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Calcium Saccharin USP NF FCC Food Grade Manufacturers, SDS GHS MSDS Sheet

Calcium Saccharin: CAS Number: 6381-91-5, EINECS EC Number: yyyyy, Molecular Formula: C14H8CaN2O6S2-3.5H2O, Molecular Weight: 467.48, HS Code ---**

For SDS MSDS Sheet Click
SDS MSDS Sheet of Calcium Saccharin Manufacturers

Calcium Saccharin
USP NF FCC Food Grade
Calcium saccharine

Saccharin is primarily produced in two types i.e. soluble and insoluble saccharin. The soluble saccharin (in water) is called Sodium Saccharin whereas insoluble saccharin is called Insoluble Saccharin. Calcium Saccharin, is also sometimes used, especially by people restricting their dietary sodium intake. Calcium Saccharin is a sweeteners that has been used in food for many years. In cosmetics and personal care products, Calcium Saccharin is used as flavoring agents in the formulation of dental products, mouthwashes and lipstick.

General Specifications of Calcium Saccharin:
Appearance: white crystal or powder
Purity: 98% min.
Melting point: 226C - 230C
Moisture: 15% max.
Arsenic: 0.0003% max.
Heavy metals: 0.001% max.
Arsenous salt: 0.0002% max.
Selenium: 0.003% max.


Saccharin Sodium USP NF is also offered. As per the monograph of Saccharin Sodium BP EP Ph Eur its content analyses between 99 to 101% assay and meets the requirement of trace impurities specified in the monograph.


Calcium Saccharin FCC Food Grade
1,2-Benzisothiazolin-3-one 1,1-Dioxide Calcium Salt
C14H8CaN2O6S2-31⁄2H2O Formula wt 467.48
INS: 954 CAS: anhydrous [6485-34-3]

DESCRIPTION
Calcium Saccharin occurs as white crystals or as a white, crystalline powder. One gram is soluble in 1.5 mL of water.
Function: Nonnutritive sweetener.

REQUIREMENTS
Identification:
A. Dissolve about 100 mg of sample in 5 mL of a 1:20 solution of sodium hydroxide, evaporate to dryness, and gently fuse the residue over a small flame until ammonia no longer evolves. After the residue has cooled, dissolve it in 20 mL of water, neutralize the solution with 2.7 N hydrochloric acid, and filter. Add 1 drop of ferric chloride to the filtrate. A violet color appears.
B. Mix 20 mg of sample with 40 mg of resorcinol, cautiously add 10 drops of sulfuric acid, and heat the mixture in a liquid bath at 200C for 3 min. After cooling, add 10 mL of water and an excess of 1 N sodium hydroxide. A fluorescent green liquid results.
C. A1:10 aqueous solution gives positive tests for Calcium.
D. Add 1 mL of hydrochloric acid to 10 mL of a 1:10 aqueous solution. A crystalline precipitate of saccharin forms. Wash the precipitate well with cold water, and dry at 105C for 2 h. The saccharin thus obtained melts between 226C and 230°C.
Assay: Not less than 98.0% and not more than 101.0% of C14H8CaN2O6S2, calculated on the anhydrous basis.
Benzoate and Salicylate: Passes test.
Lead: Not more than 2 mg/kg.
Readily Carbonizable Substances: Passes test.
Selenium: Not more than 0.003%.
Toluenesulfonamides: Not more than 0.0025%.
Water: Not more than 15.0%.

Manufacturers:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) 91-22-23770100, 23726950
Current Date Time in India GMT+5:30

e-mail: info@mubychem.com

USA & Canadian Customers may
e-mail: usa@mubychem.com
Call toll-free 1-844-682-9243 (1-844-MUBYCHEM)

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Last 25 December, 2017

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Calcium Saccharin SDS MSDS Sheet, Material Safety Data Sheet

1. Product Identification
Product: Calcium Saccharin.
CAS Number: 6381-91-5
Molecular Weight: 467.48
Chemical Formula: C14H8CaN2O6S2-3.5H2O
Relevant Uses: Industrial use only.
Recommended usage: Industrial Manufacturing.
Suppliers: As per letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910

Classification according to Regulation (EC) No 1272/2008
Skin corrosion/irritation Category 2
Serious eye irritation/damage Category 2A
Acute toxicity, inhalation Category 5
Specific target organ toxicity, single exposure; Respiratory tract irritation Category 3
Labeling according GHS USA & Regulation (EC) No 1272/2008

GHS Label Elements
Irritant
Irritant

Signal Word: Warning

Hazard statements:
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H333: May be harmful if inhaled.
H335: May cause respiratory irritation.

Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P264: Wash thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P362: Take off contaminated clothing and wash before reuse.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P304+P312: IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P337+313: If eye irritation persists get medical advice/attention.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols: Xi
Risk Phrases: R36/37/38 Irritating to eyes, respiratory system and skin.
Safety Phrases: S24/25- Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39- Wear suitable protective clothing, gloves and eye/face protection. S45- In case of accident or if you feel unwell, seek medical advice immediately.
For the full text of the H-statements and R-phrases mentioned in this Section, see Section 16.

3. Composition/Information on Ingredients

Product: Calcium Saccharin.
CAS Number: 6381-91-5
Percent: 97 - 100%

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

5. Fire Fighting Measures

Flammability of the Product: May be combustible at high temperature.
Products of Combustion: Fumes, Calcium Oxide, Carbon dioxide & Carbon Monoxide, Nitrogen Oxides and Sulfur Oxides.
Fire: Slightly flammable on heating.
Explosion: Slightly explosive on heating.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes. Containers may explode on heating

6. Accidental Release Measures

Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Avoid touching the spilled material. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow evacuating through the sanitary system.

7. Handling and Storage

Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment.
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Wash hands thoroughly after handling. Provide appropriate exhaust ventilation at places where dust is formed. If you feel unwell, seek medical attention.
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: Not Specified.
Ventilation System
: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: Colorless white powder or crystals.
Odor: Faint to None.
Solubility: It is soluble in water.
pH: NA
Density: NA
Molecular Weight:
467.48
Chemical Formula: C14H8CaN2O6S2-3.5H2O
Boiling Point: NA
Melting Point: NA

10. Stability and Reactivity

Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits Fumes, Calcium Oxide, Carbon dioxide & Carbon Monoxide, Nitrogen Oxides and Sulfur Oxides.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents.
Conditions to Avoid: Incompatibles and moisture.

11. Toxicological Information

Acute toxicity: Harmful if inhaled. Irritating to skin and eyes.
Toxicity data: ORL-RAT LD50: NA
Carcinogenic Effects: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Mutagenic Effects: NA
Teratogenic Effects: NA
Developmental Toxicity: NA.
12. Ecological Information
Environmental Fate: Not classified as environmentally hazardous.
Environmental Toxicity: This chemical is expected to cause little oxygen depletion in aquatic systems.
BOD5 and COD: Not available.
Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information

USA DOT & ADR/RID Classification: Not regulated.
Canada TDG Classification: Not regulated.
IATA: Not regulated.

15. Regulatory Information

USA:
SARA 302 Components
: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 311/312: Acute Health Hazard, Chronic Health Hazard.
SARA 313 Components: No chemicals in this material are subject to the reporting requirements
CAS# 544-17-2 is not present on state lists from CA, PA, MN, MA, FL, or NJ
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

Section 16 - Additional Information

European Labeling in Accordance with EC Directives:
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H333: May be harmful if inhaled.
H335: May cause respiratory irritation.
Hazard Symbols: Xi
Risk Phrases: R36/37/38 Irritating to eyes, respiratory system and skin.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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