Glycerol Monooleate or Glyceryl Monooleate EP BP USP Ph Eur Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Glycerol Monooleate or Glyceryl Monooleate EP BP USP Ph Eur Grade, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Glycerol Monooleate or Glyceryl Monooleate: CAS Number: 25496-72-4, EINECS EC Number: yyyyy, Molecular Formula: C21H40O4, Molecular Weight: 356.54, HS Code ---**

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Glycerol Monooleate.

Glycerol Mono-oleate BP Ph Eur Grade Specifications
Action and use: Excipient.
Ph Eur

DEFINITION
Mixture of monoacylglycerols, mainly mono-oleoylglycerol, together with variable quantities of di- and triacylglycerols. It is defined by the nominal content of monoacylglycerols and obtained by partial glycerolysis of vegetable oils mainly containing triacylglycerols of oleic (cis-9-octadecenoic) acid or by esterification of glycerol by oleic acid, this fatty acid being of vegetable or animal origin. A suitable antioxidant may be added.

CHARACTERS
Appearance: Amber, oily liquid which may be partially solidified at room temperature.
Solubility: Practically insoluble in water, freely soluble in methylene chloride.

IDENTIFICATION
A. Iodine value (see Tests).
B. Thin-layer chromatography to pass the test.
C. It complies with the limits of the assay (monoacylglycerol content).

TESTS
Acid value: Maximum 6.0, determined on 1.0 g.
Iodine value: 65.0 to 95.0.
Peroxide value: Maximum 12.0, determined on 2.0 g.
Saponification value: 150 to 175, determined on 2.0 g.
Free glycerol: Maximum 6.0 per cent, determined as described in the assay.
Composition of fatty acids:
Composition of the fatty acid fraction of the substance
palmitic acid : maximum 12.0 per cent.
stearic acid : maximum 6.0 per cent.
oleic acid : minimum 60.0 per cent.
linoleic acid : maximum 35.0 per cent.
linolenic acid : maximum 2.0 per cent.
arachidic acid: maximum 2.0 per cent.
eicosenoic acid: maximum 2.0 per cent.
Water: Maximum 1.0 per cent, determined on 1.00 g. Use as the solvent a mixture of equal volumes of anhydrous methanol and methylene chloride R.
Total ash: Maximum 0.1 per cent.

Glyceryl Monooleate USP Grade Specifications
Oleic acid, 2,3-dihydroxypropyl ester, (±).
(RS)-1-Glyceryl oleate --- 356.54 --- CAS 25496-72-4

Glyceryl Monooleate is a mixture of monoglycerides, mainly glyceryl monooleate, together with variable quantities of diglycerides and triglycerides. It is obtained by partial glycerolysis of vegetable oil that consists mainly of triglycerides of oleic acid, or by esterification of glycerol with oleic acid of vegetable or animal origin. It is defined by the nominal content of monoglycerides, and the assay requirements differ as set forth in the accompanying table. A suitable antioxidant may be added.

Packaging and storage: Preserve in tight containers. No storage requirements specified.
Labeling: The labeling indicates the nominal content of monoglycerides and the name and the concentration of any added antioxidant.

Identification:
A: Thin-Layer Chromatographic Identification to pass the test
B: It meets the requirements of the test for Iodine value.
Acid value: not more than 6.0, determined on 1.0 g.
Iodine value: between 65.0 and 95.0.
Peroxide value: not more than 12.0, determined on 2.0 g.
Saponification value: between 150 and 175 determined on 2.0 g.
Fatty acid composition: Glyceryl Monooleate exhibits the following composition profile of fatty acids.

Water: not more than 1.0%, using a mixture of methanol and methylene chloride (1:1, v/v) in place of methanol in the titration vessel.
Total ash: not more than 0.1%.
Limit of free glycerin: not more than 6.0% of free glycerin is found.

For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.

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Glycerol Monooleate SDS Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 22-Oct-20

Product Name & Other Names: Glycerol monooleate.
CAS Number: 25496-72-4
EINECS EC Code: 247-038-6
Molecular Formula: C21H40O4
Molecular Weight: 356.54
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP)

Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.

Hazards not otherwise classified (HNOC):
May causes mild skin irritation.
May causes mild eye irritation.

Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.

Product Name & Other Names: Glycerol monooleate.
CAS Number: 25496-72-4
EINECS EC Code: 247-038-6

Skin: Rinse with water. Soap may be used. Seek Medical Aid.
Eyes: Wash eyes with plenty of water for at least 15 minutes, lifting lids occasionally. Seek Medical Aid.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Ingestion: If swallowed, induce vomiting immediately after giving two glasses of water. Never give anything by mouth to an unconscious person.

Flammability of the Product: May be combustible at high temperature. May be ignited by heat, sparks or flames. Container explosion may occur under fire conditions or when heated.
Products of Combustion: Oxides of Carbon.
Fire Fighting Media and Instructions: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus for firefighting if necessary.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes.

Personal precautions, protective equipment and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to legal requirements.
Large Spill: Contain spilled material. Do not inhale dust, mist, or gas. Avoid dust/mist formation. Use a shovel to put the material into a convenient waste disposal container. Be careful that the product is not present at a concentration level above TLV. Check TLV with local authorities.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid contact with skin, eyes and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like oxidizing agents. Store in light-resistant containers.

Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Physical state and appearance: Yellow to Amber Liquid.
Odor: Fatty odor.
Odor threshold: Not available.
pH: Not available.
Relative density: 0.94
Melting point: 9C
Boiling Point: 238 - 240C at 3 mm Hg.
Flash point: 218 - 235 C, Cleveland Open Cup
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Insoluble in water. Completely soluble in ethanol and acetone.
Viscosity: Not available.
Molecular Formula: C21H40O4
Molecular Weight: 356.54

Stability: It is stable in room temperature in closed containers under normal storage & handling.
Conditions of instability: Incompatible materials, Excess heat, light.
Incompatibility with various substances: Avoid high temperatures, sparks, open flames and moisture. Avoid contact with strong oxidizing agents and strong acids.
Polymerization: Will not occur.
Hazardous decomposition products: Carbon dioxide and carbon monoxide and other hazardous decomposition products formed under fire conditions.

LD50 Oral - Rat - 5,000 mg/kg.
Carcinogenic Effects: Not a reported carcinogen by IARC, NTP, ACGIH, OSHA.
Reproductive toxicity: No data available.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.

Toxicity to fish: Not available. Do not allow to enter into ground-water, surface water or drains.
Products of Biodegradation: The product itself and its products of degradation are not toxic.
Persistence and Degradability: No information available.
Mobility: No information available.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

Waste Disposal: Waste must be disposed of in accordance with federal, state and local environmental control regulations.

DOT USA, TDG Canada & ADR/RID Europe: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods: Not dangerous goods.

USA Regulations:
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards: No SARA Hazards
California Prop 65: California No Significant Risk Level: None of the chemicals in this product are listed.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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	Nominal content of acylglycerol (percent)
	40	60	90
Monoaclylglycerol	32-52	55-65	90-100
Diaclylglycerol	30-50	15-35	<10
Triaclylglycerol	5-20	2-10	<2

	Nominal Content of Monoglycerides (%)
	40	60	90
Monoglycerides	32-52	55-65	90-101
Diglycerides	30-50	15-35	<10
Triglycerides	5-20	2-10	<2

Carbon-Chain Length	No. of Double Bonds	Percentage (%)
16	0	not more than 12.0
18	0	not more than 6.0
18	1	not less than 60.0
18	2	not more than 35.0
18	3	not more than 2.0
20	0	not more than 2.0
20	1	not more than 2.0

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