Potassium ferricyanide or Potassium ferricyanate or Potassium hexacyanoferrate(III) or Red Prussiate of Potash Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Potassium ferricyanide or Potassium ferricyanate, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc.

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Potassium ferricyanide or Potassium ferricyanate or Potassium hexacyanoferrate(III) or Red Prussiate of Potash: CAS Number: 13746-66-2, EINECS EC Number: 237-323-3, Molecular Formula: K3[Fe(CN)6], Molecular Weight: 329.24, HS Code ---**

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SDS MSDS Sheet of Potassium ferricyanide or Potassium ferricyanate or Potassium hexacyanoferrate(III) or Red Prussiate of Potash Manufacturers

Potassium ferricyanide
Potassium ferricyanate or Potassium hexacyanoferrate(III) or Red Prussiate of Potash Pure Suppliers
Potassium ferricyanide

Potassium ferricyanide or Potassium ferricyanate is the chemical compound with the formula K3[Fe(CN)6]. It is soluble in water and its solution shows some green-yellow fluorescence. The compound is use in blueprint drawing and in photography. Potassium ferricyanide is used to reduce the size of color dots without reducing their number. It is also used in black-and-white photography. The compound is also used to harden iron and steel, in electroplating, dyeing wool, as a laboratory reagent, and as a mild oxidizing agent in organic chemistry.

Properties and General Specifications of Potassium ferricyanide or Potassium ferricyanate or Potassium hexacyanoferrate(III):
Appearance: Deep red crystals, sometimes small pellets, orange to dark red powder.
Relative density: 1.89.
Melting point: 300C.
Boiling point: Decomposes
Solubility: Slightly soluble in alcohol, soluble in acid, soluble in water.
Assay by Na2S2O3Titration: 99.0% minimum.
pH: around 6.
Chloride: 0.2% maximum.
Insoluble matter: 0.005% maximum.
Ferrocyanide: 0. 5% maximum.
Sulfate: 0.01 % maximum.

Potassium Ferricyanide Analytical Reagent Grade Specifications:
Potassium Hexacyanoferrate(III)
K3Fe(CN)6 --- Formula Wt 329.25
CAS Number 13746-66-2

REQUIREMENTS
Assay: 99.0% K3Fe(CN)6

MAXIMUM ALLOWABLE
Insoluble matter: 0.005%
Chloride (Cl): 0.01%
Sulfate (SO4): 0.01%
Ferro compounds: 0.05% as ferrocyanide radical [Fe(CN)6]4–

We also manufacture and supply as under:

Potassium ferrocyanide trihydrate

Potassium ferricyanide

Sodium ferrocyanide.

Manufacturers:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
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Last 27 August, 2022

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Potassium ferricyanide or Potassium ferricyanate or Potassium hexacyanoferrate(III) or Red Prussiate of Potash SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet

1. Product Identification

Product Name & Other Names: Potassium ferricyanide or Potassium ferricyanate or Potassium hexacyanoferrate(III) or Red Prussiate of Potash.
CAS No.: 13746-66-2
EINECS EC Number: 237-323-3
Chemical Formula: K3[Fe(CN)6]
Molecular Weight: 329.24
Relevant uses and uses advised against (if any): Industrial Manufacturing
SUPPLIER: As per Letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.

Labeling according GHS & Regulation (EC) No 1272/2008

GHS Label Elements
NONE

Signal Word: None

Hazards not otherwise classified (HNOC):

May causes mild skin irritation.
May Causes mild eye irritation.

Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.

3. Composition/Information on Ingredients

Product Name & Other Names: Potassium ferricyanide or Potassium ferricyanate or Potassium hexacyanoferrate(III) or Red Prussiate of Potash.
CAS No.: 13746-66-2
EINECS EC Number: 237-323-3

4. First Aid Measures

Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty.
Ingestion: Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing.
Skin Contact:
Wash exposed area with soap and water. Get medical advice if irritation develops.
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention.

5. Fire Fighting Measures

Fire: Not considered to be a fire hazard.
Explosion: Not considered to be an explosion hazard.
Fire Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Use means suitable for extinguishing surrounding fire.
Special Information: Use protective clothing and breathing equipment appropriate for the surrounding fire. Carbon oxides, Nitrogen oxides (NOx), Potassium oxides, Iron oxide are formed in fire condition. Thermal decomposition can release of irritating gases and vapors.

6. Accidental Release Measures

Personal precautions, protective equipment and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental  precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to legal requirements.
Large Spill: Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to legal requirements.

7. Handling and Storage

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid contact with skin, eyes and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong acids, strong oxidizing agents, ammonia, hydrochloric acid, cyanides. Containers may be hazardous when empty.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits:
USA ACGIH TLV: TWA: 1 mg/m3.
OSHA PEL: (Vacated) TWA: 1 mg/m3.
Ventilation System: In general, dilution ventilation is a satisfactory health hazard control for this substance. However, if conditions of use create discomfort to the worker, a local exhaust system should be considered.
Personal Respirators (NIOSH Approved): Not expected to require personal respirator usage. For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Safety glasses. Maintain eye wash fountain and quick-drench facilities.

9. Physical and Chemical Properties

Appearance: Deep red crystals, sometimes small pellets, orange to dark red powder.
Odor: Not available.
Odor threshold: Not available.
pH: around 6.
Relative density: 1.89
Melting point/freezing point: 300C.
Initial boiling point and boiling range: Decomposes.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Hardly soluble in water.
Viscosity: Not available.
Chemical Formula: K3[Fe(CN)6]
Molecular Weight: 329.24

10. Stability and Reactivity

Stability: Stable under ordinary conditions of use and storage. Light sensitive.
Hazardous Decomposition Products: When heated to decomposition, substance may emit oxides of carbon and nitrogen along with potassium and iron compound.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong acids, strong oxidizing agents, ammonia, hydrochloric acid, cyanides. Contact with acids liberates very toxic gas. Heating can release hazardous gases.
Conditions to Avoid: No information found.

11. Toxicological Information

LD50 Oral - Mouse - 2970 mg/kg.
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as probable or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

12. Ecological Information

Toxicity:
Toxicity to fish LC50 - Poecilia reticulata (guppy) - 2,8 mg/l - 96 h.
Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna (Water flea) - 549 mg/l - 48 h
Persistence and Degradability: No information available.
Mobility: No information available.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused material in accordance with federal, state and local requirements.

14. Transport Information

DOT: Not regulated as dangerous goods.
ADR/RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods

15. Regulatory Information

SARA 311/312: Acute: No; Chronic: No; Fire: No; Pressure: No; Reactivity: No (Pure / Solid)
SARA 313: Not applicable
SARA 302: Not applicable
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

16. Other Information

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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