4-Chlorobenzaldehyde or p-Chlorobenzaldehyde or para-Chlorobenzaldehyde Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of 4-Chlorobenzaldehyde or p-Chlorobenzaldehyde, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc.

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4-Chlorobenzaldehyde or p-Chlorobenzaldehyde or para-Chlorobenzaldehyde: CAS Number: 104-88-1, EINECS EC Number: 203-247-4, Molecular Formula: C7H5ClO, Molecular Weight: 140.57, HS Code 2913 00 00

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SDS MSDS Sheet of 4-Chlorobenzaldehyde or p-Chlorobenzaldehyde or para-Chlorobenzaldehyde Manufacturers

4-Chlorobenzaldehyde
p-Chlorobenzaldehyde or para-Chlorobenzaldehyde Pure Suppliers
4-Chlorobenzaldehyde

4-Chlorobenzaldehyde or p-Chlorobenzaldehyde or para-Chlorobenzaldehyde is used as an intermediate for the manufacture of dyestuffs, optical brighteners, pharmaceuticals, agricultural chemicals and metal finishing products.

General Properties and Specifications of 4-Chlorobenzaldehyde or p-Chlorobenzaldehyde or para-Chlorobenzaldehyde:
CAS Number: 104-88-1.
Molecular Formula: C7H5ClO
Molecular weight: 140.57
Appearance: White to yellowish powder or crystals.
Assay: 98.5% minimum.
Relative density: around 1.2
Melting point: 46C to 47C.
Boiling Point: 213C to 216C.
Flash point: 87C.
Auto-ignition temperature: 237C.
Solubility: Insoluble in water.
Storage: Store below 30C.

We also manufacture and supply as under:

2-Bromo-5-Hydroxybenzaldehyde

2-Chlorobenzaldehyde

4-Chlorobenzaldehyde

2,4 Dichlorobenzaldehyde

4-Hydroxybenzaldehyde

Epichlorohydrine

Benzaldehyde

Benzyl Chloride

Benzalkonium Chloride

Benzyl Bromide

Benzophenone

Benzyl Alcohol

Benzoic Acid

Benzyl Benzoate

Benzoyl Peroxide

Butyraldehyde

Glutaraldehyde Solution

Propionaldehyde

Formaldehyde Solution.

Manufacturers:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30

e-mail: info@mubychem.com

USA, Canada, Mexico and other American
neighbouring buyers may
e-mail: us@mubychem.com
Call toll-free 1-844-682-9243 (1-844-MUBYCHEM)

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Last 25 August, 2022

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4-Chlorobenzaldehyde or p-Chlorobenzaldehyde or para-Chlorobenzaldehyde SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 28-Nov-20

1. Product Identification

Product Name & Other Names: 4-Chlorobenzaldehyde or p-Chlorobenzaldehyde or para-Chlorobenzaldehyde.
CAS No.: 104-88-1
EINECS EC Number: 203-247-4
Molecular Formula: C7H5ClO
Molecular Weight: 140.57
Relevant uses and uses advised against (if any): Laboratory and Industrial Use.
Supplier: As per letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, oral Category 4, H302
Skin corrosion/irritation Category 2, H315
Skin sensitization Category 1, H317
Serious eye damage/eye irritation Category 2A, H319
Hazardous to the aquatic environment, long-term hazard Category 2, H411

Labeling according GHS USA & Regulation (EC) No 1272/2008

GHS Label Elements
irritant.png
Irritant

GHS Label Elements
marinepollutant.png
Aquatic Toxicity

Signal Words: Warning

Hazard Statements:
H302: Harmful if swallowed.
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
H411: Toxic to aquatic life with long lasting effects.

Precautionary Statements:
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash contaminated parts thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P301+P310: IF SWALLOWED: Immediately call a POSION CENTER or doctor/physician.
P302+352: IF ON SKIN: Wash with plenty of soap and water.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P333+313: If skin irritation or a rash occurs: Get medical advice/attention.
P403+233+235: Store in a well-ventilated place. Keep container tightly closed. Keep cool.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/national regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xn = Harmful
Xi = Irritant.
N = Dangerous for the environment.
Risk Phrase:
R22 Harmful if swallowed
R36/38 Irritating to eyes and skin.
R43 May cause sensitization by skin contact
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

3. Composition/Information on Ingredients

Product Name & Other Names: 4-Chlorobenzaldehyde or p-Chlorobenzaldehyde or para-Chlorobenzaldehyde.
CAS No.: 104-88-1

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do not use mouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Get medical attention.
Ingestion: Rinse mouth. Do not induce vomiting without medical advice. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Never give anything by mouth to a victim who is unconscious or is having convulsions. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Use a mild soap if available. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. For minor skin contact, avoid spreading material on unaffected skin.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

5. Fire Fighting Measures

Products of Combustion: Carbon oxides, hydrogen chloride and fumes.
Fire Extinguishing Media: Water fog. Alcohol foam. Dry chemical. Polymer foam. Dry chemical powder. Carbon dioxide (CO2). Do not use a solid water stream as it may scatter and spread fire. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

6. Accidental Release Measures

Personal precautions, protective equipment, and emergency procedures: Ventilate area of leak or spill. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material. Keep out of low areas.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Move the containers to a safe and open area if the leak is irreparable. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container.
Small Spill: Avoid dust/mist formation. Avoid breathing dust/mist. Ensure adequate ventilation. Wipe up with absorbent material (e.g. cloth, fleece). Clean contaminated surface thoroughly.
Large Spill: Use a non-combustible material like vermiculite, sand, or earth to cover up the product and place into a container for later disposal.

7. Handling and Storage

Precautions for safe handling: Do not handle or store near an open flame, heat, or other sources of ignition. All equipment used when handling the product must be grounded. Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Avoid prolonged exposure. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents and oxidizing agents, strong bases, and reducing agents. Keep away from heat and sources of ignition. Keep containers tightly closed in a cool, well-ventilated place. Sensitivity to light. Store below 30C.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: Contains no substances with occupational exposure limit values.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: White to yellowish powder or crystals.
Odor: Not available.
Odor threshold: Not available.
pH: Not available.
Relative density: around 1.2
Melting  point/Freezing  point: 46C to 47C.
Initial boiling point and boiling range: 213C to 216C.
Flash point: 87C.
Auto-ignition temperature: 237C.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility  (water): Insoluble in water.
Viscosity: Not available.
Molecular Formula: C7H5ClO
Molecular Weight: 140.57

10. Stability and Reactivity

Stability: It is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits toxic fumes along with carbon oxides and hydrogen chloride when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Oxidizing agents, strong bases and reducing agents.
Conditions to Avoid: Avoid heat, sparks, open flames and other ignition sources. Contact with incompatible materials. Sensitivity to light.

11. Toxicological Information

Toxicity data:
LD50 Oral – Rat: 840 mg/kg.
LC50 Inhalation - Rat: > 0.241 mg/l; 4 h.
LD50 Dermal Rat: > 5,000 mg/kg
Carcinogenicity: Not expected to be hazardous by OSHA criteria.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

12. Ecological Information

Toxicity to fish: semi-static test LC50 Pimephales promelas (fathead minnow): 2.2 mg/l; 96 h.
Ecotoxicity: Components of this product have been identified as having potential environmental concerns.
Environmental effects: Hazardous to the aquatic environment, long-term hazard.
Aquatic toxicity: May cause long-term adverse effects in the aquatic environment.
Persistence and Degradability: Biodegradable.
Mobility: No information available.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with law.

14. Transport Information

DOT USA, TDG Canada & ADR/RID Europe:
UN number: UN 3077.
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (4-CHLOROBENZALDEHYDE).
Class 9; Packing group III.
IATA/ICAO & IMDG/IMO:
UN number: UN 3077.
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (4-CHLOROBENZALDEHYDE).
Class 9; Packing group III.

15. Regulatory Information

USA:
SARA 302 Components
: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components: Does not contain any chemical with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards: Acute Health Hazard. See section 2.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

Section 16 - Additional Information

European Labeling in Accordance with EC Directives:
H302: Harmful if swallowed.
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
H411: Toxic to aquatic life with long lasting effects.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xn = Harmful
Xi = Irritant.
N = Dangerous for the environment.
Risk Phrase:
R22 Harmful if swallowed
R36/38 Irritating to eyes and skin.
R43 May cause sensitization by skin contact
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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