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Calamine IP BP USP Grade Manufacturers, SDS GHS MSDS Sheet

Calamine: CAS Number: ------, EINECS EC Number: ------, Molecular Formula: ------, Molecular Weight: ------, HS Code ---**

For SDS MSDS Sheet Click
SDS MSDS Sheet of Calamine USP Manufacturers

Calamine powder

Calamine BP
Action and use: Antipruritic.
Calamine is a basic zinc carbonate suitably coloured with iron(III) oxide.
An amorphous, impalpable, pink or reddish brown powder, the colour depending on the variety and amount of iron(III) oxide present and the process by which it is incorporated. Practically insoluble in water. It dissolves with effervescence in hydrochloric acid .
A. Yields the reactions characteristic of carbonates.
B. To 2 g add 5 ml of hydrochloric acid and heat to boiling; if necessary, add hydrochloric acid drop wise until a bright yellow solution is obtained. Cool and add 13.5 M ammonia until the first sign of precipitate (solution A). The solution yields characteristic of iron salts. Dilute 1 ml of solution A to 5 ml with water; the solution yields the reaction characteristic of zinc salts.
Calcium: Dissolve 0.50 g in a mixture of 10 ml of water and 2.5 ml of glacial acetic acid and filter. To 0.5 ml of the filtrate add 15 ml of 5 M ammonia and 2 ml of a 2.5% w/v solution of ammonium oxalate and allow to stand for 2 minutes. The solution remains clear.
Soluble barium salts: To the remainder of the filtrate obtained in the test for Calcium add 2 ml of 1 M sulphuric acid and allow to stand for 5 minutes. The solution remains clear.
Lead: Not more than 150 ppm when determined by atomic absorption spectrophotometry ,
Chloride: Dissolve 0.15 g in water with the addition of 1 ml of nitric acid , filter and dilute to 30 ml with water. The resulting solution complies with the limit test for chlorides (0.07%).
Sulphate: Dissolve 0.1 g in water with the addition of 3 ml of 2 M hydrochloric acid , filter and dilute to 60 ml with water. The resulting solution complies with the limit test for sulphates, (0.6%).
Ethanol-soluble dyes: Shake 1.0 g with 10 ml of ethanol (90%) and filter. The filtrate is colourless,.
Matter insoluble in hydrochloric acid: Dissolve 1 g in 20 ml of warm 2 M hydrochloric acid and filter. The residue, when washed with water and dried to constant weight at 105C, weighs not more than 10 mg.
Water-soluble dyes: Shake 1.0 g with 10 ml of water and filter. The filtrate is colourless.
Residue on ignition: 68.0 to 74.0%, when ignited at a temperature not lower than 900C until, after further ignition, two successive weighing do not differ by more than 0.2% of the weight of the residue. Use 1 g.

Calamine USP
Iron oxide (Fe2O3), mixture with zinc oxide.
Calamine  [8011-96-9].
Calamine is Zinc Oxide with a small proportion of ferric oxide, and contains, after ignition, not less than 98.0 percent and not more than 100.5 percent of zinc oxide (ZnO).
A: Treat 1 g with 10 mL of 3 N hydrochloric acid, and filter: the filtrate responds to the tests for Zinc .
B: Treat 1 g with 10 mL of 3 N hydrochloric acid, heat to boiling, and filter: the filtrate assumes a reddish color upon the addition of ammonium thiocyanate.
Microbial limits: It meets the requirements of the tests for absence of Staphylococcus aureus and Pseudomonas aeruginosa.
Loss on ignition: Weigh accurately about 2 g, and ignite at 500 degrees to constant weight: it loses not more than 2.0% of its weight.
Acid-insoluble substances: Dissolve 2.0 g in 50 mL of 3 N hydrochloric acid. If an insoluble residue remains, collect it on a tared filter, wash with water, dry at 105 degree for 1 hour, cool, and weigh: the weight of the residue does not exceed 40 mg (2.0%).
Alkaline substances: Digest 1.0 g with 20 mL of water on a steam bath for 15 minutes, filter, and add 2 drops of phenolphthalein: if a red color is produced, not more than 0.20 mL of 0.10 N sulfuric acid is required to discharge it.
Arsenic: 8 ppm.
Calcium: Digest 1 g in 25 mL of 3 N hydrochloric acid for 30 minutes, filter to remove the insoluble ferric oxide, and add 6 N ammonium hydroxide to the filtrate until the precipitate first formed is re-dissolved, then add 5 mL more of 6 N ammonium hydroxide. To 10 mL of this solution add 2 mL of ammonium oxalate: not more than a slight turbidity is produced.
Calcium or magnesium: To another 10-mL portion of the solution prepared for the test for Calcium add 2 mL of dibasic sodium phosphate: not more than a slight turbidity is produced.
Lead: To 1 g add 15 mL of water, stir, then add 3 mL of glacial acetic acid, and warm on a steam bath until dissolved. Filter, and add 5 drops of potassium chromate: no turbidity is produced.
Assay: Digest about 1.5 g of freshly ignited Calamine, accurately weighed, with 50.0 mL of 1 N
sulfuric acid, applying gentle heat until no further solution occurs. Filter the mixture, and wash the residue on the filter with hot water until the last washing is neutral to litmus paper. To the combined filtrate and washings add 2.5 g of ammonium chloride, cool, add methyl orange, and titrate with 1 N sodium hydroxide. Each mL of 1 N sulfuric acid is equivalent to 40.69 mg of ZnO.

Calamine IP
IP grade calamine is also ofered.

For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.


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Last 18 August, 2017

List of All the IP BP USP FCC ACS Grades of Chemicals
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Borax; Sodium Borate Boric Acid
Calcium Acetate Calcium Carbonate
Calcium Chloride Calcium Hydroxide
Calcium Levulinate Calcium Oxide
Calcium Saccharate Calcium Sulfate
Carbamide Peroxide Carmellose
Carmellose Calcium Carmellose Sodium
Chromic Chloride Citric Acid

Copper Sulfate, Cupric Sulphate

Cupric or Copper Chloride
Ferric Chloride Hexahydrate Fumaric Acid
Gentian Violet Glacial acetic Acid
Magnesium Chloride Hexa & Anhydrous Magnesium Oxide
Magnesium Stearate Magnesium Sulfate Hepta & Anhydrous
Maleic Acid Malic Acid BP USP
Manganese Chloride Manganese Sulfate
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Oleic Acid Potash  Alum
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Potassium Carbonate Potassium Chloride
Potassium Hydroxide Pellets Potassium Iodide
Potassium Nitrate Propionic Acid
Propylene Carbonate  
Selenious acid Sodium Acetate
Sodium Bicarbonate Sodium Butyrate
Sodium Carbonate Sodium Feredetate
Sodium Fluoride Sodium Hydroxide Pellets
Sodium Molybdate Sodium Perborate
Sodium Propionate Sodium Selenite Pentahydrate
Sodium Sulfate Sodium Tartrate Dihydrate
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Stannous Fluoride  
Tartaric Acid Urea
Zinc Carbonate Zinc Chloride
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D-Glucuronolactone Hydrazine Hydrate
DC Directly Compressible Calcium Carbonate Encapsulated Citric Acid
Encapsulated Fumaric Acid Encapsulated Sodium Bicarbonate
Isatoic Anhydride  
Magnesium Butyrate Octyldodecanol
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Sodium Bisulphate Skatole; 3-methylindole
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Zinc Chloride Zinc Sulphate

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Calamine SDS MSDS Sheet, Material Safety Data Sheet

Section 1: Chemical Product and Company Identification
Product Name: Calamine
CAS Number: Mixture also called 8011-96-9
Recommended usage: Industrial Manufacturing.
Suppliers: As per letterhead.

Section 2: Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Hazardous to the aquatic environment, long-term hazard Category 1 (H410)

Labeling according GHS & Regulation (EC) No 1272/2008

GHS Label Elements
Aquatic Toxicity
Aquatic Toxicity

Signal Words: Warning

Hazard statements:
H410: Very toxic to aquatic life with long lasting effects

Precautionary statements: P363, P501
P273: Avoid release to the environment.
P391: Collect spillage.
P501: Dispose of contents/container in accordance with local/regional/national/international regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard symbol(s): N
R-phrase(s): R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S-phrase(s): S60 This material and its container must be disposed of as hazardous waste.
S61 Avoid release to the environment.
For the full text of the H-statements & R-phrases mentioned in this Section, see Section 16.

Section 3: Composition and Information on Ingredients

Ingredient 1: Zinc Oxide
CAS Number: 1314-13-2
EINECS EC-No.: 215-222-5
% by Weight
: >90%
Ingredient 2: Diiron trioxide
CAS Number: 1309-37-1
EINECS EC-No.: 215-222-5
% by Weight
: <5%

Section 4: First Aid Measures

Always get medical attention after the first aid is over.

Eye Contact: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin Contact: After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cover the irritated skin with an emollient. If irritation persists, seek medical attention.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
If swallowed: Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.
Auto-Ignition Temperature: Not applicable.
Products of Combustion:
Zinc Iron & their oxide.
Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not available.
Fire Fighting Media and Instructions: Not applicable. However wear self contained breathing apparatus for fire-fighting if necessary.

Section 6: Accidental Release Measures

Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements. Evacuate personnel to safe areas. Avoid breathing dust.
Large Spill: Use a shovel to put the material into a convenient waste disposal container. Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

Section 7: Handling and Storage
Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with skin and eyes. Avoid ingestion and inhalation.
Storage: Store in a cool, dry place. Keep containers tightly closed.

Section 8: Exposure Controls/Personal Protection

Occupational Exposure Limits for Zinc Oxide:
USA ACGIH, ACGIH TWA (mg/m³): 2 mg/m³
USA ACGIH, ACGIH STEL (mg/m³): 10 mg/m³
USA OSHA, OSHA PEL (TWA) (mg/m³): 5 mg/m³
USA NIOSH, NIOSH REL (TWA) (mg/m³): 5 mg/m³
Occupational Exposure Limits for Diiron trioxide:
USA. ACGIH Threshold Limit Values (TLV) (mg/m3) (TWA) 5
Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill: Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.

Section 9: Physical and Chemical Properties

Physical state and appearance: Calamine is pink-yellowish solid. (Powdered solid.)
Odor: Odorless.
Taste: Not available.
pH (1% soln/water): Not available..
Boiling Point: Not available.
Melting Point: Not available..
Specific Gravity: 5.6
Solubility: Very slightly soluble in cold water, hot water.

Section 10: Stability and Reactivity Data

Stability: It is stable.
Incompatibility with various substances: Strong oxidizing agents & acids.
Polymerization: No.

Section 11: Toxicological Information

LD50 Oral: Not available.
LC50: Not available.
Carcinogenicity: Not listed as a suspected/confirmed carcinogen by ACGIH, IARC, NTP, SHA.
Other Toxic Effects on Humans: Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation.
Section 12: Ecological Information
Toxicity to fish: LC50 - Not available.
Toxicity to daphnia and other aquatic invertebrates: Not available.
BOD5 and COD: Not available.
Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: Insoluble in water. (can be separated from aqueous systems by sedimentation and/or filtration techniques). Predicted to have low mobility in soil. An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Very toxic to aquatic life.

Section 13: Disposal Considerations

Waste Disposal: Dispose all waste in accordance with legal requirement.

Section 14: Transport Information

DOT Classification: Not a DOT controlled material (United States).
Transport hazard Classes: 9
Packing group: III
Environmental hazards: Yes
Transport hazard Classes: 9
Packing group: III
Environmental hazards: Yes
Transport hazard Classes: 9
Packing group: III
Environmental hazards: Yes

Section 15: Other Regulatory Information

SARA 302 Components
: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 toxic chemical notification and release reporting: Zinc oxide.
California Prop. 65: Not applicable

Section 16 - Additional Information

H410 = Very toxic to aquatic life with long lasting effects
N = Dangerous for the Environment
R50/53 = Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.