Synthetic Cryolite Sodium Cryolite or Sodium Aluminium Fluoride or Trisodium Hexafluoroaluminate and Potassium Cryolite or Tripotassium Hexafluoroaluminate and Lithium Cryolite or TriLithiumhexafluoroaluminate Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Synthetic Sodium Potassium Lithium Cryolite Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc.

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Synthetic Cryolite, Sodium Cryolite or Sodium Aluminium Fluoride or Trisodium Hexafluoroaluminate: CAS Number: 15096-52-3 and 13775-53-6, EINECS EC Number: 237-410-6, Molecular Formula: Na3AlF6, Molecular Weight: 209.94, HS Code ---**

Synthetic Potassium Cryolite or Tripotassium Hexafluoroaluminate: CAS Number: 13775-52-5, EINECS EC Number: 237-409-0, Molecular Formula: K3AIF6, Molecular Weight: 258.27, HS Code ---**

Synthetic Lithium Cryolite or TriLithiumhexafluoroaluminate: CAS Number: 13821-20-0, EINECS EC Number: 237-509-4, Molecular Formula: Li3AlF6, Molecular Weight: 161.79, HS Code ---**

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Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Synthetic Cryolite, Sodium Cryolite or Sodium Aluminium Fluoride or Trisodium Hexafluoroaluminate and Synthetic Potassium Cryolite or Tripotassium Hexafluoroaluminate and Synthetic Lithium Cryolite or TriLithiumhexafluoroaluminate.

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SDS MSDS Sheet of Lithium Cryolite or Lithium Aluminium Fluoride or Trilithium Hexafluoroaluminate Manufacturers

Synthetic Cryolite
Sodium Cryolite, Potassium Cryolite, Lithium Cryolite Pure Suppliers
Sodium Cryolite Potassium Cryolite Lithium Cryolite

Sodium Cryolite (Na3AlF6, sodium hexafluoroaluminate) is an uncommon mineral. Due to its rarity it is possibly the only mineral on Earth ever to be mined to commercial extinction. Cryolite occurs as glassy, colorless, white-reddish to gray-black prismatic monoclinic crystals. Synthetic Sodium Cryolite can be manufactured. Cryolite is used as an insecticide and a pesticide. It is also used to give fireworks a yellow color. It is also used in metallurgical applications such as foundry additives for aluminum foundry, sleeves, cover flux, filler for bonded abrasives glass and enamel industries.

Specifications of Sodium Cryolite:
Molar Mass: 209.94
Molecular Formula: Na3AlF6
Specific Gravity: 2.9 to 3.0
Melting Point: 1012C
Appearance: Colorless to white or off-white.
Assay: 98.5%
pH: 7 to 9.0
Fluorine F: 54.28% typical.
Aluminum: 12.68% typical.
Free HF: 0.002%
Silica as SiO2: 0.6%
Chloride as Cl: 0.003%
Sulphate as SO4: 0.004%
Iron as Fe: 0.05%
Lead Pb: 0.02%
Solubility: Soluble in AlCl3 solution, soluble in H2SO4 with the evolution of HF.
Solubility in Water: Insoluble in water.


Potassium Cryolite or Tripotassium Hexafluoroaluminate is used in production of abrasives: as active filler in resin-bonded abrasives for metal treatment Blasting and pyrotechnics: for fireworks Production of welding agents: as components in coatings of welding rods and welding powders.

Specifications of Potassium Cryolite:
Appearance: White powder
K: 41.0 to 41.50%
Al: 11.0 to 12.0%
F: 44.0 to 45.5%
Fe: 0.03% maximum.
SO4: 0.02% maximum.
SiO2: 0.5% maximum.
Cl: 0.02% maximum.
Pb: 0.003% maximum.
Water: 3.0% maximum.


Lithium Cryolite or TriLithiumhexafluoroaluminate (Li3AlF6) is used in production of abrasives: as active filler in resin-bonded abrasives for metal treatment; production of welding agents: as components in coatings of welding rods and welding powders; production of soldering agents: as component for fluxing agents.

Specifications of Lithium Cryolite:
Appearance: White powder
Li3AlF6: 94.0 to 96.0%
Fe: 0.02% maximum.
SO4: 0.02% maximum.
SiO2: 0.5% maximum.
Cl: 0.01% maximum.
Pb: 0.01% maximum.
Water: 4.0% maximum.

We manufacture and supply Fluoride products as under:

Ammonium Bifluoride

Ammonium Fluoride

Calcium Fluoride

Chromium Fluoride

Potassium Fluoride

Sodium Fluoride

Sodium Silico Fluoride

Sodium, Potassium, Lithium Cryolite

Stannous Fluoride

Strontium Acetate Carbonate Fluoride Nitrate Sulfate.

Manufacturers:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30

e-mail: info@mubychem.com

USA, Canada, Mexico and other American
neighbouring buyers may
e-mail: us@mubychem.com
Call toll-free 1-844-682-9243 (1-844-MUBYCHEM)

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Last 26 August, 2022

List of All the IP, BP, EP, Ph Eur, USP NF, JP, FCC Food, Analytical Reagent Grades of Chemicals
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Manganese Chloride Manganese Sulfate
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Selenious acid Sodium Acetate
Sodium Bromate Sodium Diacetate
Sodium Formaldehyde Bisulfite Sodium Lactobionate
Sodium Thiosulfate Zinc Chloride

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Sodium Cryolite or Sodium Aluminum Fluoride SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet
11-Oct-20

Section 1: Product and Company Identification

Product Name & Other Names: Synthetic Cryolite, Sodium Cryolite or Sodium Aluminum Fluoride or Trisodium Hexafluoroaluminate.
CAS No.: 5096-52-3 and 13775-53-6
EINECS, EC Number: 237-410-6
Molecular Weight: 209.94
Chemical Formula: Na3AlF6
Relevant uses and uses advised against (if any): Laboratory chemicals, Manufacture of substances
Supplier: As per letterhead.

Section 2: Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Inhalation (Category 4), H332
Specific target organ toxicity - repeated exposure (Category 1), H372
Chronic aquatic toxicity (Category 2), H411

Labeling according to GHS & Regulation (EC) No 1272/2008

GHS Label Elements
Irritant
Irritant

GHS Label Elements
Health Hazard
Health Hazard

GHS Label Elements
Marine Pollutant
Marine Pollutant

Signal Words: Danger

Hazard statements:
H332: Harmful if inhaled.
H372 Causes damage to organs through prolonged or repeated exposure.
H410: Toxic to aquatic life with long lasting effects.

Precautionary statements:
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264 Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P314: Get Medical advice/attention if you feel unwell.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308+313: IF exposed or concerned: Get medical advice/attention.
P337+313: If eye irritation persists get medical advice/attention.
P342+311: If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
P391: Collect spillage.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/regional/national/international regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xn Harmful
N Dangerous for Environment.
Risk Phrase:
R20 Harmful by inhalation.
R48 Danger of serious damage to health by prolonged exposure.
R 51/53 Toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment.

Section 3: Composition / Information on Ingredients

Product Name & Other Names: Synthetic Cryolite, Sodium Cryolite or Sodium Aluminum Fluoride or Trisodium Hexafluoroaluminate.
CAS No.: 5096-52-3 and 13775-53-6
EINECS, EC Number: 237-410-6

Section 4: First Aid Measures

Always seek medical attention after first aid measures are provided

Eyes: Immediately flush eyes with excess water for 15 minutes, lifting lower and upper eyelids occasionally.
Skin: Immediately flush skin with excess water for 15 minutes while removing contaminated clothing.
Ingestion: Call Emergency Medical immediately. Rinse mouth with cold water. Give victim 1-2 cups of water or milk to drink. Induce vomiting immediately.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration.
Notes to Physician: Treat symptomatically.

Section 5: Fire Fighting Measures

It is non-flammable solid.
Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide.
Protective equipment and precautions for firefighters: Use water spray, foam, or dry chemical to extinguish fire. Firefighters should wear full fire fighting turn-out gear and respiratory protection. Cool container with water spray.
Special hazards arising from the substance: Hydrogen fluoride, Sodium oxides, Aluminum oxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes.

Section 6: Accidental Release Measures

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

Section 7: Handling and Storage

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, strong bases, and strong acids.

Section 8: Exposure Controls / Personal Protection

Exposure guidelines:
USA-OSHA PEL: (Vacated) TWA 2.5 mg/m3 (as F) (listed under Fluorides)
USA-NIOSH: TWA 2.5 mg/m3 (as F) (listed under Fluorides).
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Section 9: Physical and Chemical Properties

Physical state and appearance: Colorless to white or off-white.
Odor: Odorless.
Odor threshold: Not available.
pH (1% soln/water): 7 to 9.
Relative density: about 2.90 to 3
Melting Point: 1012C.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Insoluble in water. Soluble in AlCl3 solution, soluble in H2SO4 with the evolution of HF.
Viscosity: Not available.
Molecular Weight: 209.94
Chemical Formula: Na3AlF6

Section 10: Stability and Reactivity

Avoid heat and ignition sources.
Stability: Stable under normal conditions of use and storage.
Incompatibility: Heat and strong oxidizing agents, strong bases, and strong acids. Heat.
Hazardous Decomposition Products: Hydrogen fluoride, Sodium oxides, Aluminum oxide.
Hazardous Polymerization: Has not been reported.

Section 11: Toxicology Information

LD50 Oral - Rat - >5000 mg/kg.
Acute inhalation toxicity: LC50, 4 h, Rat, 4.47 mg/l
Carcinogenicity: IARC: 3 - Group 3: Not classifiable as to its carcinogenicity to humans.
Reproductive toxicity: No information found.
Developmental Effects: No information found.
Teratogenicity: No information found.

Section 12: Ecological Information

Toxicity to fish: LC50 - Oncorhynchus mykiss (rainbow trout) - 42,5 mg/l - 96,0 h.
Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna (Water flea) - > 100 mg/l - 48 h.
Ecotoxicity (aquatic and terrestrial): Toxic to aquatic life with long lasting effects.
Persistence and Degradability: Not available.
Mobility: Not available.
Results of PBT and vPvB assessment: Not available.

Section 13: Disposal Considerations

Check with all applicable local, regional, and national laws and regulations.

Section 14: Transport Information

DOT USA and ADR/RID Europe:
UN-No: UN3077
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper technical name: (Cryolite)
Hazard Class: 9; Packing Group: III
TDG:
UN-No: UN3077
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper technical name: (Cryolite)
Hazard Class: 9; Packing Group: III
IATA
UN-No: UN3077
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper technical name: (Cryolite)
Hazard Class: 9; Packing Group: III
IMDG/IMO
UN-No: UN3077
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper technical name: (Cryolite)
Hazard Class: 9; Packing Group: III

Section 15: Regulatory Information

USA:
SARA 313 Components
: Not Listed
SARA 311/312 Hazard Categories: Acute Health Hazard, Chronic Health Hazard
California Proposition 65: Not listed.

Section 16: Other Information

European Labeling in Accordance with EC Directives:
H332: Harmful if inhaled.
H372 Causes damage to organs through prolonged or repeated exposure.
H411: Toxic to aquatic life with long lasting effects.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xn Harmful
N Dangerous for Environment.
Risk Phrase:
R20 Harmful by inhalation.
R48 Danger of serious damage to health by prolonged exposure.
R 51/53 Toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment.

Disclaimer:
**************************
Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
**************************


Potassium Cryolite or Tripotassium Hexafluoroaluminate SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet
11-Oct-20

Section 1: Product and Company Identification

Product Name & Other Names: Potassium Cryolite or Tripotassium Hexafluoroaluminate.
CAS No.: 13775-52-5
EINECS, EC Number: 237-409-0
Molecular Weight: 258.27
Chemical Formula: K3AIF6
Relevant uses and uses advised against (if any): Laboratory chemicals, Manufacture of substances
Supplier: As per letterhead.

Section 2: Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Inhalation (Category 4), H332
Skin irritation (Category 2), H315
Eye irritation (Category 2), H319
Specific target organ toxicity - single exposure (Category 3), H335
Specific target organ toxicity - repeated exposure (Category 1), H372
Hazardous to the aquatic environment, acute hazard (Category 3), H402

Labeling according to GHS & Regulation (EC) No 1272/2008

GHS Label Elements
Irritant
Irritant

GHS Label Elements
Health Hazard
Health Hazard

Signal Words: Danger

Hazard statements:
H332: Harmful if inhaled.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H372 Causes damage to organs through prolonged or repeated exposure.
H402: Harmful to aquatic life.

Precautionary statements:
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264 Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P314: Get Medical advice/attention if you feel unwell.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308+313: IF exposed or concerned: Get medical advice/attention.
P337+313: If eye irritation persists get medical advice/attention.
P342+311: If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
P391: Collect spillage.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/regional/national/international regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
Xn Harmful
Xi Irritant
R20 Harmful by inhalation
Risk Phrases:
R36/37/38 Irritating to eyes, respiratory system and skin.
R48 Danger of serious damage to health by prolonged exposure.
R52 Harmful to aquatic organisms.

Section 3: Composition / Information on Ingredients

Product Name & Other Names: Potassium Cryolite or Tripotassium Hexafluoroaluminate.
CAS No.: 13775-52-5
EINECS, EC Number: 237-409-0

Section 4: First Aid Measures

Always seek medical attention after first aid measures are provided

Eyes: Immediately flush eyes with excess water for 15 minutes, lifting lower and upper eyelids occasionally.
Skin: Immediately flush skin with excess water for 15 minutes while removing contaminated clothing.
Ingestion: Call Emergency Medical immediately. Rinse mouth with cold water. Give victim 1-2 cups of water or milk to drink. Induce vomiting immediately.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration.
Notes to Physician: Treat symptomatically.

Section 5: Fire Fighting Measures

It is non-flammable solid.
Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide.
Protective equipment and precautions for firefighters: Use water spray, foam, or dry chemical to extinguish fire. Firefighters should wear full fire fighting turn-out gear and respiratory protection. Cool container with water spray.
Special hazards arising from the substance: Hydrogen fluoride, Potassium oxides, Aluminum oxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes.

Section 6: Accidental Release Measures

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

Section 7: Handling and Storage

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, strong bases, and strong acids.

Section 8: Exposure Controls / Personal Protection

Exposure guidelines:
USA-OSHA PEL: (Vacated) TWA 2.5 mg/m3 (as F) (listed under Fluorides)
USA-NIOSH: TWA 2.5 mg/m3 (as F) (listed under Fluorides).
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Section 9: Physical and Chemical Properties

Physical state and appearance: White or off-white powder.
Odor: Odorless.
Odor threshold: Not available.
pH (1% soln/water): around 6.
Relative density: 2.8 approximately.
Melting Point: 1025C.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Very slightly soluble in water.
Viscosity: Not available.
Molecular Weight: 258.27
Chemical Formula: K3AIF6

Section 10: Stability and Reactivity

Avoid heat and ignition sources.
Stability: Stable under normal conditions of use and storage.
Incompatibility: Heat and strong oxidizing agents, strong bases, and strong acids. Heat.
Hazardous Decomposition Products: Hydrogen fluoride, Potassium oxides, Aluminum oxide.
Hazardous Polymerization: Has not been reported.

Section 11: Toxicology Information

LD50 Oral - Rat - >2000 mg/kg.
Carcinogenicity: This product does not contain any ingredient designated as probable or suspected human carcinogens by ACGIH.
Reproductive toxicity: No information found.
Developmental Effects: No information found.
Teratogenicity: No information found.

Section 12: Ecological Information

Toxicity to fish: LC50 - 96 h : > 10 mg/l - Brachydanio rerio (zebrafish) static test.
Toxicity to daphnia and other aquatic invertebrates: EC50 - 48 h : 22.9 mg/l - Daphnia magna (Water flea).
Ecotoxicity (aquatic and terrestrial): Harmful to aquatic life with long lasting effects.
Persistence and Degradability: Not available.
Mobility: Not available.
Results of PBT and vPvB assessment: Not available.

Section 13: Disposal Considerations

Check with all applicable local, regional, and national laws and regulations.

Section 14: Transport Information

DOT USA and ADR/RID Europe: Not regulated.
TDG: Not regulated.
IATA: Not regulated.
IMDG/IMO: Not regulated.

Section 15: Regulatory Information

USA:
SARA 313 Components
: Not Listed
SARA 311/312 Hazard Categories: Acute Health Hazard, Chronic Health Hazard
California Proposition 65: Not listed.

Section 16: Other Information

European Labeling in Accordance with EC Directives:
H332: Harmful if inhaled.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H372 Causes damage to organs through prolonged or repeated exposure.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
Xn Harmful
Xi Irritant
Risk Phrases:
R20 Harmful by inhalation
R36/37/38 Irritating to eyes, respiratory system and skin.
R48 Danger of serious damage to health by prolonged exposure.
R52 Harmful to aquatic organisms.

Disclaimer:
**************************
Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
**************************


Lithium Cryolite or Trilithiumhexafluoroaluminate SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet
11-Oct-20

Section 1: Product and Company Identification

Product Name & Other Names: Lithium Cryolite or Trilithiumhexafluoroaluminate.
CAS No.: 13821-20-0
EINECS, EC Number: 237-509-4
Molecular Weight: 161.79
Chemical Formula: Li3AlF6
Relevant uses and uses advised against (if any): Laboratory chemicals, Manufacture of substances
Supplier: As per letterhead.

Section 2: Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Oral (Category 4), H302
Acute toxicity, Inhalation (Category 3), H331
Specific target organ toxicity - repeated exposure (Category 1), H372
Hazardous to the aquatic environment, acute hazard (Category 3), H402

Labeling according to GHS & Regulation (EC) No 1272/2008

GHS Label Elements
Toxic
Toxic

GHS Label Elements
Health Hazard
Health Hazard

Signal Words: Danger

Hazard statements:
H302: Harmful if swallowed.
H331: Toxic if inhaled
H372 Causes damage to organs through prolonged or repeated exposure.
H402: Harmful to aquatic life.

Precautionary statements:
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264 Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P285: In case of inadequate ventilation wear respiratory protection.
P330 : Rinse mouth
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P304+341: IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308+313: IF exposed or concerned: Get medical advice/attention.
P337+313: If eye irritation persists get medical advice/attention.
P342+311: If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
P391: Collect spillage.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/regional/national/international regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Risk Phrase:
T Toxic
Xn Harmful
Risk Phrase:
R22 Harmful if swallowed.
R23 Toxic by inhalation.
R48 Danger of serious damage to health by prolonged exposure.
R52 Harmful to aquatic organisms.

Section 3: Composition / Information on Ingredients

Product Name & Other Names: Lithium Cryolite or Trilithiumhexafluoroaluminate.
CAS No.: 13821-20-0
EINECS, EC Number: 237-509-4

Section 4: First Aid Measures

Always seek medical attention after first aid measures are provided

Eyes: Immediately flush eyes with excess water for 15 minutes, lifting lower and upper eyelids occasionally.
Skin: Immediately flush skin with excess water for 15 minutes while removing contaminated clothing.
Ingestion: Call Emergency Medical immediately. Rinse mouth with cold water. Give victim 1-2 cups of water or milk to drink. Induce vomiting immediately.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration.
Notes to Physician: Treat symptomatically.

Section 5: Fire Fighting Measures

It is non-flammable solid. When heated to decomposition, emits fumes. Avoid contamination with oxidizing agents.
Protective equipment and precautions for firefighters: Firefighters should wear full fire fighting turn-out gear and respiratory protection. Cool container with water spray.
Special hazards arising from the substance: Lithium oxide, Aluminum oxides, Hydrogen fluoride and Toxic fumes.
Suitable fire fighting medium: Use water spray, dry sand, foam or dry chemical or carbon dioxide to extinguish fire. Use water spray to cool unopened containers.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes.

Section 6: Accidental Release Measures

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

Section 7: Handling and Storage

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, strong acids, and strong bases.

Section 8: Exposure Controls / Personal Protection

Exposure guidelines: TWA: 0.1 mg/m3 occupation exposure limits. Provide appropriate exhaust ventilation at places where dust is formed.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Section 9: Physical and Chemical Properties

Physical state and appearance: White to off-white solids, (Crystals  or Powder).
Odor: Odorless..
Odor threshold: Not available.
pH (1% soln/water): Around 6.
Relative density: about 2.6
Melting Point: 600C literature.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility(ies): Not available.
Viscosity: Not available.
Molecular Weight: 161.79
Chemical Formula: Li3AlF6

Section 10: Stability and Reactivity

Avoid heat and ignition sources.
Stability: Stable under normal conditions of use and storage. Decomposes by reaction with strong acids., Decomposes on heating.
Incompatibility: Heat, strong oxidizing agents strong acids and strong bases.
Hazardous Decomposition Products: Lithium oxide, Aluminum oxides, Hydrogen fluoride and Toxic fumes.
Hazardous Polymerization: Has not been reported.

Section 11: Toxicology Information

LD50 [oral, rat female]; 300 - 2,000 mg/kg.
LD50 : > 2,000 mg/kg - Rat , male and female
LC50 - 4 h (aerosol rat , male and female) : 0.5 - 1 mg/l
Carcinogenicity: Not listed as by IARC, NTP, OSHA.
Reproductive toxicity: Not available.
Germ cell mutagenicity: Not available.
Specific target organ toxicity - repeated exposure: Causes damage to organs through prolonged or repeated exposure.
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

Section 12: Ecological Information

Toxicity to fish: LC50 - 96 h : > 100 mg/l - Gobiocypris rarus (rare gudgeon) semi-static test.
Toxicity to daphnia and other aquatic invertebrates: EC50 - 48 h : 18.2 mg/l - Daphnia magna (Water flea) static test.
Ecotoxicity (aquatic and terrestrial): Harmful to terrestrial and aquatic plants and animals. Do not release to environment.
Persistence and degradability: No data available.
Results of PBT and vPvB assessment: No data available.
Mobility in soil: No data available.

Section 13: Disposal Considerations

Check with all applicable local, regional, and national laws and regulations.

Section 14: Transport Information

DOT USA and ADR/RID Europe:
UN-No: UN3288
Proper Shipping Name: TOXIC SOLID, INORGANIC, N.O.S. (Trilithium hexafluoroaluminate).
Hazard Class: 6.1; Packing Group: III
TDG:
UN-No: UN3288
Proper Shipping Name: TOXIC SOLID, INORGANIC, N.O.S. (Trilithium hexafluoroaluminate).
Hazard Class: 6.1; Packing Group: III
IATA
UN-No: UN3288
Proper Shipping Name: TOXIC SOLID, INORGANIC, N.O.S. (Trilithium hexafluoroaluminate).
Hazard Class: 6.1; Packing Group: III
IMDG/IMO
UN-No: UN3288
Proper Shipping Name: TOXIC SOLID, INORGANIC, N.O.S. (Trilithium hexafluoroaluminate).
Hazard Class: 6.1; Packing Group: III

Section 15: Regulatory Information

USA:
SARA Title III, Section 302
: Not listed.
SARA Title III, Section 313: Not listed.
SARA 311/312 Hazard Categories: Acute Health Hazard, Chronic Health Hazard
California Proposition 65: Not listed.

Section 16: Other Information

European Labeling in Accordance with EC Directives:
H302: Harmful if swallowed.
H331: Toxic if inhaled
H372 Causes damage to organs through prolonged or repeated exposure.
H402: Harmful to aquatic life.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Risk Phrase:
T Toxic
Xn Harmful
Risk Phrase:
R22 Harmful if swallowed.
R23 Toxic by inhalation.
R48 Danger of serious damage to health by prolonged exposure.
R52 Harmful to aquatic organisms.

Disclaimer:
**************************
Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
**************************