Aluminum Sesquichlorohydrate or Aluminum chlorohydroxide or Aluminum hydroxychloride Manufacturers, SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Aluminum Sesquichlorohydrate or Aluminum chlorohydroxide or Aluminum hydroxychloride, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Aluminum Sesquichlorohydrate or Aluminum chlorohydroxide or Aluminum hydroxychloride

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail prices, Uses etc available on these pages for Aluminum Sesquichlorohydrate or Aluminum chlorohydroxide or Aluminum hydroxychloride.

Aluminum sesquichlorohydrate is an aluminum salt used as an antiperspirant agent, cosmetic astringent and deodorant agent apart from other uses. It works by physically blocking eccrine sweat gland ducts. The United States Food and Drug Administration considers the use of aluminium sesquichlorohydrate in antiperspirants to be safe and it is permitted in concentrations up to 25%.

Aluminum Sesquichlorohydrate USP Grade:
Aly(OH)3y-zClz-nH2O --- 11097-68-0
Aluminum chlorohydroxide.
Aluminum hydroxychloride.

Aluminum Sesquichlorohydrate consists of complex basic aluminum chloride that is polymeric and loosely hydrated and encompasses a range of aluminum to chloride atomic ratios between 1.26:1 and 1.90:1. It contains not less than 90.0 percent and not more than 110.0 percent of the labeled amount of anhydrous aluminum sesquichlorohydrate.

Packaging and storage: Preserve in well-closed containers.
Labeling: The label states the content of anhydrous aluminum sesquichlorohydrate.
Identification: A solution (1 in 10) responds to the tests for Aluminum and for Chloride.
pH: between 3.0 and 5.0, in a solution [15 in 100 (w/w)].
Arsenic: 2 microgm per g.
Heavy metals: 20 microgm per g.
Limit of iron: The limit is 150 microgm per g.
Content of aluminum: To be determined.
Content of chloride: To be determined.
Aluminum/chloride atomic ratio: Divide the percentage of aluminum found in the test for Content of aluminum by the percentage of chloride found in the test for Content of chloride, and multiply by 35.453/26.98, in which 35.453 and 26.98 are the atomic weights of chlorine and aluminum, respectively: the ratio is between 1.26:1 and 1.90:1.
Assay: Calculate the percentage of anhydrous aluminum sesquichlorohydrate in the Aluminum Sesquichlorohydrate by the formula:
Al({26.98x + [17.01(3x 1)] + 35.453} / 26.98x)
in which Al is the percentage of aluminum found in the test for Content of aluminum, x is the aluminum/chloride atomic ratio found in the test for Aluminum/chloride atomic ratio, 26.98 is the atomic weight of aluminum, 17.01 is the molecular weight of the hydroxide anion (OH), and 35.453 is the atomic weight of chlorine (Cl).

Aluminum Sesquichlorohydrate Solution consists of complex basic aluminum chloride that is polymeric and encompasses a range of aluminum-to-chloride atomic ratios between 1.26:1 and 1.90:1. The following solvents may be used: water, propylene glycol, dipropylene glycol, or alcohol. It contains the equivalent of not less than 90.0 percent and not more than 110.0 percent of the labeled concentration of anhydrous aluminum sesquichlorohydrate.

Packaging and storage: Preserve in well-closed containers.
Labeling: Label Solution to state the solvent used and the claimed concentration of anhydrous aluminum sesquichlorohydrate contained therein.
Identification:
A: A solution containing the equivalent of about 100 mg of anhydrous aluminum sesquichlorohydrate per mL responds to the tests for Aluminum and for Chloride.
B: Identification of propylene glycol (where stated on the label): Add about 10 mL of isopropyl alcohol to 2 g of Solution, mix, and filter. Evaporate the filtrate to about 1 mL on a steam bath: the IR absorption spectrum of a film of this solution on a silver chloride disk exhibits maxima only at the same wavelengths as that of a similar preparation of a film of propylene glycol.
C: Identification of dipropylene glycol (where stated on the label): Add about 10 mL of isopropyl alcohol to 2 g of Solution, mix, and filter. Evaporate the filtrate to about 1 mL on a steam bath: the IR absorption spectrum of a film of this solution on a silver chloride disk exhibits maxima only at the same wavelengths as that of a similar preparation of a film of dipropylene glycol.
D: Identification of alcohol (where stated on the label): Mix 5 drops of Solution in a small beaker with 1 mL of potassium permanganate solution (1 in 100) and 5 drops of 2 N sulfuric acid, and cover the beaker immediately with filter paper moistened with a freshly prepared solution of 0.1 g of sodium nitroferricyanide and 0.25 g of piperazine in 5 mL of water: an intense blue color is produced on the filter paper, the color becoming paler after a few minutes.
pH: between 3.0 and 5.0, in a solution prepared by diluting 3 g of the Solution with water to obtain 10 mL.
Arsenic: The limit is 2 microgm per g.
Heavy metals: The limit is 10 microgm per g.
Limit of iron: The limit is 75 microgm per g.
Content of aluminum: To be determined.
Content of chloride: To be determined.
Aluminum/chloride atomic ratio: Divide the percentage of aluminum found in the test for Content of aluminum by the percentage of chloride found in the test for Content of chloride, and multiply by 35.453/26.98, in which 35.453 and 26.98 are the atomic weights of chlorine and aluminum, respectively: the ratio is between 1.26:1 and 1.90:1.
Assay: Calculate the percentage of anhydrous aluminum sesquichlorohydrate in the Solution by the formula:
Al({26.98x + [17.01(3x 1)] + 35.453} / 26.98x)
in which Al is the percentage of aluminum found in the test for Content of aluminum, x is the aluminum/chloride atomic ratio found in the test for Aluminum/chloride atomic ratio, 26.98 is the atomic weight of aluminum, 17.01 is the molecular weight of the hydroxide anion (OH), and 35.453 is the atomic weight of chlorine (Cl).

Aly(OH)3y zClz.nH2O.mH(OCH2CH2)nOH
Aluminum chlorohydroxide polyethylene glycol complex.
Aluminum hydroxychloride polyethylene glycol complex.

Aluminum Sesquichlorohydrex Polyethylene Glycol consists of aluminum sesquichlorohydrate in which some of the waters of hydration have been replaced by polyethylene glycol. It encompasses a range of aluminum-tochloride atomic ratios between 1.26:1 and 1.90:1. It contains not less than 90.0 percent and not more than 110.0 percent of the labeled amount of anhydrous aluminum sesquichlorohydrate.

Packaging and storage: Preserve in well-closed containers.
Labeling: The label states the content of anhydrous aluminum sesquichlorohydrate.
Identification:
A: A solution (1 in 10) responds to the tests for Aluminum and for Chloride.
B: Infrared Absorption: to meet the requirement.
pH: between 3.0 and 5.0, in a solution [15 in 100 (w/w)].
Arsenic: 2 microgm per g.
Heavy metals: 20 microgm per g.
Limit of iron: The limit is 150 microgm per g.
Content of aluminum: To be determined.
Content of chloride: To be determined.
Aluminum/chloride atomic ratio: Divide the percentage of aluminum found in the test for Content of aluminum by the percentage of chloride found in the test for Content of chloride, and multiply by 35.453/26.98, in which 35.453 and 26.98 are the atomic weights of chlorine and aluminum, respectively: the ratio is between 1.26:1 and 1.90:1.

Aly(OH)3y-zClz.nH2O.mC3H8O2
Aluminum chlorohydroxide propylene glycol complex.
Aluminum hydroxychloride propylene glycol complex.

Aluminum Sesquichlorohydrex Propylene Glycol consists of aluminum sesquichlorohydrate in which some of the waters of hydration have been replaced by propylene glycol. It encompasses a range of aluminum to chloride atomic ratios between 1.26:1 and 1.90:1. It contains not less than 90.0 percent and not more than 110.0 percent of the labeled amount of anhydrous aluminum sesquichlorohydrate.

Packaging and storage: Preserve in well-closed containers.
Labeling: The label states the content of anhydrous aluminum sesquichlorohydrate.
Identification:
A: A solution (1 in 10) responds to the tests for Aluminum and for Chloride.
B: Infrared Absorption
pH: between 3.0 and 5.0, in a solution [15 in 100 (w/w)].
Arsenic: 2 microgm per g.
Heavy metals: 20 microgm per g.
Limit of iron: The limit is 150 microgm per g.
Content of aluminum: To be determined.
Content of chloride: To be determined.
Aluminum/chloride atomic ratio: Divide the percentage of aluminum found in the test for Content of aluminum by the percentage of chloride found in the test for Content of chloride, and multiply by 35.453/26.98, in which 35.453 and 26.98 are the atomic weights of chlorine and aluminum, respectively: the ratio is between 1.26:1 and 1.90:1.

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Aluminum Sesquichlorohydrate or Aluminum Chlorohydroxide or Aluminum Hydroxychloride SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 29-Sep-20

Product Name & Other Names: Aluminum sesquichlorohydrate or Aluminum chlorohydroxide or Aluminum hydroxychloride.
CAS No.: 11097-68-0
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008:

Acute toxicity, Oral (Category 5) H303
Skin corrosion/irritation (Category 2) H315
Serious eye damage/eye irritation (Category 2A) H319

Hazard statements:
H303: May be harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.

Precautionary statements:
P261: Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P262: Do not get in eyes, on skin, or on clothing.
P264 Wash skin thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+313: If skin irritation occurs: Get medical advice/attention.
P337+P313: If eye irritation persists: Get medical advice/ attention.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xi Irritant
Risk Phrases:
R36/38 Irritating to eyes and skin.

Product Name & Other Names: Aluminum sesquichlorohydrate or Aluminum chlorohydroxide or Aluminum hydroxychloride.
CAS No.: 11097-68-0

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to Physician: Treat symptomatically.

Flammability of the Product: The product is not flammable.
Products of Combustion: It forms oxides of aluminum and hydrochloric acid when heated to decomposition.
Fire Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide.
Special Information In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Avoid dust/mist formation. Avoid breathing dust/mist. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, acids, and alkalis.

Airborne Exposure Limits: None established. Assure it as below 2mg/m3.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Clear to yellowish.
Odor: Not available.
Odor threshold: Not available.
pH: Not available.
Relative density: Not available.
Melting point/freezing point: Not available.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Readily soluble in water and it reacts with it.
Viscosity: Not available.

Stability: Stable under ordinary conditions of use and storage. It must be kept in air-tight containers.
Hazardous Decomposition Products: It produces oxides of aluminum along with hydrochloric acid when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Incompatible with oxidizing material acids and alkalis.
Conditions to Avoid: Heat, Sun light, Incompatibles, Metals.

Toxicity to Animals: Not available.
Carcinogenic Effects: Not a reported carcinogen .
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.

Environmental Toxicity: Not available.
BOD5 and COD: Not available.
Persistence and degradability: Not available. It is soluble in water and unlikely to be persistent.
Bioaccumulative potential: Not available
Mobility: Not available. It is soluble in water and hence it is likely to be mobile.
Avoid draining the material in waterways.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused in accordance with federal, state, and local requirements.

DOT (USA) & ADR/RID Europe: Not Regulated.
IMDG: Not Regulated.
IATA: Not Regulated.

USA:
OSHA Hazards: Irritant.
SARA 311/312 Hazards: Immediate Health Hazard. See section 2.

European Labeling in Accordance with EC Directives:
H303: May be harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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