Tributylamine or TBA Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Tributylamine or TBA, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc.

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Tributylamine or TBA: CAS Number: 102-82-9, EINECS EC Number: 203-058-7, Molecular Formula: C12H27N or [CH3(CH2)3]3N, Molecular Weight: 185.35, HS Code 2921 19 99

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SDS MSDS Sheet of Tributylamine or TBA Manufacturers

Tributylamine
TBA Pure Suppliers
Tributylamine

Tributylamine or TBA is an organic compound with the molecular formula (C4H9)3N. It is a colorless liquid with an amine-like odor. Tributylamine is used as a catalyst and as a solvent in organic syntheses and polymerization.

General Properties and Specifications of Tributylamine or TBA:
Appearance: Colorless to pale yellow liquid.
Odor: Ammonia-like odor.
Assay: 99% minimum.
Water: 0.2% maximum.
Relative density: about 0.78
Melting point: -70C literature.
Boiling point: 214C literature.
Flash point: 63C literature.
Auto-ignition temperature: 210C.
Solubility: Slightly soluble in water. Soluble in acetone. Very soluble in ethanol, ethyl ether.

We also manufacture and supply as under:

n-Butylamine

Dibutylamine

Diethylamine

Tertiary Butylamine

Tributylamine

Manufacturers:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30

e-mail: info@mubychem.com

USA, Canada, Mexico and other American
neighbouring buyers may
e-mail: us@mubychem.com
Call toll-free 1-844-682-9243 (1-844-MUBYCHEM)

Manufacturers india
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Last 28 August, 2022

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Tributylamine or TBA SDS GHS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet
27-Mar-21

1. Product Identification

Product Name & Other Names: Tributylamine or TBA.
CAS No.: 102-82-9
EINECS EC No.: 203-058-7
Molecular Formula: C12H27N or [CH3(CH2)3]3N
Molecular Weight: 185.35
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP)
:

Flammable liquids (Category 4), H227
Acute toxicity, Oral (Category 4), H302
Acute toxicity, Dermal (Category 1), H310
Skin irritation (Category 2), H315
Acute toxicity, Inhalation (Category 2), H330

Labeling according to Regulation (EC) No 1272/2008

GHS Label Elements
Toxic
Toxic

Signal Words: Danger

Hazard statements:
H227: Combustible liquid
H302: Harmful if swallowed.
H310: Fatal in contact with skin.
H330: Fatal if inhaled.
H315 Causes skin irritation.

Precautionary statements:
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/light/…/equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P330: Rinse mouth.
P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P403+233+235: Store in a well-ventilated place. Keep container tightly closed. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to authorized agents only.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard symbols:
T+ Very toxic
Xi Irritant.
R-phrases:
R22 Harmful if swallowed.
R26/27 Very toxic by inhalation and in contact with skin.
R38 Irritating to skin.

3. Composition/Information on Ingredients

Product Name & Other Names: Tributylamine or TBA.
CAS No.: 102-82-9
EINECS EC No.: 203-058-7

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

5. Fire Fighting Measures

Flammability of the Product: Flammable.
Flash Points: 63C literature.
Products of Combustion: Carbon dioxide, Carbon monoxide, Nitrogen oxides and fumes.
Explosion: Explosive in presence of heat.
Fire Extinguishing Media: Use dry chemical, foam, water spray, carbon dioxide. Flammable liquid and vapor. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas. Never direct a water jet in the container to prevent any splashing of the product which could cause spreading of the fire. Cool containing vessels with water jet to prevent pressure build-up, auto-ignition, or explosion.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

6. Accidental Release Measures

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Avoid mist formation. Avoid breathing mist/vapors. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Remove all sources of ignition. Provide proper ventilation. Keep people away from and upwind of spill/leak. Entry to non-involved personnel should be controlled around the leakage area by roping off. Absorb the material on a porous, inert material such as earth, sand, or vermiculite. Carefully sweep up the material without causing dust. Dispose of in accordance with local regulations.
Large liquid spillages should be contained by use of sand or another inert material. The spillage should be transferred to a suitable container and recovered or disposed of in accordance with local regulations. Because of the danger of spontaneous combustion, any combustible material, such as cloth, used for cleaning spillages, should be saturated with water, and disposed of promptly, preferably by incineration.

7. Handling and Storage

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, acids, bases. Store locked up.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: Not Established.
Ventilation System
: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: Colorless to pale yellow liquid.
Odor: Ammonia-like odor.
Odor threshold: Not available.
pH: Not available.
Relative density: about 0.78
Boiling Point: 214C literature.
Melting Point: -70C literature
Flash Point: 63C literature.
Auto-ignition temperature: 210C.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Slightly soluble in water. Soluble in acetone. Very soluble in ethanol, ethyl ether.
Viscosity: Not available.
Molecular Formula: C12H27N or [CH3(CH2)3]3N
Molecular Weight: 185.35

10. Stability and Reactivity

Stability: Stable under ordinary conditions of use and storage. Vapor/air-mixtures are explosive at high temperature. Forms explosive mixtures with air on intense heating.
Hazardous Decomposition Products: It emits Carbon dioxide, Carbon monoxide, Nitrogen oxides & Fumes.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, Acids, Bases.
Conditions to Avoid: Incompatibles, oxidizing agents, heat flame & light.

11. Toxicological Information

Toxicity data:
LD50 Oral Rat: 420 mg/kg.
LC50 Inhalation Rat: 4 h – 0.5 mg/l.
LD50 Dermal Rabbit: 195 mg/kg.
Carcinogenicity: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology: No information found
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: No information found
Neurotoxicity: No information found.

12. Ecological Information

Toxicity to fish: LC50 Leuciscus idus (Golden orfe) 57.5 - 63.0 mg/l; 48 h.
Toxicity to daphnia and other aquatic invertebrates: semi-static test EC50 - Daphnia magna (Water flea) - 8 mg/l - 48 h
Persistence and Degradability: Unlikely to persist due to water solubility.
Mobility: Likely to be mobile due to water solubility.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state, and local requirements.

14. Transport Information

DOT USA, TDG Canada & ADR/RID Europe:
Shipping Name: TRIBUTYLAMINE
Hazard Class: 6.1; Packing Group: II
UN Number: UN2542
IMDG/IMO:
Shipping Name: TRIBUTYLAMINE
Hazard Class: 6.1; Packing Group: II
UN Number: UN2542
IATA/ICAO:
Shipping Name: TRIBUTYLAMINE
Hazard Class: 6.1; Packing Group: II
UN Number: UN2542

15. Regulatory Information

USA:
SARA 311/312 Hazards
: Fire Hazard, Chronic Health Hazard. See section 2.
California prop. 65: Contains no chemical subject to California Prop 65.

16. Other Information

European Labeling in Accordance with EC Directives:
H227: Combustible liquid
H302: Harmful if swallowed.
H310: Fatal in contact with skin.
H330: Fatal if inhaled.
H315 Causes skin irritation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard symbols:
T+ Very toxic
Xi Irritant.
R-phrases:
R22 Harmful if swallowed.
R26/27 Very toxic by inhalation and in contact with skin.
R38 Irritating to skin.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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