Triethanolamine or Trolamine BP Ph Eur USP NF EP IP Grade Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Triethanolamine or Trolamine BP Ph Eur USP NF EP IP Grade, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Triethanolamine or Trolamine: CAS Number: 102-71-6, EINECS EC Number: 203-049-8, Molecular Formula: C6H15NO3 or (HOCH2CH2)3N, Molecular Weight: 149.19, HS Code ---**

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Triethanolamine or Trolamine.

Triethanolamine or Trolamine, TEOA or TELA or 2,2′,2′′-Nitrilotriethanol or Tris(2-hydroxyethyl)amine is a viscous organic compound that is both a tertiary amine and a triol. It is a colorless compound. In pharmaceutics, triethanolamine is the active ingredient of some eardrops used to treat impacted earwax. It also serves as a pH balancer in many different cosmetic products, ranging from cleansing creams and milks, skin lotions, eye gels, moisturizers, shampoos, shaving foams, and so on. Cleansing milk–cream emulsions based on TEOA are particularly good at removing makeup. Triethanolamine is also used in the manufacture of emulsifiers and dispersing agents for textile specialties, agricultural chemicals, waxes, mineral and vegetable oils, paraffin, polishes, cutting oils, petroleum de-emulsifiers, and cement additives.

General Specifications of Triethanolamine or Trolamine:
Appearance: Clear and substantially free of suspended matter
Sulfated ash: 0.05% maximum
Assay: 99.5% - 100.8%
Diethanolamine: 0.4% maximum
Refractive index 20°C: 1.4810 - 1.4860
Residual Solvents Passes Test.
Specific gravity 25/25°C: 1.120 to 1.128
Water: 0.2% maximum.

Trolamine USP NF Grade Specifications:
C6H15NO3 --- 149.19
Ethanol, 2,2',2"-nitrilotris-.
2,2',2"-Nitrilotriethanol --- [CAS 102-71-6].

Trolamine is a mixture of alkanolamines consisting largely of triethanolamine [N(C2H4OH)3] containing some diethanolamine [NH(C2H4OH)2] and monoethanolamine [NH2(C2H4OH)]. It contains not less than 99.0 percent and not more than 107.4 percent of alkanolamines, calculated on the anhydrous basis as N(C2H4OH)3.
Packaging and storage: Preserve in tight, light-resistant containers.

Identification:
A: Infrared Absorption.
B: To 1 mL add 0.1 mL of cupric sulfate: a deep blue color is produced. Add 5 mL of 1 N sodium hydroxide, and concentrate to one-third of the original volume by boiling: the blue color remains.
C: To 1 mL add 0.3 mL of cobaltous chloride: a carmine red color is produced.
Specific gravity: between 1.120 and 1.128.
Refractive index: between 1.481 and 1.486 at 20C.
Water: not more than 0.5%, a mixture of 5.0 mL of glacial acetic acid and 20 mL of methanol being used as the solvent.
Residue on ignition: not more than 0.05%.
Assay: Transfer about 2 g of Trolamine, accurately weighed, to a 300-mL conical flask. Add 75 mL of water and 2 drops of methyl red and titrate with 1 N hydrochloric acid: each mL of 1 N hydrochloric acid is equivalent to 149.2 mg of triethanolamine, expressed as N(C2H4OH)3.

Triethanolamine BP Ph Eur Grade Specifications:
Trolamine Ph Eur
C6H15NO3 --- 149.2 --- CAS 102-71-6
Action and use: Pharmaceutical aid.

DEFINITION
2,2′,2″-Nitrilotriethanol.
Content: 99.0 per cent m/m to 103.0 per cent m/m of total bases (anhydrous substance).

CHARACTERS
Appearance: Clear, viscous, colourless or slightly yellow liquid, very hygroscopic.
Solubility: Miscible with water and with ethanol (96 per cent), soluble in methylene chloride.
IDENTIFICATION
First identification: B, C
Second identification: A, B, D
A. Relative density: 1.120 to 1.130.
B. Refractive index: 1.482 to 1.485.
C. Examine the chromatograms obtained in the test for related substances.
Results The principal peak in the chromatogram obtained with the test solution is similar in retention time and size to the principal peak in the chromatogram obtained with reference solution (a).
D. To 1 mL add 0.3 mL of copper sulfate solution R. A blue colour develops. Add 2.5 mL of dilute sodium hydroxide solution and heat to boiling. The blue colour remains unchanged.

TESTS
Solution S: Dissolve 12 g in water and dilute to 20 mL with the same solvent.
Appearance of solution: Solution S is clear and not more intensely coloured than reference solution B.
Related substances: To pass the test by Gas chromatography
Water: Maximum 1.0 per cent, determined on 1.000 g.
Sulfated ash: Maximum 0.1 per cent, determined on 1.0 g. Do not carry out the initial heating on a water-bath.

ASSAY
Dissolve 1.200 g in 75 mL of carbon dioxide-free water. Add 0.3 mL of methyl red solution. Titrate with1 M hydrochloric acid. 1 mL of 1 M ;hydrochloric acid is equivalent to 0.149 g of C6H15NO3.

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Triethanolamine or Trolamine SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 22-Nov-20

Product Name & Other Names: Triethanolamine or Trolamine
CAS No.: 102-71-6
EINECS EC Number: 203-049-8
Molecular Weight: 149.19
Chemical Formula: C6H15NO3 or (HOCH2CH2)3N
Relevant uses and uses advised against (if any): Industrial use.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.

Hazards not otherwise classified (HNOC):
May causes mild skin irritation.
May causes mild eye irritation.

Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.

Product Name & Other Names: Triethanolamine or Trolamine
CAS No.: 102-71-6
EINECS EC Number: 203-049-8

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wash affected areas with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention if symptoms occur.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Fire: Not considered to be a fire hazard.
Explosion: Reactions with incompatibles may pose an explosion hazard.
Fire Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide. Use means suitable for extinguishing surrounding fire.
Special hazards arising from the substance or mixture: Carbon oxides, Nitrogen oxides (NOx).
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Prevent any contact with hot surfaces. Do not handle or store near an open flame, heat, or other sources of ignition. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded.
Conditions for safe storage, including any incompatibilities: It will absorb moisture from air. Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like acids, strong oxidizing etc. Containers may be hazardous when empty.

Airborne Exposure Limits:
USA ACGIH: 5mg/m3 TWA
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved):
If the exposure limit is exceeded and engineering controls are not feasible, a half face piece particulate respirator (NIOSH type N95 or better filters) may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece particulate respirator (NIOSH type N100 filters) may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. If heat is involved, an ammonia/methylamine, dust/mist cartridge may be necessary.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection:: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Clear, viscous, colourless or slightly yellow liquid, very hygroscopic.
Odor: Develops odor of ammonia.
Odor: Not available.
Odor threshold: Not available.
pH: 10.5 to 11.5
Relative density: 1.12.
Boiling Point: 360C Decomposes.
Melting Point: 17C to 21C.
Flash point: 190C.
Auto-ignition temperature: 325C.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Soluble in water.
Viscosity: Not available.
Molecular Weight: 149.19
Chemical Formula: C6H15NO3 or (HOCH2CH2)3N

Stability: Stable under ordinary conditions of use and storage. Forms explosive mixtures with air on intense heating. Sensitive to air and moisture.
Hazardous Decomposition Products: Decomposes upon heating and can form products including ammonia, oxides of nitrogen, carbon oxides and fumes.
Hazardous Polymerization: Will not occur.
Incompatibilities: Acids, strong oxidizing, heat, moisture, sunlight.

LD50 Oral Rat: 6.400 mg/kg
LD50 Dermal - Rabbit - > 22,5 g/kg
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

Toxicity to fish: flow-through test LC50 Pimephales promelas (fathead minnow): 11,800 mg/l; 96 h.
Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia (water flea) - 609.98 mg/l - 48 h
Environmental Toxicity: At high concentrations, it can be toxic to aquatic life.
Results of PBT and vPvB assessment: Not available.

Not considered a hazardous waste. Follow standard disposal procedures. Dispose of container and unused contents in accordance with legal requirements.

DOT USA, TDG Canada & ADR/RID Europe: Not dangerous goods.
IMDG?IMO & IATA/ICAO: Not dangerous goods.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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