Oleic Acid BP USP NF FCC Food Grade Manufacturers, with SDS MSDS Sheet
Supplier, Manufacturer, Exporter of Oleic Acid, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.
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Oleic Acid: Synonym: cis-9-Octadecenoic acid, Elainic acid, CAS Number: 112-80-1, Molecular Formula: CH3(CH2)7CH=CH(CH2)7COOH, Molecular Weight: 282.46, EINECS: EC Number 204-007-1 HS Code ---**
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MSDS Sheet of Oleic Acid ManufacturersSpanish Fabricantes de ácido oleico
Portuguese Fabricantes de ácido oleico
Oleic Acid
BP USP FCC Food Grade Suppliers
Oleic acid is a fatty acid that occurs naturally in various animal and vegetable fats and oils. It is an odorless, colorless oil, although commercial samples may be yellowish. In chemical terms, oleic acid is classified as a monounsaturated omega-9 fatty acid, abbreviated with a lipid number of 18:1 cis-9. It has the formula CH3(CH2)7CH=CH(CH2)7COOH. The term "oleic" means related to, or derived from, oil of olive, the oil that is predominantly composed of oleic acid. Oleic acid is an unsaturated fatty acid that is the most widely distributed and abundant fatty acid in nature. It is used commercially in the preparation of oleates and lotions, and as a pharmaceutical solvent.
Oleic Acid BP Grade Specifications
C18H34O2 -- 282.5 -- CAS 112-80-1
Action and use: Excipient.
Ph EurDEFINITION
(Z)-Octadec-9-enoic acid (C18H34O2; Mr 282.5), together with varying amounts of saturated and other unsaturated fatty acids. A suitable antioxidant may be added.
Content: 65.0 per cent to 88.0 per cent of C18H34O2.CHARACTERS
Appearance: Clear, yellowish or brownish, oily liquid.
Solubility: Practically insoluble in water, miscible with alcohol and with methylene chloride.
Relative density: About 0.892.IDENTIFICATION
A. It complies with the test for acid value (see Tests).
B. It complies with the test for iodine value (see Tests).
C. It complies with the test for composition of fatty acids (see Tests).
Margaric acid: Maximum 0.2 per cent for oleic acid of vegetable origin and maximum 4.0 per cent for oleic acid of animal origin.TESTS
Appearance: The substance to be examined is not more intensely coloured than reference solution.
Acid value: 195 to 204, determined on 0.5 g.
Iodine value: 89 to 105.
Peroxide value: Maximum 10.0.
Composition of fatty acids by Gas chromatography:
myristic acid: maximum 5.0 per cent;
palmitic acid : maximum 16.0 per cent;
palmitoleic acid : maximum 8.0 per cent;
stearic acid : maximum 6.0 per cent;
oleic acid : 65.0 per cent to 88.0 per cent;
linoleic acid : maximum 18.0 per cent;
linolenic acid : maximum 4.0 per cent;
fatty acids of chain length greater than C18: maximum 4.0 per cent.
Total ash: Maximum 0.1 per cent, determined on 2.00 g.LABELLING
The label states the origin of oleic acid (animal or vegetable).
Oleic Acid USP NF Grade Specifications
C18H34O2 282.46
9-Octadecenoic acid, (Z)-.[CAS 112-80-1].Oleic Acid is manufactured from fats and oils derived from edible sources, animal or vegetable, and consists chiefly of (Z)-9-octadecenoic acid [CH3(CH2)7CH:CH(CH2)7COOH]. It may contain suitable stabilizers.
NOTE: Oleic Acid labeled solely for external use is exempt from the requirement that it be prepared from edible sources.
Labeling: If it is for external use only, the labeling so indicates. Label it to indicate whether it is
derived from animal or vegetable sources. Indicate the names and quantity of any added stabilizers.
Specific gravity: between 0.889 and 0.895.
Congealing temperature: between 3 and 10 for Oleic Acid derived from animal sources; between 10 and 16 for Oleic Acid derived from vegetable sources.
Acid value: between 196 and 204, about 2 g, accurately weighed, being used.
Iodine value: between 85 and 95.
Residue on ignition: not more than 1 mg (about 0.01%), from a 10-mL portion.
Mineral acids: Shake 5 mL with an equal volume of water at a temperature of about 25 for 2 minutes, allow the liquids to separate, and filter the water layer through a paper filter previously moistened with water: the filtrate is not reddened by the addition of 1 drop of methyl orange.
Neutral fat or mineral oil: Boil 1 mL with about 500 mg of sodium carbonate and 30 mL of water in a 250-mL flask: the resulting solution, while hot, is clear or, at most, opalescent.
Oleic Acid FCC Food Grade Specifications
(Z)-9-Octadecenoic Acid
CH3(CH2)7CH CH(CH2)7COOH
C18H34O2 Formula wt 282.47
CAS: [112-80-1]DESCRIPTION
Oleic Acid occurs as a colorless to pale yellow, oily liquid when freshly prepared, but upon exposure to air it gradually absorbs oxygen and darkens. It is an unsaturated acid obtained from fats. When strongly heated in air, it decomposes and produces acrid vapors. Its specific gravity is about 0.895. It is practically insoluble in water, but is miscible with alcohol, with ether, and with fixed and volatile oils.
Function: Component in the manufacture of other food grade additives; defoaming agent; lubricant; binder.REQUIREMENTS
Acid Value: Between 196 and 204.
Iodine Value: Between 83 and 103.
Lead: Not more than 0.1 mg/kg.
Residue on Ignition: Not more than 0.01%.
Saponification Value: Between 196 and 206.
Titer (Solidification Point): Not above 10°.
Unsaponifiable: Matter Not more than 2.0%.
Water: Not more than 0.4%.For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.
We manufacture and supply as under:
Lauric Acid or Dodecanoic acid
Palmitic acid or Hexadecanoic acid.
Manufacturers:
MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
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Oleic Acid SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 10-Nov-201. Product Identification
Product Name & Other Names: Oleic Acid or cis-9-Octadecenoic acid or Elainic acid.
CAS Number: 112-80-1
EINECS: EC Number: 204-007-1
Molecular Formula: CH3(CH2)7CH=CH(CH2)7COOH
Molecular Weight: 282.46
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Supplier: As per letterhead.2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008Skin irritation Category 2, H315
Eye irritation Category 2B, H320Labeling according GHS & Regulation (EC) No 1272/2008
GHS Label Elements
IrritantSignal Words: Warning
Hazard statements:
H315: Causes skin irritation.
H320: Causes eye irritation.Precautionary statements:
P264: Wash … thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P337+P313: If eye irritation persists: Get medical advice/ attention.P362: Take off contaminated clothing and wash before reuse.Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xi Irritant
Risk Phrases:
R36/38 Irritating to eyes and skin.3. Composition/Information on Ingredients
Product Name & Other Names: Oleic Acid or cis-9-Octadecenoic acid or Elainic acid.
CAS Number: 112-80-1
EINECS: EC Number: 204-007-14. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen and get medical attention immediately.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing and shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.5. Fire Fighting Measures
Fire: As with most organic solids, fire is possible at elevated temperatures or by contact with an ignition source.
Explosion: Fine mist/dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard.
Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.6. Accidental Release Measures
Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill: Stop leak if without risk. Do not touch spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep up and remove to an approved disposal container. Use water spray to reduce dust/mist/vapors. Prevent entry into sewers, basements, or confined areas.7. Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizers and bases. Containers may be hazardous when empty. Avoid dust formation and control ignition sources. Employ grounding, venting and explosion relief provisions in accord with accepted engineering practices in any process capable of generating dust and/or static electricity. Empty only into inert or non-flammable atmosphere.8. Exposure Controls/Personal Protection
Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.9. Physical and Chemical Properties
Appearance: White to yellow liquid.
Odor: Characteristic.
Odor threshold: Not available.
pH: 1.0 - 2 at 150 g/l at 25 °C (77 °F).
Relative density: 0.89
Boiling Point: 286 °C (547 °F) lit. Different reporting also observed.
Melting Point: 7 - 14 °C.
Flash point 189 °C (372 °F): closed cup
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Insoluble in water.
Viscosity: Not available.
Molecular Formula: CH3(CH2)7CH=CH(CH2)7COOH
Molecular Weight: 282.4610. Stability and Reactivity
Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizers and bases.
Conditions to Avoid: Direct sunlight. Extremely high or low temperatures, Heat, dusting, and incompatibles.11. Toxicological Information
Acute toxicity:
LD50 Oral - Rat - 74.000 mg/kg
LD50 Dermal - rat - > 2,000 mg/kg
LD50 Intravenous - Rat - 2,4 mg/kg
LD50 Intraperitoneal - Mouse - 282 mg/kg
LD50 Intravenous - Mouse - 230 mg/kg.
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Teratogenic Effects: Not available.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.12. Ecological Information
Toxicity to fish:
LC50 - Pimephales promelas (fathead minnow) - 205 mg/l - 96 h
LC0 – fish 100 mg/l
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Environmental Fate: Sufficient information is not available. When released into the soil, Oleic Acid is expected to leach into groundwater. When released into the soil, this material is expected to biodegrade. When released into water, this material is expected to biodegrade. This material is not expected to significantly bio accumulate.13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused Oleic Acid in accordance with legal requirements.
14. Transport Information
DOT USA, TDG Canada & ADR/RID Europe: Not dangerous goods.
IMDG/IMO: Not dangerous goods.
IATA: Not dangerous goods.15. Regulatory Information
USA:
SARA 302: Not subject to the reporting requirements of SARA Title III, Section 302.
SARA 313: Does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards: Acute Health Hazard. See section 2.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.Section 16 - Additional Information
European Labeling in Accordance with EC Directives:
Classification according to EU Directives 67/548/EEC or 1999/45/EC:
H315 = Causes skin irritation.
H320 = Causes eye irritation
Hazard Symbol:
Xi Irritant
Risk Phrase:
R36/38 Irritating to eyes and skin.Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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