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Formaldehyde Solution Formalin BP USP Grade Manufacturers, SDS GHS MSDS Sheet

Formaldehyde: CAS Number: 50-00-0, EINECS EC Number: -, Molecular Formula: HCHO, Molecular Weight: 30.03, HS Code ---**

For SDS MSDS Sheet Click
SDS MSDS Sheet of Formaldehyde Solution Manufacturers

Formaldehyde Solution
Pure BP USP Grade
Formaldehyde Solution

Formaldehyde is a naturally occurring organic compound with the formula CH2O (H-CHO). It is the simplest of the aldehydes (R-CHO) and is also known by its systematic name methanal. The common name of this substance comes from its similarity and relation to formic acid.

Formaldehyde Solution BP
Formaldehyde Solution (35 per cent), Ph Eur
CH2O -- 30.03 -- 50-00-0
Action and use: When suitably diluted, used in the treatment of warts.

Content: 34.5 per cent m/m to 38.0 per cent m/m of formaldehyde (CH2O; Mr 30.03). It contains methanol as stabiliser.

Appearance: Clear, colourless liquid.
Solubility: Miscible with water and with ethanol (96 per cent). It may be cloudy after storage.

A. Dilute 1 ml of solution S (see Tests) to 10 ml with water. To 0.05 ml of the solution add 1 ml of a 15 g/l solution of chromotropic acid sodium salt, 2 ml of water and 8 ml of sulphuric acid. A violet-blue or violet-red colour develops within 5 min.
B. To 0.1 ml of solution S add 10 ml of water. Add 2 ml of a 10 g/l solution of phenylhydrazine hydrochloride, prepared immediately before use, 1 ml of potassium ferricyanide solution and 5 ml of hydrochloric acid. An intense red colour is formed.
C. Mix 0.5 ml with 2 ml of water and 2 ml of silver nitrate solution  in a test-tube. Add dilute ammonia until slightly alkaline. Heat on a water-bath. A grey precipitate or a silver mirror is formed.
D. It complies with the limits of the assay.

Solution S: Dilute 10 ml, filtered if necessary, to 50 ml with carbon dioxide-free water.
Appearance of solution: Solution S is colourless.
Acidity: To 10 ml of solution S add 1 ml of phenolphthalein solution. Not more than 0.4 ml of 0.1 M sodium hydroxide is required to change the colour of the indicator to red.
Methanol: To pass Gas chromatography.
Sulphated ash: Maximum 0.1 per cent, determined on 1.0 g.

Into a 100 ml volumetric flask containing 2.5 ml of water and 1 ml of dilute sodium hydroxide solution, introduce 1.000 g of the solution to be examined, shake and dilute to 100.0 ml with water. To 10.0 ml of the solution add 30.0 ml of 0.05 M iodine. Mix and add 10 ml of dilute sodium hydroxide solution. After 15 min, add 25 ml of dilute sulphuric acid and 2 ml of starch solution. Titrate with 0.1 M sodium thiosulphate.
1 ml of 0.05 M iodine is equivalent to 1.501 mg of CH2O.

Formaldehyde Solution USP
CH2O 30.03
Formaldehyde [50-00-0].
Formaldehyde Solution in bulk containers contains not less than 37.0 percent, by weight, of formaldehyde (CH2O), with methanol added to prevent polymerization. Formaldehyde Solution in small containers (4 liters or less) contains not less than 36.5 percent, by weight, of formaldehyde (CH2O), with methanol present to prevent polymerization.

Packaging and storage: Preserve in tight containers, and preferably store at a temperature not below 15C.
Labeling: The label of bulk containers of the Solution directs the drug repackager to demonstrate compliance with the USP Assay limit for formaldehyde of not less than 37.0%, by weight, immediately prior to repackaging.

A: Dilute 2 mL with 10 mL of water in a test tube, and add 1 mL of silver-ammonia-nitrate: metallic silver is produced either in the form of a finely divided, gray precipitate, or as a bright, metallic mirror on the sides of the test tube.
B: Add 2 drops to 5 mL of sulfuric acid in which about 20 mg of salicylic acid has been dissolved, and warm the liquid very gently: a permanent, deep-red color appears.

Acidity: Measure 20.0 mL into a flask containing 20 mL of water, add 2 drops of bromothymol blue and titrate with 0.1 N sodium hydroxide: not more than 10.0 mL of 0.1 N sodium hydroxide is consumed.
Assay: Transfer about 3 mL of Solution to a tared flask containing 10 mL of water, insert the stopper in the flask tightly, and accurately determine the weight of the Solution taken. Slowly and quantitatively add a mixture of 50.0 mL of 1 N sodium hydroxide and 50 mL of hydrogen peroxide that has been previously neutralized to bromothymol blue with 1 N sodium hydroxide. Heat the contents of the flask cautiously on a steam bath for 15 minutes, shaking it occasionally with a rotary motion. Allow the mixture to cool, rinse the funnel and the inner wall of the flask with water, and after allowing it to stand for 30 minutes, add 2 to 5 drops of bromothymol blue and titrate the excess alkali with 1 N sulfuric acid. Perform a blank determination (see Residual Titrations under Titrimetry). Also make a correction based upon the acidity found in the test for Acidity. Each mL of 1 N sodium hydroxide is equivalent to 30.03 mg of CH2O.

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Last 14 August, 2017

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Fumaric Acid Ferrous Sulphate
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Gentian Violet Mannitol
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Magnesium Trisilicate Maleic Acid
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Potassium Chloride Potassium Gluconate
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Sodium Caprylate Sodium Fluoride
Sodium Gluconate Sodium Hydroxide Pellets
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Sodium Thiosulfate Sodium Sulfate
Stannous Chloride Dihydrate Zinc Carbonate
Zinc Chloride Zinc Gluconate
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Formaldehyde Solution (with Methanol) SDS MSDS Sheet, Material Safety Data Sheet

1. Product Identification

Synonyms: Formalin (with Methanol)
CAS No.: 50-00-0
EINECS EC Code: 200-001-8
Molecular Weight: 30.03.
Chemical Formula: HCHO.
Intended Use: Industrial Manufacturing.
Suppliers: As per letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Oral (Category 3), H301
Acute toxicity, Dermal (Category 3), H311
Acute toxicity, Inhalation (Category 3), H331
Skin corrosion (Category 1B), H314
Skin sensitization (Category 1), H317
Germ cell mutagenicity (Category 2), H341
Carcinogenicity (Category 1B), H350
Specific target organ toxicity - single exposure (Category 1), H370
Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335

Labeling according to GHS USA & Regulation (EC) No 1272/2008

GHS Label Elements

GHS Label Elements

GHS Label Elements
Health hazard
Health Hazard

Signal Word: Danger

Hazard Statements:
H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H335 May cause respiratory irritation.
H341 Suspected of causing genetic defects.
H350 May cause cancer.
H370 Causes damage to organs.

Precautionary Statements
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash ... thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P272: Contaminated work clothing should not be allowed out of the workplace
P280-Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310+330: IF SWALLOWED: Rinse mouth and immediately call a POISON CENTER or doctor/physician.
P302+P352: IF ON SKIN: Wash with soap and water.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308+313: IF exposed or concerned: Get medical advice/attention.
P314: Get Medical advice/attention if you feel unwell.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P363: Wash contaminated clothing before reuse.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
T Toxic, Xi Irritant, C Corrosive
R23/25            Toxic by inhalation and if swallowed
R36/37/38 Irritating to eyes, respiratory system and skin
For the full text of the H-statements & R-phrases mentioned in this Section, see Section 16.

OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.

3. Composition/Information on Ingredients
Ingredient I: Formaldehyde 30-45% in water.
CAS No.: 50-00-0
EINECS EC Code: 200-001-8

Ingredient II: Methanol 5-20% in water.
CAS No.: 67-56-1
EINECS EC Code: 200-659-6

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove the victim to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Contact medical center quickly. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Get medical attention.

5. Fire Fighting Measures

Fire: Flash point: Not available.
Auto ignition temperature: Not available.
Toxic fumes, carbon dioxide and carbon monoxide may be formed in fire.
Fire Extinguishing Media: Dry chemical, foam or carbon dioxide and water spray jet.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Use water spray to cool unopened containers.

6. Accidental Release Measures
Small Spill: Wear respiratory protection. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. Mop and pick up the material and place in an appropriate waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Avoid mist formation. Keep away from heat. Keep away from sources of ignition. Provide ventilation. Contact Environment Agency. Wear full protective equipment and ensure proper ventilation.

7. Handling and Storage

Keep away from heat and source of fire preferably in a ventilated area. Keep in tightly closed container. Do not breathe mist or dust. Containers of Formaldehyde may be hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and precautions listed for the product. Do not allow to freeze. Avoid contact.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits:
Formaldehyde 37%, in Aqueous Solution
ACGIH                        ACGIH TLV-C (ppm)            0.3 ppm
USA OSHA                 OSHA PEL (TWA) (ppm)      0.75 ppm
USA OSHA                 OSHA PEL (STEL) (ppm)     2 ppm
USA IDLH                  US IDLH (ppm)                      20 ppm
ACGIH                        ACGIH TLV-TWA (ppm)      200 ppm
ACGIH                        ACGIH TLV-STEL (ppm)     250 ppm
USA OSHA                 OSHA PEL (TWA) (mg/m³) 260 mg/m³
USA OSHA                 OSHA PEL (TWA) (ppm)      200 ppm
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to the substance is apparent and engineering controls are not feasible, consult an industrial hygienist. For emergencies, or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.

9. Physical and Chemical Properties

Appearance: Clear liquid.
Odor: Typical aldehyde pungent smell.
Solubility: miscible with water
Specific Gravity: 1.09 approximate
pH: NA.
% Volatiles by volume @ 21C (70F): NA
Boiling Point: >100C
Melting Point: - NA.
Molecular Weight: 30.03.
Chemical Formula: HCHO.

10. Stability and Reactivity

Stability: Formaldehyde is stable under ordinary conditions of use and storage with the stabilizer.
Hazardous Decomposition Products: Carbon dioxide, carbon monoxide and toxic fumes may form when heated to decomposition.
Incompatibilities: Strong oxidizing agents, Aniline, Phenol, Isocyanates, Acid anhydrides, Strong acids, Strong bases, Amines, Peroxides, Acid chlorides, Alkali metals, Reducing agents, heat and sparks.
Conditions to Avoid: Heat, flames, ignition sources and incompatibles.

11. Toxicological Information

Oral rat LD50: Not available
The product is listed as carcinogen, Group 1: Carcinogenic to humans (Formaldehyde).
Warning: contains methanol. May be fatal or cause blindness if swallowed.

12. Ecological Information

Environmental Toxicity: Toxic to fish and aquatic life.
Biodegradability: The product is easily biodegradable.
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information

UN Number: 2209
Proper shipping name: Formaldehyde solution
Class: 8, Packing group: III
UN Number: 2209
Proper shipping name: Formaldehyde solution
Class: 8, Packing group: III

15. Regulatory Information

: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
HMIS (Perceived): Health Hazard: 3, Fire Hazard: 2, Reactivity: 0
NFPA (Perceived): Health: 3, Flammability: 2, Reactivity: 0

Canada WHMIS: CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC). CLASS D-2A: Material causing other toxic effects (VERY TOXIC).

Section 16 - Additional Information

European/International Regulations European Labeling in Accordance with EC Directives:
EINECS EC Code: 200-001-8
H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H335 May cause respiratory irritation.
H341 Suspected of causing genetic defects.
H350 May cause cancer.
H370 Causes damage to organs.
T = Toxic
Xi = Irritant
C = Corrosive
R23/25            = Toxic by inhalation and if swallowed.
R36/37/38 = Irritating to eyes, respiratory system and skin.
S22- Do not breathe dust.
S24- Avoid contact with skin.
S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.Disclaimer:

Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.