Benzaldehyde BP Ph Eur USP NF Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Benzaldehyde, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Benzaldehyde: CAS Number: 100-52-7, EINECS EC Number: 202-860-4, Molecular Formula: C7H6O, Molecular Weight: 106.12, HS Code 29122990 or 29130090

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Benzaldehyde.

Benzaldehyde USP NF Specifications:
C7H6O --- 106.12
Benzoic aldehyde;
Phenyl formaldehyde --- CAS 100-52-7

DEFINITION
Benzaldehyde contains NLT 98.0% and NMT 102.0% of benzaldehyde (C7H6O).

IDENTIFICATION
A. Infrared Absorption
ASSAY
To pass the test by chromatography.
Acceptance criteria: 98.0%–102.0%
Limit of Hydrocyanic Acid: To pass the test.
Limit of Nitrobenzene: To pass the test.
Chlorinated Compounds: To pass the test.
Limit of Ethylbenzene, Cyclohexylmethanol, Benzyl Alcohol, and Benzoic Acid: To pass the test by chromatography.
Acceptance criteria
Each individual impurity: NMT 1.0%
Total impurities: NMT 2.0%
Water Determination: NMT 1.5%
Packaging and Storage: Preserve in well-filled, tight, light-resistant containers. Store at room temperature and avoid exposure to excessive heat.

DEFINITION
Benzaldehyde contains not less than 98.0% w/w and not more than 100.5% w/w of C7H6O.

CHARACTERISTICS
A clear, colourless liquid. Slightly soluble in water; miscible with ethanol (96%) and with ether.
TESTS
Refractive index: 1.544 to 1.546.
Weight per mL: 1.043 to 1.049 g.
Free acid: Not more than 1.0% w/v, calculated as benzoic acid, C7H6O2, when determined by the following method. To 10 mL add 20 mL of ethanol (96%) previously neutralised to phenolphthalein solution and titrate with 0.1M sodium hydroxide using phenolphthalein solution as indicator. Each mL of 0.1M sodium hydroxide is equivalent to 12.21 mg of C7H6O2.
Chlorinated compounds: Not more than 0.05% w/v, calculated as Cl.

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Benzaldehyde SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 01-Sept-21

Product Name & Other Names: Benzaldehyde
CAS No.: 100-52-7
EINECS EC Number: 202-860-4
Molecular Formula: C7H6O
Molecular Weight: 106.12
Relevant uses and uses advised against (if any): Laboratory and Industrial Use.
Supplier: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, oral (Category 4) H302
Skin corrosion/irritation (Category 2) H315
Serious eye damage/eye irritation (Category 2A) H319
Acute toxicity, Inhalation (Category 4) H332
Specific target organ toxicity - single exposure, Respiratory system (Category 3) H335
Long-term (chronic) aquatic hazard (Category 3) H412

Hazard Statements:
H302 + H332: Harmful if swallowed or if inhaled.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H412: Harmful to aquatic life with long lasting effects.

Precautionary Statements:
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash contaminated parts thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+352: IF ON SKIN: Wash with plenty of soap and water.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 + P312: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P333+313: If skin irritation or a rash occurs: Get medical advice/attention.
P403+233+235: Store in a well-ventilated place. Keep container tightly closed. Keep cool.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/national regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
Xi Irritant.
C Corrosive.
Risk Phrases:
R20/22 Harmful by inhalation and if swallowed.
R36/37/38 Irritating to eyes, respiratory system, and skin.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Product Name & Other Names: Benzaldehyde
CAS No.: 100-52-7
EINECS EC Number: 202-860-4

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do not use mouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Get medical attention.
Ingestion: Rinse mouth. Do not induce vomiting without medical advice. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Never give anything by mouth to a victim who is unconscious or is having convulsions. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Use a mild soap if available. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. For minor skin contact, avoid spreading material on unaffected skin.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Products of Combustion: Carbon oxides and Fumes.
Fire Extinguishing Media: Water spray. Alcohol foam. Polymer foam. Dry chemical powder. Carbon dioxide (CO2). Avoid a solid water stream as it may scatter and spread fire. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes.
Extinguishing Media Not recommended: Avoid using solid water jet as it may scatter the fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Personal precautions: Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering. Keep out of low areas.
Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not contaminate water.
Methods for cleaning up: Clean up in accordance with all applicable regulations. Should not be released into the environment.
Small Spill: Avoid dust/mist formation. Avoid breathing dust/mist/gas. Ensure adequate ventilation. Wipe up with absorbent material (e.g. cloth, fleece). Clean contaminated surface thoroughly.
Large Spill: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep up and remove to an approved disposal container.

Precautions for safe handling: Keep away from sources of ignition - No smoking. Take measures to prevent the build-up of electrostatic charge. Do not handle or store near an open flame, heat or other sources of ignition. All equipment used when handling the product must be grounded. Use only under a chemical fume hood. Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid contact with skin, eyes and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Prevent any contact with hot surfaces. Avoid prolonged exposure. Do not empty into drains. Avoid release to the environment.
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, strong acids, and bases.

Airborne Exposure Limits: Not established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice.

Appearance: A clear, colorless liquid.
Odor: Like bitter almonds.
Odor threshold: Not available.
pH: about 5.9
Relative density: about 1.05
Boiling point: 178C to 179C.
Melting point/Freezing point: -26C.
Flash Point: Not available
Auto-ignition Temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Mildly soluble in water.
Viscosity: 16 cps @ 25C.
Molecular Formula: C7H6O
Molecular Weight: 106.12

Stability: It is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits Carbon oxides and Fumes when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents. Strong reducing agents. Strong bases. oxygen. Aluminum. copper. Copper alloys. Alkali metals.
Conditions to Avoid: Avoid light, heat, sparks, open flames, and other ignition sources. Contact with incompatible materials.

Toxicity data:
LD50 Oral Rat: 1430 mg/kg.
LC50 Inhalation Rat: 4 h - 1 - 5 mg/l.
LD50 Dermal Rabbit: > 1250 mg/kg.
Carcinogenicity: Not expected to be hazardous by IARC, NTP, ACGIH and OSHA criteria.
Mutagenic Effects: No information available.
Reproductive Effects: No information available.
Developmental Effects: No information available.
Teratogenicity: No information available.

Toxicity to fish: flow-through test LC50 - Lepomis macrochirus - 1,07 mg/l - 96 h.
Toxicity to daphnia and other aquatic invertebrates: semi-static test EC50 - Daphnia magna (Water flea) - 19,7 mg/l - 48 h.
Persistence and degradability: Unlikely to persist due to water solubility.
Mobility in soil: Likely to be mobile due to water solubility.
Results of PBT and vPvB assessment: Not available.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with law.

DOT USA, TDG Canada & ADR/RID Europe:
UN Number: 1990
Proper Shipping Name: Benzaldehyde
Hazard Class: 9, Packing Group: III.
IMDG/IMO:
UN Number: 1990
Proper Shipping Name: Benzaldehyde
Hazard Class: 9, Packing Group: III.
IATA:
UN Number: 1990
Proper Shipping Name: Benzaldehyde
Hazard Class: 9, Packing Group: III.

USA:
SARA 311/312 Hazards: Acute Health Hazard. See section 2.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

European Labeling in Accordance with EC Directives:
H302 + H332: Harmful if swallowed or if inhaled.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H412: Harmful to aquatic life with long lasting effects.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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