTIFICATION
First identification: B, C
Second identification: A, D, E
A. Relative density: 1.117 to 1.121.
B. Refractive index: 1.500 to 1.505.
C. Infrared absorption spectrophotometry.
Preparation Thin films.
Comparison diethyl phthalate CRS.
D. Thin-layer chromatography. To pass the test.
Results The principal spot in the chromatogram obtained with the test solution is similar in position and size to the principal spot in the chromatogram obtained with the reference solution.
E. To about 0.1 mL add 0.25 mL of sulfuric acid and 50 mg of resorcinol. Heat on a water-bath for 5 min. Allow to cool. Add 10 mL of water and 1 mL of strong sodium hydroxide solution. The solution becomes yellow or brownish-yellow and shows green fluorescence.

TESTS
Appearance: The substance to be examined is clear and not more intensely coloured than reference solution.
Acidity: Dissolve 20.0 g in 50 mL of ethanol (96 per cent) previously neutralised to phenolphthalein solution. Add 0.2 mL of phenolphthalein solution. Not more than 0.1 mL of 0.1 M sodium hydroxide is required to change the colour of the indicator to pink.
Related substances: To pass the test by Gas chromatography.
Water: Maximum 0.2 per cent, determined on 10.0 g.
Sulfated ash: Maximum 0.1 per cent, determined on 1.0 g.

ASSAY
Introduce 0.750 g into a 250 mL borosilicate glass flask. Add 25.0 mL of 0.5 M alcoholic potassium hydroxide and a few glass beads. Boil in a water-bath under a reflux condenser for 1 h. Add 1 mL of phenolphthalein solution and titrate immediately with 0.5 M hydrochloric acid. Carry out a blank titration. Calculate the volume of 0.5 M alcoholic potassium hydroxide used in the saponification.
1 mL of 0.5 M alcoholic potassium hydroxide is equivalent to 55.56 mg of C12H14O4.

STORAGE
In an airtight container.

For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.

We manufacture and supply as under:

Cellulose Acetate Phthalate

Diethyl phthalate or DEP

Diallyl Phthalate

Dimethyl Terephthalate

Dimethyl 5-sulfoisophthalate sodium salt.

Hydroxypropyl Methycellulose Phthalate

Isophthalic Acid

Phthalic Acid

Phthalic Anhydride

Phthalimide

Potassium Hydrogen Phthalate

Potassium Phthalimide.

Manufacturers:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30

e-mail: info@mubychem.com

USA, Canada, Mexico and other American
neighbouring buyers may
e-mail: us@mubychem.com
Call toll-free 1-844-682-9243 (1-844-MUBYCHEM)

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Last 26 August, 2022

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Diethyl phthalate or DEP SDS GHS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet
 15-Oct-20

Section 1: Chemical Product and Company Identification

Product Name & Other Names: Diethyl phthalate or DEP.
CAS Number: 84-66-2
EINECS EC Code: 201-550-6
Molecular Formula: C12H14O4 or C6H4-1,2-(CO2C2H5)2
Molecular Weight: 222.24
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

Section 2: Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP)

Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.

Labeling Regulation as per GHS & EC 1272/2008 (CLP) & GHS

GHS Label Elements
NONE

Signal Word: None

Hazards not otherwise classified (HNOC):
May causes mild skin irritation.
May causes mild eye irritation.

Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.

Section 3: Composition and Information on Ingredients

Product Name & Other Names: Diethyl phthalate or DEP.
CAS Number: 84-66-2
EINECS EC Code: 201-550-6

Section 4: First Aid Measures

Always seek medical advice after the first aid treatment.
Skin: Rinse with water. Soap may be used. Seek Medical Aid.
Eyes: Wash eyes with plenty of water for at least 15 minutes, lifting lids occasionally. Seek Medical Aid.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Ingestion: If swallowed, induce vomiting immediately after giving two glasses of water. Never give anything by mouth to an unconscious person.

Section 5: Fire and Explosion Data

Products of Combustion: Oxides of Carbon. The product can ignite at high temperature.
Fire Fighting Media and Instructions: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus for firefighting if necessary.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes.

Section 6: Accidental Release Measures

Personal precautions, protective equipment and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Ensure adequate ventilation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to legal requirements.
Large Spill: Contain spilled material. Do not inhale vapors, mist, or gas. Avoid dust/mist formation. Cover with inert absorbent material and use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

Section 7: Handling and Storage

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid contact with skin, eyes and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like oxidizing agents.

Section 8: Exposure Controls/Personal Protection

Exposure Guidelines:
ACGIH TLV: TWA: 5 mg/m3
OSHA PEL: (Vacated) TWA: 5 mg/m3.
Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Section 9: Physical and Chemical Properties

Physical state and appearance: Clear, colorless or very slightly yellow, oily liquid.
Odor: Without significant odor.
Odor threshold: Not available.
pH: Not available.
Relative density: 1.12
Melting point/freezing point: -4C literature.
Initial boiling point and boiling range: 295C literature.
Flash point: 161C literature.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Practically insoluble in water, miscible with ethanol (96 per cent).
Viscosity: Not available.
Molecular Formula: C12H14O4 or C6H4-1,2-(CO2C2H5)2
Molecular Weight: 222.24

Section 10: Stability and Reactivity Data

Stability: It is stable in room temperature in closed containers under normal storage & handling.
Conditions of instability: Incompatible materials, Strong oxidizers.
Incompatibility with various substances: Avoid high temperatures, sparks, open flames and moisture. Avoid contact with strong oxidizing agents.
Polymerization: Will not occur.

Section 11: Toxicological Information

LD50 Oral - Rat: 8600 mg/kg.
LD50 Dermal – Rat: > 11200 mg/kg
Carcinogenic Effects: Not a reported carcinogen by IARC, NTP, ACGIH, OSHA.
Reproductive toxicity: No data available.
Teratogenicity: No data available.
Developmental Effects: No data available.
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

Section 12: Ecological Information

Toxicity to fish: flow-through test LC50 - Cyprinodon variegatus (sheepshead minnow) - 29 mg/l  - 96 h.
Toxicity to daphnia and other aquatic invertebrates: static test LC50 - Daphnia magna (Water flea) - 90 mg/l  - 48 h.
BOD5 and COD: Not available.
Persistence and Degradability: Readily biodegradable.
Bioaccumulation/ Accumulation: No information available.
Mobility: No information available.

Section 13: Disposal Considerations

Waste Disposal: Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT USA & ADR/RID Europe: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods

Section 15: Other Regulatory Information

USA Regulations:
SARA 313: Not applicable
SARA 311/312 Hazard Categories: Not applicable
California Prop 65: California No Significant Risk Level: None of the chemicals in this product are listed.

Section 16 - Additional Information

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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