Benzalkonium Chloride BKC Pure JP IP EP BP USP Grade Solution Powder Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Benzalkonium Chloride BKC JP IP EP BP USP, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Benzalkonium Chloride BKC: CAS Number: 8001-54-5 or 63449-41-2, EINECS EC Number: 264-151-6, Molecular Formula: Variable, Molecular Weight: Variable, HS Code ---**

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail prices, Uses etc available on these pages for Benzalkonium Chloride BKC.

Benzalkonium chloride, also known as BZK, BKC, BAC, alkyldimethylbenzylammonium chloride and ADBAC, is a type of cationic surfactant. It is an organic salt classified as a quaternary ammonium compound. It has three main categories of use: as a biocide, a cationic surfactant, and as a phase transfer agent.
Depending on purity, benzalkonium chloride ranges from colorless to a pale yellow (impure). Benzalkonium chloride is readily soluble in ethanol and acetone. Dissolution in water is slow. Aqueous solutions should be neutral to slightly alkaline. Solutions foam when shaken. Concentrated solutions have a bitter taste and a faint almond-like odor. Standard concentrates are manufactured as 50% and 80% w/w solutions, and sold under trade names. We offer both Benzalkonium chloride solution and Benzalkonium chloride powder.

General Specifications Benzalkonium Chloride Solution:
Purity: 50% & 80%
Boiling point:100C
Flash point: 41C
Storage condition: 2-8C
Storage: For two year in room shady and dry place
Appearance: Light yellow clear liquid
Application: As non-oxidizing biocide.

Benzalkonium Chloride BP Ph Eur Grade:
8001-54-5
Action and use: Antiseptic.

DEFINITION
Mixture of alkylbenzyldimethylammonium chlorides, the alkyl groups mainly having chain lengths of C12, C14and C16.
Content: 95.0 per cent to 104.0 per cent of alkylbenzyldimethylammonium chlorides (anhydrous substance) calculated using the average relative molecular mass.

CHARACTERS
Appearance: White or yellowish-white powder or gelatinous, yellowish-white fragments, hygroscopic. On heating it forms a clear molten mass.
Solubility: Very soluble in water and in ethanol (96 per cent). An aqueous solution froths copiously when shaken.

IDENTIFICATION
First identification: B, E
Second identification: A, C, D, E
A. Ultraviolet and visible absorption spectrophotometry - To pass the test.
B. Examine the chromatograms obtained in the test for average relative molecular mass and ratio of alkyl components.
Results The principal peaks in the chromatogram obtained with the test solution are similar in retention time to the principal peaks in the chromatogram obtained with the reference solution.
C. To 2 mL of solution S (see Tests) add 0.1 mL of glacial acetic acid and, drop-wise, 1 of sodium tetraphenylborate solution. A white precipitate is formed. Filter. Dissolve the precipitate in a mixture of 1 mL of acetone and 5 mL of ethanol (96 per cent) heating to not more than 70C. Add water drop-wise to the warm solution until a slight opalescence forms. Heat gently until the solution is clear and allow to cool. White crystals separate. Filter, wash with 3 quantities, each of 10 mL, of water and dry in vacuo overdiphosphorus pentoxide or anhydrous silica gel at a temperature not exceeding 50C. The crystals melt at 127C to 133C.
D. To 5 mL of dilute sodium hydroxide solution add 0.1 mL of bromophenol blue solution and 5 mL of methylene chloride and shake. The methylene chloride layer is colourless. Add 0.1 mL of solution S and shake. The methylene chloride layer becomes blue.
E. To 2 mL of solution S add 1 mL of dilute nitric acid. A white precipitate is formed which dissolves on the addition of 5 mL of ethanol (96 per cent). The solution gives reaction of chlorides.

TESTS
Solution S: Dissolve 1.0 g in carbon dioxide-free water and dilute to 100 mL with the same solvent.
Appearance of solution: Solution S is clear and not more intensely coloured than reference solution.
Acidity or alkalinity: To 50 mL of solution S add 0.1 mL of bromocresol purple solution. Not more than 0.1 mL of0.1 M hydrochloric acid or 0.1 M sodium hydroxide is required to change the colour of the indicator.
Average relative molecular mass and ratio of alkyl components: To pass the test.
Impurities A, B and C: To pass the test.
Amines and amine salts: To pass the test.
Water: Maximum 10 per cent, determined on 0.300 g.
Sulfated ash: Maximum 0.1 per cent, determined on 1.0 g.

Benzalkonium Chloride USP Grade:
Ammonium, alkyldimethyl(phenylmethyl)-, chloride.
Alkylbenzyldimethylammonium chloride [CAS 8001-54-5].

Benzalkonium Chloride is a mixture of alkylbenzyldimethylammonium chlorides of the general formula: [C6H5CH2N(CH3)2R]Cl in which R represents a mixture of alkyls, including all or some of the group beginning with n-C8H17 and extending through higher homologs, with n-C12H25, n-C14H29, and n-C16H33 comprising the major portion. On the anhydrous basis, the content of the n-C12H25 homolog is not less than 40.0 percent, and the content of the n-C14H29 homolog is not less than 20.0 percent, of the total alkylbenzyldimethylammonium chloride content. The amounts of the n-C12H25 and n-C14H29 homolog components comprise together not less than 70.0 percent of the total alkylbenzyldimethylammonium chloride content. The total alkylbenzyldimethylammonium chloride content, calculated on the anhydrous basis, allowance being made for the amount of residue on ignition, is not less than 97.0 percent and not more than 103.0 percent of [C6H5CH2N(CH3)2R]Cl.

Packaging and storage: Preserve in tight containers.
Identification:
A: To a solution (1 in 100) add 2 N nitric acid or mercuric chloride TS: a white precipitate is formed, and it is soluble in alcohol.
B: Dissolve about 200 mg in 1 mL of sulfuric acid, add 100 mg of sodium nitrate, and heat on a steam bath for 5 minutes. Cool, dilute with water to 10 mL, add 500 mg of zinc dust, and warm for 5 minutes on a steam bath. To 2 mL of the clear supernatant add 1 mL of sodium nitrite solution (1 in 20), cool in ice water, then add 3 mL of a solution of 500 mg of 2-naphthol in 10 mL of 6 N ammonium hydroxide: an orange-red color is produced.
C: A solution of it in a mixture of equal volumes of water and alcohol responds to the tests for Chloride.
Water: not more than 15.0%.
Residue on ignition: not more than 2.0%.
Water-insoluble matter: A solution (1 in 10) is free from turbidity and insoluble matter.
Limit of foreign amines: To 5 mL of a solution (1 in 50) add 3 mL of 1 N sodium hydroxide: no precipitate is formed. Heat to boiling: the odor of amines is not perceptible.
Ratio of alkyl components: To pass the test.
Assay for total alkylbenzyldimethylammonium chlorides: Weigh accurately a quantity of Benzalkonium Chloride equivalent to about 500 mg of anhydrous benzalkonium chloride, and transfer, with the aid of 35 mL of water, to a glass-stoppered, 250-mL conical separator containing 25 mL of chloroform. Add 10.0 mL of freshly prepared potassium iodide solution (1 in 20), insert the stopper in the separator, shake, allow the layers to separate, and discard the chloroform layer. Wash the aqueous layer with three 10-mL portions of chloroform, and discard the washings. Transfer the aqueous layer to a glass-stoppered, 250-mL conical flask, and rinse the separator with three 5-mL portions of water, adding the washings to the flask. Add 40 mL of cold hydrochloric acid to the flask, mix, and titrate with 0.05 M potassium iodate VS until the solution becomes light brown in color. Add 5 mL of chloroform, insert the stopper into the flask, and shake vigorously. Continue the titration, dropwise, with shaking after each addition, until the chloroform layer becomes colorless and the aqueous layer is clear yellow. Perform a blank determination, using 20 mL of water as the sample. The difference between the two titrations represents the amount of potassium iodate equivalent to the weight of benzalkonium chloride in the sample. Each mL of 0.05 M potassium iodate is equivalent to x/10 mg of benzalkonium chloride,where x represents the average molecular weight of the sample, derived by summing, for all homologs, the products

where W is the molecular weight of a given homolog, A is the area of the peak produced by that homolog in the chromatogram from the Ratio of alkyl components test, and B is the total peak area for all homologs in that chromatogram.

Benzalkonium Chloride Solution USP Grade:
Benzalkonium Chloride Solution contains not less than 95.0 percent and not more than 105.0 percent of the labeled amount of benzalkonium chloride in concentrations of 1.0 percent or more; and not less than 93.0 percent and not more than 107.0 percent of the labeled amount in concentrations of less than 1.0 percent. It may contain a suitable coloring agent and may contain not more than 10 percent of alcohol.
Caution: Mixing Benzalkonium Chloride Solution with ordinary soaps and with anionic detergents may decrease or destroy the bacteriostatic activity of the Solution.

Packaging and storage: Preserve in tight containers, and prevent contact with metals.

Identification:
A: It responds to Identification tests A and C under Benzalkonium Chloride.
B: The residue obtained by evaporating, on a steam bath, a volume of Solution equivalent to about 200 mg of benzalkonium chloride responds to Identification test B under Benzalkonium Chloride.
Microbial limits: Solution containing less than 5.0% of benzalkonium chloride meets the requirements of the test for absence of Pseudomonas aeruginosa.
Alcohol content (if present): between 95.0% and 105.0% of the labeled amount of C2H5OH is found.
Limit of foreign amines: A volume of Solution, equivalent to 100 mg of benzalkonium chloride, and adjusted to a concentration of 1 in 50, meets the requirements of the test for Foreign amines under Benzalkonium Chloride.
Ratio of alkyl components: To pass the test.
Assay: Evaporate or dilute with water to about 30 mL an accurately measured volume of Solution, equivalent to about 275 mg of benzalkonium chloride. Transfer the solution with the aid of a minimum quantity of water to a glass-stoppered, 250-mL conical separator. Add 25 mL of chloroform, and proceed as directed in the Assay for total alkylbenzyldimethylammonium chlorides under Benzalkonium Chloride, beginning with “Add 10.0 mL of freshly prepared potassium iodide solution (1 in 20).”

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Benzalkonium Chloride SDS Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 02-Oct-20

Product Name & Other Names: Benzalkonium Chloride, BZK, BKC, BAC, alkyldimethylbenzylammonium chloride and ADBAC
CAS No.: 8001-54-5 or 63449-41-2
EINECS EC Code: 264-151-6
Molecular Weight: Variable.
Chemical Formula: Variable.
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Oral (Category 3), H301
Acute toxicity, Dermal (Category 4), H312
Skin corrosion (Category 1B), H314
Chronic aquatic toxicity (Category 1), H410

Hazard Statements:
H301: Toxic if swallowed
H312: Harmful in contact with skin.
H314: Causes severe skin burns and eye damage.
H410: Very toxic to aquatic life with long lasting effects.

Precautionary Statements
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash ... thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P272: Contaminated work clothing should not be allowed out of the workplace
P273 Avoid release to the environment.
P280-Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310+330: IF SWALLOWED: Rinse mouth and immediately call a POISON CENTER or doctor/physician.
P302+P352: IF ON SKIN: Wash with soap and water.
P303 + P361 + P352 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P314: Get Medical advice/attention if you feel unwell.
P330: If swallowed, rinse mouth.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P390 Absorb spillage to prevent material damage.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
T Toxic
C Corrosive
N Dangerous for the environment
Risk Phrases:
R23/25 Toxic by inhalation and if swallowed
R34 Causes burns.
R41 Risk of serious damage to eyes.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Product Name/Synonyms: Benzalkonium Chloride, BZK, BKC, BAC, alkyldimethylbenzylammonium chloride and ADBAC. >50% in water.
CAS No.: 8001-54-5 or 63449-41-2
EINECS EC Code: 264-151-6

Inhalation: If inhaled, it will cause irritation and damage to nose and throat. Remove the victim to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: It will cause irritation and burns to mouth, digestive tract and stomach. Contact medical center quickly. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: On contact, it can cause itching, pain, swelling and redness. Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: It can cause severe damage to eyes. Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Get medical attention.

Fire: Combustible.
Auto ignition temperature: NA
Toxic fumes, nitrogen oxides, carbon dioxide and carbon monoxide may be formed in fire.
Explosion: Not known.
Fire Extinguishing Media: Dry chemical, foam or carbon dioxide or water jet.
Unsuitable extinguishing media: Do not use a direct stream of water to extinguish.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.

Personal precautions, protective equipment, and emergency procedures: Ventilate area of leak or spill. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Mop and pick up the material and place in an appropriate waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container. Avoid mist formation. Keep away from heat. Keep away from sources of ignition. Provide ventilation. Wear full protective equipment and ensure proper ventilation.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents and strong acids & alkalis and reducing agents. Keep away from heat and source of fire preferably in a ventilated area. Keep in tightly closed container. Do not breathe mist or dust. Do not store near food items.

Airborne Exposure Limits: Contains no substances with occupational exposure limit values.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to the substance is apparent and engineering controls are not feasible, consult an industrial hygienist. For emergencies, or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Colorless to slightly yellow liquid. (Anhydrous material is white to off-white powder).
Odor: Characteristic smell.
Odor threshold: Not available.
pH: 5 to 9.
Relative density: 0.97 approximate.
Melting point/freezing point: Not available.
Boiling Point: >100C
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: miscible with water
Viscosity: Not available.
Molecular Weight: Variable.
Chemical Formula: Variable.

Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Toxic fumes, nitrogen oxides, carbon dioxide and carbon monoxide may be formed in fire.
Hazardous Polymerization: Not reported.
Incompatibilities: Strong acids & alkalis, oxidizing & reducing agents, heat and sparks. Hygroscopic. Also incompatible with nitrates, anion detergents.
Conditions to Avoid: Heat, flames, ignition sources and incompatibles.

Toxic if swallowed; Harmful in contact with skin; Causes severe skin burns and eye damage.
Oral rat LD50: 240 mg/kg
Dermal rat LD50: 1420 mg/kg.
Reproductive Effects: No information available.
Developmental Effects: No information available.
Teratogenicity: No information available.
Carcinogenicity: The product is not listed as carcinogen by OSHA, IARC, ACGIH or NTP.

Environmental Toxicity: Very toxic to aquatic life with long lasting effects.
Toxicity to fish:
mortality LOEC - Oncorhynchus kisutch - 17.8 mg/l - 3.0 d
LC50 - Lepomis macrochirus - 0.31 mg/l - 96.0 h
mortality NOEC - Oncorhynchus kisutch - 10 mg/l - 3.0 d.
Results of PBT and vPvB assessment: Not available.
Persistence and degradability: No data available.
Mobility in soil: No data available.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

DOT USA & ADR/RID Europe
UN Number: 3261
Proper shipping name: Corrosive liquid, acidic, organic. NOS (Benzyl-C12-14-alkyldimethylammonium chlorides)
Class: 8, Packing group: II
IMDG & IATA
UN Number: 3261
Proper shipping name: Corrosive liquid, acidic, organic. NOS (Benzyl-C12-14-alkyldimethylammonium chlorides)
Class: 8, Packing group: II

USA:
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312: Acute & Chronic.
California Prop 65: No Significant Risk Level: None of the chemicals in this product are listed.

European Labeling in Accordance with EC Directives:
H301: Toxic if swallowed
H312: Harmful in contact with skin.
H314: Causes severe skin burns and eye damage.
H410: Very toxic to aquatic life with long lasting effects.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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