Ethylenediamine or Ethane-1,2-diamine or 1,2-Diaminoethane Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Ethylenediamine, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Ethylenediamine or Ethane-1,2-diamine or 1,2-Diaminoethane: CAS Number: 107-15-3, EINECS EC Number: 203-468-6, Molecular Formula: C2H8N2 or C2H4(NH2)2, Molecular Weight: 60.10, HS Code ---**

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Ethylenediamine or Ethane-1,2-diamine or 1,2-Diaminoethane.

Ethylenediamine or Ethane-1,2-diamine or 1,2-Diaminoethane is the organic compound with the formula C2H4(NH2)2. This colorless liquid with an ammonia-like odor is a strongly basic amine. It is a widely used building block in chemical synthesis. Ethylenediamine readily reacts with moisture in humid air to produce a corrosive, toxic and irritating mist. Ethylenediamine is used in large quantities for production of many industrial chemicals. Ethylenediamine is an ingredient in the common bronchodilator drug aminophylline. Ethylenediamine has also been used in dermatologic preparations. It is also used as a pharmaceutical excipient.

General Specification of Ethylenediamine or Ethane-1,2-diamine or 1,2-Diaminoethane:
Appearance: Clear fuming liquid.
Assay: 99.5% minimum
Water: 0.3 % maximum.
Relative density: about 0.9

Ethylenediamine USP Grade Specifications:
C2H8N2 --- 60.10
1,2-Ethanediamine.
Ethylenediamine [CAS 107-15-3].

Ethylenediamine contains not less than 98.0 percent and not more than 100.5 percent, by weight, of C2H8N2.
[Caution—Use care in handling Ethylenediamine because of its caustic nature and the irritating properties of its vapor.]
NOTE—Ethylenediamine is strongly alkaline and may readily absorb carbon dioxide from the air to form a nonvolatile carbonate. Protect ethylenediamine against undue exposure to the atmosphere.

Packaging and storage: Preserve in well-filled, tight, glass containers.
Identification: To 2 mL of cupric sulfate solution (1 in 100) add 3 drops of a solution of Ethylenediamine (1 in 6), and shake: a purplish blue color is produced.
Heavy metals: Evaporate 5.0 mL on a steam bath to dryness, add to the residue 1 mL of hydrochloric acid and 0.5 mL of nitric acid, and evaporate again to dryness. Dissolve the residue in 20 mL of warm water, cool, dilute with water to 100 mL, mix, and use 20 mL of this solution for the test: the limit is 0.002%.
Assay: Weigh accurately about 1 mL of Ethylenediamine in a tared, glass-stoppered flask containing about 25 mL of water. Dilute with water to about 75 mL, add a mixed indicator of bromocresol green and methyl red (5 in 6), mix, and titrate with 1 N hydrochloric acid. Perform a blank determination, and make any necessary correction. Each mL of 1 N hydrochloric acid is equivalent to 30.05 mg of C2H8N2.

CHARACTERS
Appearance: Clear, colourless or slightly yellow liquid, hygroscopic.
Solubility: Miscible with water and with anhydrous ethanol.
On exposure to air, white fumes are evolved. On heating, it evaporates completely.

IDENTIFICATION
A. Relative density: 0.895 to 0.905.
B. Boiling point: 116C to 118C.
C. To 0.2 mL add 0.5 mL of acetic anhydrid. Boil. A crystalline mass forms after cooling, which dissolves in 5 mL of 2-propanol with heating. Cool the solution and add 5 mL of ether. If necessary, initiate crystallization by scratching the walls of the test-tube with a glass rod. Filter through a sintered-glass filter, wash with several portions of ether and dry at 100-105C. The residue meltsat 173C to 177C.

TESTS
Solution S: Mix 10 g with carbon dioxide-free water and dilute to 100 mL with the same solvent.
Appearance of solution: Solution S is clear and not more intensely coloured than the reference solution.
Carbonate: A mixture of 4 mL of solution S and 6 mL of calcium hydroxide solution is not more opalescent than reference suspension II.
Chlorides: Maximum 100 ppm.
Ammonia and other bases: Dissolve 1.2 g in 20 mL of ethanol (96 per cent) and add, drop-wise with stirring, 4.5 mL of hydrochloric acid. Evaporate to dryness on a water-bath, breaking up any resulting cake with a glass rod, and dry at 100-105C for 1 h. 1 g of the residue is equivalent to 0.4518 g of C2H8N2. Calculate the percentage content of C2H8N2: it does not vary by more than 0.5 from the percentage content determined in the assay.
Iron: Maximum 10 ppm, determined on solution S.
Residue on evaporation: Maximum 0.3 per cent.

ASSAY
Place 25.0 mL of 1 M hydrochloric acid and 0.2 mL of methyl red mixed solution in a flask. Add 0.600 g of the substance to be examined. Titrate with 1 M sodium hydroxide until the colour changes from violet-red to green. 1 mL of 1 M hydrochloric acid is equivalent to 30.05 mg of C2H8N2.

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Ethylenediamine or Ethane-1,2-diamine or 1,2-Diaminoethane SDS GHS, Material Safety Data Sheet
MSDS GHS, Material Safety Data Sheet 18-Oct-20

Product Name & Other Names: Ethylenediamine or Ethane-1,2-diamine or 1,2-Diaminoethane.
CAS No.: 107-15-3
EINECS EC No.: 203-468-6
Molecular Formula: C2H8N2 or C2H4(NH2)2
Molecular Weight: 60.10
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP):

Flammable liquids (Category 3) H226
Acute toxicity, Oral (Category 4) H302
Acute toxicity, Inhalation (Category 4) H332
Acute toxicity, Dermal (Category 3) H311
Skin corrosion (Sub-category 1B) H314
Skin sensitization (Category 1), H317
Respiratory sensitization (Category 1) H334
Long-term (chronic) aquatic hazard (Category 3) H412

Hazard statements:
H226: Flammable liquid and vapor.
H302 + H332: Harmful if swallowed or if inhaled.
H311: Toxic in contact with skin.
H314: Causes severe skin burns and eye damage.
H317: May cause an allergic skin reaction.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H412: Harmful to aquatic life with long lasting effects.

Precautionary statements:
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/light/…/equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P330: Rinse mouth.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+352: IF ON SKIN: Wash with soap and water.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P370+378: In case of fire: Use water spray or fog for extinction.
P403+233+235: Store in a well ventilated place. Keep container tightly closed. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to authorized agents only.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard symbols:
T = Toxic
N = Dangerous for the environment.
C = Corrosive.
R-phrases:
R10 Flammable.
R20/22 Harmful by inhalation and if swallowed.
R24 Toxic in contact with skin.
R35 Causes severe burns
R41 Risk of serious damage to eyes.
R42 May cause sensitization by inhalation
R43 May cause sensitization by skin contact
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Product Name & Other Names: Ethylenediamine or Ethane-1,2-diamine or 1,2-Diaminoethane.
CAS No.: 107-15-3
EINECS EC No.: 203-468-6

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Flammability of the Product: Flammable.
Auto-Ignition Temperature: 385C.
Flash Points: 34C
Products of Combustion: Carbon oxides, Nitrogen oxides (NOx) and fumes. Flash back possible over considerable distance., Container explosion may occur under fire conditions. Vapors may form explosive mixture with air.
Fire: Inflammable.
Explosion: Explosive in presence of heat.
Fire Extinguishing Media: Use water spray or fog. Flammable liquid and vapor. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas. Never direct a water jet in the container in order to prevent any splashing of the product which could cause spreading of the fire. Cool containing vessels with water jet in order to prevent pressure build-up, auto-ignition or explosion.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes.

Personal precautions, protective equipment and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep up, and remove to an approved disposal container.
Small Spill: Avoid mist formation. Avoid breathing mist. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Remove all sources of ignition. Provide proper ventilation. Absorb the material on a porous, inert material such as earth, sand or vermiculite. If solid/powder - carefully sweep up the material without causing dust. Dispose of in accordance with local regulations.

Precautions for safe handling: Keep away from sources of ignition - No smoking. Take measures to prevent the build-up of electrostatic charge. Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid contact with skin, eyes and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, strong reducing agents, strong acids, strong bases. Keep the product in its original container well sealed, in a dry and ventilated area, away from potential sources of ignition and protected from light. Protect against physical damage. Air and moisture sensitive. Handle and store under inert gas.

Airborne Exposure Limits:
ACGIH TLV TWA: 10 ppm Skin.
OSHA PEL (Vacated) TWA: 10 ppm; (Vacated) TWA: 25 mg/m3
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Clear liquid.
Odor: Ammonia-like odor.
Odor threshold: Not available.
pH: around 12
Relative Density: 0.9
Boiling Point: 118C
Melting Point: 8.5C
Flash point: 34C.
Auto-ignition temperature: 385C.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor Pressure (mm Hg): Not available.
Vapor Density (Air=1): Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Soluble in water (Reacts).
Viscosity: Not available.
Molecular Formula: C2H8N2 or C2H4(NH2)2
Molecular Weight: 60.10

Stability: Stable under ordinary conditions of use and storage. Vapour/air-mixtures are explosive at intense warming. The product is air sensitive. Reacts violently with acid halides, perchlorates, Acrolein, Halogenated hydrocarbon, Acid chlorides, Alcohols, Aldehydes, phosphorus halides.
Hazardous Decomposition Products: It emits Carbon oxides, Nitrogen oxides (NOx) and fumes.
Hazardous Polymerization: Will not occur.
Incompatibilities: Aluminum, Lead, magnesium, Zinc, zinc alloys, Copper, Copper alloys, Iron, brass, bronze. Oxidizing agents, Phosphorus halides, Aldehydes, Organic halides.
Conditions to Avoid: Incompatibles, Air, Moisture, Heat, flames and sparks & light.

Toxicity data
LD50 Oral - Rat - male and female - 866 mg/kg.
LC50 Inhalation - Rat - 4 h - > 10 - 20 mg/l.
LD50 Dermal - Rabbit - male - 560 mg/kg.
Carcinogenicity: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology: No information found
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: No information found
Neurotoxicity: No information found

Environmental Toxicity: Harmful to aquatic life with long lasting effects.
Toxicity to fish: semi-static test LC50 - Poecilia reticulata (guppy) - 640 mg/l - 96 h.
Toxicity to daphnia and other aquatic invertebrates: static test EC50 - Daphnia magna (Water flea) - 16,7 mg/l - 48 h.
Persistence and Degradability: No information available. Persistence is unlikely.
Mobility: Will likely be mobile in the environment due to its water solubility.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

DOT USA Classification:
UN Number: UN1604
Shipping Name: Ethylenediamine
Hazard Class: 8 (3); Packing Group: II
Canada TDG Classification:
UN Number: UN1604
Shipping Name: Ethylenediamine
Hazard Class: 8 (3); Packing Group: II
IATA & ADR/RID Europe
UN Number: UN1604
Shipping Name: Ethylenediamine
Hazard Class: 8 (3); Packing Group: II

USA:
SARA 302 Components: Listed.
SARA 313 Components: No chemicals are reportable under Section 313.
SARA 311/312 Hazards: Fire Hazard: Immediate Health Hazard: Acute Yes, Chronic Health Hazard.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

European Labeling in Accordance with EC Directives:
H226: Flammable liquid and vapor.
H302 + H332: Harmful if swallowed or if inhaled.
H311: Toxic in contact with skin.
H314: Causes severe skin burns and eye damage.
H317: May cause an allergic skin reaction.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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