Hexamine or Hexamethylenetetramine or Methenamine or Urotropin Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Glutaraldehyde, Hexamine or Hexamethylenetetramine, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Hexamine or Hexamethylenetetramine or Methenamine or Urotropin: CAS Number: 100-97-0, EINECS EC Number: 202-905-8, Molecular Formula: C6H12N4 or (CH2)6N4, Molecular Weight: 140.19, HS Code 2933 69 40

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Hexamine or Hexamethylenetetramine or Methenamine or Urotropin.

Hexamine or Hexamethylenetetramine or methenamine or hexamine or urotropin is a heterocyclic organic compound with the formula (CH2)6N4. This white crystalline compound is highly soluble in water and polar organic solvents. It is used in pharmaceutical and other industries. Hexamethylene tetramine or hexamine is also used as a food additive as a preservative. It is listed under E number E239.

General Properties and Specifications of Hexamine or Hexamethylenetetramine or Methenamine or Urotropin:
Appearance: White crystalline powder.
Odor: Fishy, ammonia-like odor.
Assay: 99.5%
pH: about 8 to 9
Moisture: 0.5% maximum.
Ash Content: 0.05% maximum.
Heavy Metal (Pb): 0.001% maximum.
Chloride (Cl): 0.015% maximum.
Sulphate (SO4): 0.02% maximum.
Ammonium (NH3): 0.001% maximum.
Relative density: about 1.33
Melting point: 280C (Sublimes) literature.
Flash point: 250C.
Solubility: Soluble in water.

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Hexamine or Hexamethylenetetramine or Methenamine or Urotropin
SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 13-Nov-20

Product Name & Other Names: Hexamine or Hexamethylenetetramine or Methenamine or Urotropin.
CAS No.: 100-97-0
EINECS EC Number: 202-905-8
Chemical Formula: C6H12N4 or (CH2)6N4
Molecular Weight: 140.19
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Hazard statements:
H228 Flammable solid.
H317 May cause an allergic skin reaction.

Precautionary statements:
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P220: Keep/Store away from clothing/…/combustible materials.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P362: Take off contaminated clothing and wash before reuse.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342+311: If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
F Highly flammable.
Xi Irritant.
Risk Phrases:
R10 flammable.
R43 May cause sensitization by skin contact.

Product Name & Other Names: Hexamine or Hexamethylenetetramine or Methenamine or Urotropin.
CAS No.: 100-97-0
EINECS EC Number: 202-905-8

Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin: Immediately flush skin with plenty of water for at least 15 minutes. Remove and wash contaminated clothing and shoes before reuse. Get medical attention if irritation develops.
Eyes: Immediately flush eyes with plenty of water for 15 minutes, occasionally lifting upper and lower eyelids. Hold eyelids apart during irrigation. Get medical attention.
Inhalation: Remove person to fresh air. If breathing is difficult, give oxygen. If not breathing administer artificial respiration. Get medical attention.

Flash Point: 250C
Fire/Explosion: The product is flammable.
Extinguishing Medium: Water spray, alcohol-resistant foam, sand, dry chemical, or carbon dioxide. Use water spray to cool unopened containers.
Special hazards arising from the substance or mixture: Poisonous fume, carbon dioxide, carbon monoxide, nitrogen oxides (NOx).
Fire Fighting Instructions: Use suitable protective equipment for surrounding fire. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. In case of fire in the surroundings: Keep containers cool by spraying with water. Eliminate all ignition sources if safe to do so.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Personal precautions, protective equipment, and emergency procedures: Ventilate area of leak or spill. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container. Do not touch or walk through this product. Stop leak if safe to do so. Prevent entry into waterways, drains, confined areas. Prevent dust cloud. Use personal protective equipment. Keep people away from and upwind of spill/leak. Entry to non-involved personnel should be controlled around the leakage area by roping off, etc. Use spark-proof tools and explosion-proof equipment. Ensure all leaks are completely removed to prevent subsequent ignition.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, halogenated hydrocarbon, nitric acid, acetic anhydride, iodine, iodoform. Protect against physical damage. Keep away from heat, sparks, and flame. Isolate from all combustibles and incompatible substances.

Exposure Limits: his product does not contain any hazardous materials with biological limits established by the region-specific regulatory bodies.
Engineering Controls: Use adequate exhaust ventilation to keep airborne concentrations below the allowable exposure limit.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: White crystalline powder.
Odor: Not available.
Odor threshold: Not available.
pH: about 8 to 9
Relative density: about 1.33
Melting point/freezing point: 280C (Sublimes) literature.
Initial boiling point and boiling range: NA.
Flash point: 250C.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility(ies): Soluble in water.
Viscosity: Not available.
Chemical Formula: C6H12N4 or (CH2)6N4
Molecular Weight: 140.19

Chemical Stability: Stable under recommended temperatures and pressures.
Incompatibility (Materials to Avoid): Strong oxidizing agents, halogenated hydrocarbon, nitric acid, acetic anhydride, iodine, iodoform.
Conditions to Avoid: Incompatible materials, direct sunlight, heat shock, friction.
Hazardous Decomposition Products: Poisonous fume, carbon dioxide, carbon monoxide, nitrogen oxides (NOx).
Hazardous Polymerization: Will not occur.

Toxicity to Animals: LD50 Oral: 9200 mg/kg ( Rat ). LD50 Dermal: >2000 mg/kg ( Rat )
Carcinogenicity: Not a reported carcinogen by any agency.
Teratogenicity: No information found.
Reproductive Effects: No information found.
Mutagenicity: No information found.
Neurotoxicity: No information found.

Toxicity to fish: static test LC50 - Cyprinodon variegatus (sheepshead minnow) - 49.000 mg/l - 96 h.
Toxicity to daphnia and other aquatic invertebrates: static test EC50 - Daphnia magna (Water flea) - 36.000 mg/l - 48 h.
Persistence and Degradability: Unlikely to persist due to water solubility.
Mobility: Likely to be mobile due to water solubility.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

Dispose of in accordance with all applicable local, state, and federal regulations at an approved waste disposal facility.

DOT USA, TDG Canada & ADR/RID Europe:
UN number: 1328 Class: 4.1 Packing group: III
Proper shipping name: HEXAMETHYLENETETRAMINE
IMDG/IMO
UN number: 1328 Class: 4.1 Packing group: III
Proper shipping name: HEXAMETHYLENETETRAMINE
IATA:
UN number: 1328 Class: 4.1 Packing group: III
Proper shipping name: HEXAMETHYLENETETRAMINE

USA:
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 311/312: Reactivity Hazard; Acute Health Hazard; Chronic Health Hazard.

European Labeling in Accordance with EC Directives:
H228 Flammable solid.
H317 May cause an allergic skin reaction.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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