Aluminum Chlorohydrate or Aluminium Chlorohydrate USP Grade Solution and Powder Manufacturers (also Aluminium Sesquichlorohydrate), SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Aluminium Chlorohydrate or Aluminum Chlorohydrate, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Aluminium chlorohydrate: CAS Number: Dihydrate 12042-91-0 and Anhydrous 1327-41-9, EINECS EC Number: 215-477-2, Molecular Formula: AlnCl(3n-m)(OH)m, Molecular Weight: Dihydrate is 210.48 and Anhydrous is 174.45, HS Code ---**

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail prices, Uses etc available on these pages for Aluminium chlorohydrate powder and solution.

Aluminium chlorohydrate is an aluminium salts having the general formula AlnClAlnCl(3n-m)(OH)m. It is used in cosmetics as an antiperspirant and as a coagulant in water purification.

In water purification, this compound is preferred in some cases because of its high charge, which makes it more effective at destabilizing and removing suspended materials than other aluminium salts. Further, the high degree of neutralization of the HCl results in minimal impact on treated water pH when compared to other aluminium and iron salts.

Specifications of Aluminium Chlorohydrate Solution:
Appearance: Clear to yellowish hazy liquid.
Specific Gravity: 1.33 to 1.35
pH of 30% (w/w): 3.5 to 4.5
Aluminum (Al): 12.2 to 12.7%
Aluminium as (Al2O3): 23 to 24%
Chloride (Cl): 7.9 to 8.4%
Iron (Fe): 300ppm maximum
Arsenic (As2O3): 2ppm maximum
Lead (Pb): 10ppm maximum.

Aluminum Chlorohydrate Solution consists of complex basic aluminum chloride that is polymeric and encompasses a range of aluminum-to-chloride ratios between 1.91:1 and 2.10:1. The following solvents may be used: water, propylene glycol, dipropylene glycol, or alcohol. It contains the equivalent of not less than 90.0 percent and not more than 110.0 percent of the labeled concentration of anhydrous aluminum chlorohydrate.

Packaging and storage: Preserve in well-closed containers.
Labeling: Label Solution to state the solvent used and the claimed concentration of anhydrous aluminum chlorohydrate contained therein.
Identification:
A: A solution containing the equivalent of about 100 mg of anhydrous aluminum chlorohydrate per mL responds to the tests for Aluminum and for Chloride.
B: Identification of propylene glycol (where stated on the label): Add about 10 mL of isopropyl alcohol to 2 g of Solution, mix, and filter. Evaporate the filtrate to about 1 mL on a steam bath: the IR spectrum of a film of this solution on a silver chloride disk exhibits maxima only at the same wavelengths as that of a similar preparation of a film of propylene glycol.
C: Identification of dipropylene glycol (where stated on the label): Add about 10 mL of isopropyl alcohol to 2 g of Solution, mix, and filter. Evaporate the filtrate to about 1 mL on a steam bath: the IR spectrum of a film of this solution on a silver chloride disk exhibits maxima only at the same wavelengths as that of a similar preparation of a film of dipropylene glycol.
D: Identification of alcohol (where stated on the label): In a small beaker mix 5 drops of Solution with 1 mL of potassium permanganate solution (1 in 100) and 5 drops of 2 N sulfuric acid. Immediately cover the beaker with filter paper moistened with a freshly prepared solution of 0.1 g of sodium nitroferricyanide and 0.25 g of piperazine in 5 mL of water: an intense blue color is produced on the filter paper, the color fading after a few minutes.
pH: between 3.0 and 5.0, in a solution prepared by diluting 3 g of the solution with water to obtain 10 mL.
Arsenic: Prepare the Test Preparation using an accurately weighed quantity of the Solution. The limit is 2 ppm.
Heavy metals: Prepare the Test Preparation using an accurately weighed quantity of the Solution. The limit is 0.001%.
Limit of iron: To pass the test --- (75 micro-gm per g).
Content of aluminum: To pass the test.
Content of chloride: To pass the test.
Aluminum/chloride atomic ratio: --- the ratio is between 1.91:1 and 2.10:1.

Assay: Calculate the percentage of anhydrous aluminum chlorohydrate in the Solution by the formula:
Al{[26.98x + (17.01)(3x 1) + 35.453] / 26.98x}
in which Al is the percentage of aluminum found in the test for Content of aluminum, x is the aluminum/chloride atomic ratio, 26.98 is the atomic weight of aluminum, 17.01 is the molecular weight of the hydroxide ion (OH), and 35.453 is the atomic weight of chloride (Cl).

Certificate of Analysis of Aluminum Chlorohydrate Powder:
Color: Off-white to Slight yellow
Appearance: Fine Powder
Aluminum (Al): 23.5 - 27.5%
Chloride (Cl): 15.5 – 18.5%
Al:Cl atomic ratio: 1.91:1 – 2.10:1
pH (15% w/w): 4.0 – 4.8
Odor: Odorless.

Specifications of Aluminum Chlorohydrate USP Grade:
Aly(OH)3y-zClz·H2O
Aluminum chlorohydroxide.
Aluminum hydroxychloride.
Dihydrate --- 12042-91-0.
Anhydrous --- 1327-41-9.
Aluminum chlorohydroxide, dihydrate.
Aluminum hydroxychloride, dihydrate.
Dihydrate --- 210.48 --- CAS 12042-91-0.
Anhydrous --- 174.45 --- CAS 1327-41-9.

Aluminum Chlorohydrate consists of complex basic aluminum chloride that is polymeric and loosely hydrated and encompasses a range of aluminum to chloride atomic ratios between 1.91:1 and 2.10:1. It contains the equivalent of not less than 90.0 percent and not more than 110.0 percent of the labeled amount of anhydrous aluminum chlorohydrate.

Packaging and storage: Preserve in well-closed containers.
Labeling: The label states the content of anhydrous aluminum chlorohydrate.
Identification: A solution (1 in 10) responds to the tests for Aluminum and for Chloride.
pH: between 3.0 and 5.0, in a solution [15 in 100 (w/w)].
Arsenic: 2 micro-gm per g.
Heavy metals: 0.002%.
Limit of iron: To pass the test --- (150 micro-gm per g).
Content of aluminum: To pass the test.
Content of chloride: To pass the test.
Aluminum/chloride atomic ratio: ---: the ratio is between 1.91:1 and 2.10:1.

For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.

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Aluminum Chlorohydrate Solution or Aluminium Chlorohydrate Solution or Poly Aluminum Chloride SDS Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 29-Sep-20

Product Name & Other Names: Aluminum Chlorohydrate Solution or Aluminium Chlorohydrate Solution or Poly Aluminum Chloride.
CAS No.: 1327-41-9
EINECS: EC Number: 215-477-2
Molecular Weight: Varies
Chemical Formula: AlnCl(3n-m)(OH)m in water.
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008:

Acute toxicity, Oral (Category 5)
Skin corrosion/irritation (Category 2)
Serious eye damage/eye irritation (Category 2A)

Hazard statements:
H303: May be harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.

Precautionary statements:
P261: Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P262: Do not get in eyes, on skin, or on clothing.
P264 Wash skin thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+313: If skin irritation occurs: Get medical advice/attention.
P337+P313: If eye irritation persists: Get medical advice/ attention.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xi Irritant
Risk Phrase:
R22 Harmful if swallowed.
R36/38 Irritating to eyes and skin.

Product Name & Other Names: Aluminum Chlorohydrate Solution or Aluminium Chlorohydrate Solution or Poly Aluminum Chloride.
CAS No.: 1327-41-9
EINECS: EC Number: 215-477-2
Percent: 40-60% in water.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to Physician: Treat symptomatically.

Flammability of the Product: The product is not flammable.
Products of Combustion: It forms oxides of aluminum and hydrochloric acid when heated to decomposition.
Fire: Nonflammable.
Fire Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide.
Special Information In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Avoid dust/mist formation. Avoid breathing dust/mist. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Contain spilled material. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water and swab.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like oxidizing material, acids, alkalis, and combustible substances. It is to be stored in corrosive area.

Airborne Exposure Limits: None established. Assure it as below 2mg/m3.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Clear to yellowish liquid.
Odor: None
Odor threshold: Not available.
pH: 3 to 5.
Relative density: 1.3 to 1.4
Melting Point: -4C to -8C
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Readily soluble in water.
Viscosity: Not available.
Molecular Weight: Varies
Chemical Formula: AlnCl(3n-m)(OH)m in water.

Stability: Stable under ordinary conditions of use and storage. It must be kept in airtight containers.
Hazardous Decomposition Products: It produces oxides of aluminum along with hydrochloric acid when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Incompatible with oxidizing material acids and alkalis.
Conditions to Avoid: Heat, Sun light, Incompatibles, Metals.

Toxicity to Animals: Oral, rat: LD50 = 9187 mg/kg.
Carcinogenic Effects: Not a reported carcinogen.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.

Environmental Toxicity: Toxicity to fish: LC50 - fish - Not available
BOD5 and COD: Not available.
Persistence and Degradability: No information available.
Mobility: No information available.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.
Avoid draining the material in waterways.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused in accordance with federal, state, and local requirements.

DOT (USA) & ADR/RID Europe: Not Regulated.
IMDG: Not Regulated.
IATA: Not Regulated.

USA:
OSHA Hazards: Irritant.
SARA 311/312 Hazards: Immediate Health Hazard. See section 2.
California Prop 65: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

European Labeling in Accordance with EC Directives
H303: May be harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xi Irritant
Risk Phrase:
R22 Harmful if swallowed.
R36/38 Irritating to eyes and skin.

Disclaimer:
**************************
Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
**************************

Aluminum Chlorohydrate Powder or Aluminium Chlorohydrate Powder or Poly Aluminium Chloride SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 29-Sep-20

Product Name & Other Names: Aluminum Chlorohydrate Powder or Aluminium Chlorohydrate Powder or Poly Aluminium Chloride.
CAS No.: 1327-41-9
EINECS: EC Number: 215-477-2
Molecular Weight: Varies
Chemical Formula: AlnCl(3n-m)(OH)m
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008:

Acute toxicity, Oral (Category 5)
Skin corrosion/irritation (Category 2)
Serious eye damage/eye irritation (Category 2A)

Hazard statements:
H303: May be harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
Xi Irritant
Xn Harmful
Risk Phrases:
R22 Harmful if swallowed.
R36/38 Irritating to eyes and skin.

Product Name & Other Names: Aluminum Chlorohydrate Powder or Aluminium Chlorohydrate Powder or Poly Aluminium Chloride.
CAS No.: 1327-41-9
EINECS: EC Number: 215-477-2

Flammability of the Product: The product is not flammable.
Products of Combustion: It forms oxides of aluminum and hydrochloric acid when heated to decomposition.
Fire: Non flammable.
Fire Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide.
Special Information In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes.

Personal precautions, protective equipment and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Avoid dust/mist formation. Avoid breathing dust/mist. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Contain spilled material. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water and swab.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid contact with skin, eyes and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like oxidizing material, acids, alkalis and combustible substances. It is to be stored in corrosive area.

Appearance: White to yellowish Powder.
Odor: None
Odor threshold: Not available.
pH: Not available.
Relative density: 1.7
Melting Point: Not available.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Readily soluble in water.
Viscosity: Not available.
Molecular Weight: Varies
Chemical Formula: AlnCl(3n-m)(OH)m

Routes of Entry: Inhalation, Ingestion, Contact.
Toxicity to Animals: Oral, rat: LD50 = 9187 mg/kg.
Carcinogenic Effects: Not a reported carcinogen.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.

USA:
SARA 311/312 Hazards: As per section 2. Immediate Acute Health Hazard.
California Prop 65: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

European Labeling in Accordance with EC Directives
H303: May be harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
Xi Irritant
Xn Harmful
Risk Phrases:
R22 Harmful if swallowed.
R36/38 Irritating to eyes and skin.

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