Ferric Ammonium Citrate USP Pure Analytical Reagent FCC Food Grade Manufacturers, with SDS MSDS Sheet |
Supplier, Manufacturer, Exporter of Ferric Ammonium Citrate, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc. The products are offered as per required specifications and in correct shape and size in mm or meshs or microns as specified by the buyer. The participating units have one or more accreditations like FDA - cGMP and GLP approval, ISO-9001 Certified, "REACH" Registered, ISO-14001, ISO/IEC 17025, ISO-22000, FSSC 22000, ISO 45001, Kosher Certified, Halal Certified, HACCP, FSSAI. We offer Commercial Pure & IP BP EP Ph Eur USP NF JP FCC Food Grade Analytical Reagent Grades of Chemicals |
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Ferric Ammonium Citrate CAS Number 1185-57-5, EINECS EC Number 214-686-6, HS Code ---**; Molecular Weight is Variable, Molecular Formula: C6H5+4yFexNyO7
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MSDS Sheet of Ferric Ammonium Citrate Manufacturers
Ferric Ammonium Citrate
Commercial USP Pure Analytical Reagent Grade Suppliers
Ammonium ferric citrate is a food additive with E number E381 used as an acidity regulator. It is a green or reddish-brown powder which is very soluble in water. The molecular formula of ammonium iron (III) citrate is variable.
Other uses for ammonium ferric citrate include water purification and printing. It is used as a reducing agent of metal salts of low activity like gold and silver. Ammonium ferric citrate is also used in Kligler iron deeps to determine hydrogen sulfide production in microbial metabolism.
Ferric Ammonium Citrate USP
Ferric Ammonium Citrate contains not less than 16.5 percent and not more than 18.5 percent of iron (Fe).
Identification:
A: Ignite about 0.5 g: it chars, and leaves a residue of iron oxide.
B: To 10 mL of a solution of Ferric Ammonium Citrate (1 in 100) add 6 N ammonium hydroxide drop wise: the solution darkens, but no precipitate forms.
C: To 5 mL of a solution of Ferric Ammonium Citrate (1 in 100) add 0.3 mL of potassium permanganate TS and 4 mL of mercuric sulfate TS, and heat the mixture to boiling: a white precipitate forms.
Ferric citrate: To a solution of Ferric Ammonium Citrate (1 in 100) add potassium ferrocyanide TS: no blue precipitate is formed.
Sulfate: 0.3% Maximum.
Oxalate: Transfer 1 g to a 125-mL separator, dissolve in 10 mL of water, add 2 mL of hydrochloric acid, and extract successively with one 50-mL portion and one 20-mL portion of ether. Transfer the combined ether extracts to a 150-mL beaker, add 10 mL of water, and remove the ether by evaporation on a steam bath. Add 1 drop of glacial acetic acid and 1 mL of calcium acetate solution (1 in 20): no turbidity is produced within 5 minutes.
Mercury: not more than 10 µg per g is found..
Limit of lead: not more than 10 µg per g is found.
Assay: Transfer about 1 g of Ferric Ammonium Citrate, accurately weighed, to a 250-mL conical flask, and dissolve in 25 mL of water and 5 mL of hydrochloric acid. Add 4 g of potassium iodide, insert the stopper, and allow to stand protected from light for 15 minutes. Add 100 mL of water, and titrate the liberated iodine with 0.1 N sodium thiosulfate VS, using starch TS as the indicator. Perform a blank determination, and make any necessary correction. Each mL of 0.1 N sodium thiosulfate is equivalent to 5.585 mg of iron (Fe).
Ferric Ammonium Citrate, Brown FCC Food Grade
Iron Ammonium Citrate
INS: 381 CAS: [1185-57-5]
DESCRIPTION
Ferric Ammonium Citrate, Brown, occurs as thin, transparent brown, red-brown, or garnet red scales or granules, or as a brown-yellow powder. It is a complex salt of undetermined structure, composed of iron, ammonia, and citric acid. It is very soluble in water, but is insoluble in alcohol. The pH of a 1:20 aqueous solution is about 5.0 to 8.0. It is deliquescent in air and is affected by light.
Function: Nutrient.
REQUIREMENTS
Identification:
A. A 500-mg sample, when ignited, chars and leaves a residue of iron oxide.
B. Add 0.3 mL of potassium permanganate TS and 4 mL of mercuric sulfate TS to 5 mL of a 1:10 aqueous solution, and heat the mixture to boiling. A white precipitate forms.
C. Dissolve about 500 mg of sample in 5 mL of water, and add 5 mL of 1 N sodium hydroxide. A red-brown precipitate forms, and ammonia is evolved when the mixture is heated.
Assay: Not less than 16.5% and not more than 18.5% of iron (Fe).
Ferric Citrate: Passes test.
Lead: Not more than 2 mg/kg.
Mercury: Not more than 1 mg/kg.
Oxalate: Passes test.
Sulfate: Not more than 0.3%.
For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.
We manufacture and supply as under:
Manufacturers:
MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
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Last
25 April, 2024
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Ferric Ammonium Citrate SDS GHS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 19-Oct-20
1. Product Identification
Product Name & Other Names: Ferric ammonium citrate or Ammonium iron(III) citrate or Ammonium ferric citrate
CAS No.: 1185-57-5
EINECS EC Number: 214-686-6
Molecular Weight: Variable
Chemical Formula: CH5+4yFexNyO7.
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Skin irritation (Category 2), H315
Eye irritation (Category 2), H319
Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335
Labeling according GHS & Regulation (EC) No 1272/2008
GHS Label Elements  Irritant |
Signal Words: Warning
Hazard statements:
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335 May cause respiratory irritation.
Precautionary statements:
P261: Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P264: Wash … thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P330: Rinse mouth.
P362: Take off contaminated clothing and wash before reuse.
P302+352: IF ON SKIN: Wash with soap and water.
P332+313: If skin irritation occurs: Get medical advice/attention.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.
P501: Dispose of contents/container to authorized agents only.
Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
Xi = Irritant.
Risk Phrases:
R36/38 Irritating to eyes and skin.
3. Composition/Information on Ingredients
Product Name & Other Names: Ferric ammonium citrate or Ammonium iron(III) citrate or Ammonium ferric citrate
CAS No.: 1185-57-5
EINECS EC Number: 214-686-6
4. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
5. Fire Fighting Measures
Flammability of the Product: Non-flammable.
Products of Combustion: Carbon & nitrogen oxides, Oxides of Iron etc.
Fire: It is not considered to be a fire hazard. It may burn at higher temperature.
Explosion: Not an Explosive item.
Fire Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide. Use means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes. On decomposition it may emit hydrogen iodide. Containers may explode on heating.
6. Accidental Release Measures
Personal precautions, protective equipment, and emergency procedures: Ventilate area of leak or spill. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.
7. Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents and alkalis.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits:
Exposure Limit
TWA 1 mg/m3: USA ACGIH Threshold Limit Values (2011)
REL 1 mg/m3: USA NIOSH: Pocket Guide to Chemical Hazards (2010)
TWA 1 mg/m3: USA OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.
9. Physical and Chemical Properties
Appearance: It is brown-green powder or crystals.
Odor: It is odorless or has slight odor of ammonia.
Odor threshold: Not available.
pH: Not available.
Relative density: around 1.8
Melting point/freezing point: Not available.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: It is freely soluble in water.
Viscosity: Not available.
Molecular Weight: Variable
Chemical Formula: CH5+4yFexNyO7.
10. Stability and Reactivity
Stability: It is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits toxic fumes, carbon & nitrogen oxides and iron oxide when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents and alkalies.
Conditions to Avoid: Incompatibles heat, light and moisture.
11. Toxicological Information
Toxicity data: Not available
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.
12. Ecological Information
Toxicity to fish: LC0 - Fundulus heteroclitus - 200 mg/l - 7 d
Persistence and Degradability: No information available.
Mobility: No information available.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state, and local requirements.
14. Transport Information
DOT USA, ADR/RID Europe: Not regulated.
Canada TDG Classification: Not regulated.
IATA: Not regulated.
15. Regulatory Information
USA:
SARA 302 Extremely hazardous substance: None present or none present in regulated quantities.
SARA 313 Components: No chemicals in this material are subject to the reporting requirements.
SARA 311/312 Hazards: Immediate (acute) health hazard.
California Prop.65: Not Listed.
16. Other Information
European Labeling in Accordance with EC Directives:
H315 = Causes skin irritation.
H319 = Causes serious eye irritation.
H335 = May cause respiratory irritation.
Hazard Symbols:
Xi = Irritant.
Risk Phrases:
R36/38 Irritating to eyes and skin.
DISCLAIMER: The information and recommendations set forth herein are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.