Polyvinyl Acetate EP USP NF BP Ph Eur FCC Food Grade Manufacturers, with SDS GHS MSDS Sheet |
Supplier, Manufacturer, Exporter of Polyvinyl Acetat, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc. The products are offered as per required specifications and in correct shape and size in mm or meshs or microns as specified by the buyer. The participating units have one or more accreditations like FDA - cGMP and GLP approval, ISO-9001 Certified, "REACH" Registered, ISO-14001, ISO/IEC 17025, ISO-22000, FSSC 22000, ISO 45001, Kosher Certified, Halal Certified, HACCP, FSSAI. We offer Commercial Pure & IP BP EP Ph Eur USP NF JP FCC Food Grade Analytical Reagent Grades of Chemicals |
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Polyvinyl Acetate: CAS Number: 9003-20-7, EINECS EC Number: yyyyy, Molecular Formula:[CH2CH(O2CCH3)]n, Molecular Weight: yyyyy HS Code ---**
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Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Polyvinyl Acetate.
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MSDS Sheet of Polyvinyl Acetate Manufacturers
Spanish Acetato de polivinilo Fabricantes
Portuguese Fabricantes de Acetato de Polivinila
Polyvinyl Acetate
Pure EP USP NF BP FCC Food Grade Suppliers
Poly(vinyl acetate) BP Ph Eur Grade Specifications
Ph Eur
CAS 9003-20-7
DEFINITION
Poly(vinyl acetate) is a thermoplastic polymer obtained by polymerisation of vinyl acetate using a suitable starter, without solvent or with water or 2-propanol. The vast majority of the acetate moieties are attached to non-neighbouring carbon atoms of the chain. The index n is about 100 - 17 000. The relative molecular mass lies between 10 000 and 1500 000. The viscosity is 4 to 250 mPa·s. The ester value, which characterises the degree of hydrolysis, is 615 to 675.
CHARACTERS
Appearance: White or almost white powder or colourless granules or beads.
Solubility: Practically insoluble in water, freely soluble in ethyl acetate, soluble in alcohol. It is hygroscopic and swells in water. It softens at temperatures above 40-50C.
IDENTIFICATION
A. Infrared absorption spectrophotometry. To pass the test.
B. It complies with the test for viscosity (see Tests).
C. Saponify 0.500 g in a mixture of 25.0 ml of 0.5 M alcoholic potassium hydroxide and 25.0 ml of water. The solution obtained gives the reaction of acetates.
TESTS
Solution S: Suspend 50.0 g in 100 ml of ethyl acetate R in a borosilicate glass flask with a ground-glass neck. Heat under a reflux condenser with constant stirring for 30 min. Allow to cool. Filter through a tared sintered glass filter (16) (2.1.2) and wash the residue with 50.0 ml of ethyl acetate, pour the filtrate into a 250 ml graduated flask. Dilute to 250 ml with ethyl acetate.
Appearance of solution: Solution S is clear and colourless.
Viscosity: 85 per cent to 115 per cent of the value stated on the label.
Determine the viscosity immediately after preparation of solution S at 20 ± 0.1C by using a rolling ball viscosimeter.
Acid value: Maximum 2.0, determined on 5.0 g dissolved in 50 ml of alcohol by shaking for 3 h.
Ester value: 615 to 675.
Saponify 0.500 g in a mixture of 25.0 ml of 0.5 M alcoholic potassium hydroxide and 25.0 ml of water.
Residual peroxides: Maximum 100 ppm, calculated as hydrogen peroxide.
Vinyl acetate: maximum 0.3 per cent to meet the test.
Heavy metals: Maximum 10 ppm.
Loss on drying: Maximum 1.0 per cent, determined on 1.000 g by drying in an oven at 105C.
Sulphated ash: Maximum 0.1 per cent, determined on 1.0 g.
LABELLING
The label states:
— the nominal relative molecular mass;
— the viscosity.
Polyvinyl Acetate FCC Food Grade Specifications
CAS 9003-20-7
DESCRIPTION
Polyvinyl Acetate occurs as a clear, water white to pale yellow, solid resin. It is prepared by the polymerization of vinyl acetate. After completion of polymerization, the resin is freed of traces of residual catalyst (usually a peroxide), monomer, and/or solvent by vacuum drying, steam sparging, washing, or any combination of these treatments. The resin is soluble in acetone, but it is insoluble in water.
Function: Masticatory substance in chewing gum base.
Identification: The infrared absorption spectrum of a melted sample on a potassium bromide plate exhibits relative maxima at the same wavelengths as those of a typical spectrum as shown in the section on Infrared Spectra, using the same test conditions as specified therein.
Free Acetic Acid: Not more than 0.05%.
Lead: Not more than 3 mg/kg.
Loss on Drying: Not more than 1.0%.
Molecular Weight: Not less than 2000.
We also supply Polyvinyl Acetate EP Grade.
Specifications of Polyvinyl Acetate USP NF Grade:
(C4H6O2 )n
Vinyl acetate homopolymer
Vinyl acetate resin --- CAS 9003-20-7.
UNII: 32K497ZK2U
DEFINITION
Polyvinyl acetate is a thermoplastic polymer, represented by the formula: (C4H6O2 )n in which the value of n lies between approximately 100 and 17,000.
IDENTIFICATION
A. Procedure:
Sample: 100 mg of Polyvinyl Acetate
Analysis: Dissolve the Sample in 2.5 mL of acetone, place two drops on a potassium bromide plate, and dry to evaporate the solvent.
Acceptance criteria: IR absorption spectrum.
B. Procedure:
Sample: 0.5 g of Polyvinyl Acetate
Analysis: Saponify the Sample in a mixture of 25.0 mL of 0.5 N alcoholic potassium hydroxide and 25.0 mL of water.
Acceptance criteria: The solution so obtained meets the requirements of the tests for Acetate.
Residue on Ignition: NMT 0.1%
Residual Peroxides:
Sample: 0.85 g of Polyvinyl Acetate
Analysis: Place the Sample in a borosilicate glass flask with a ground-glass neck. Add 10.0 mL of ethyl acetate, and heat under a reflux condenser with constant agitation. Allow to cool. Replace the air in the container with oxygen-free nitrogen and add a solution of 1.0 mL of glacial acetic acid and 0.5 g of sodium iodide in 40.0 mL of water. Shake thoroughly and allow to stand protected from light for 20 min. Titrate with 0.005 N sodium thiosulfate until the yellow color is discharged. Perform a blank titration.
Acceptance criteria: The difference between the titration volumes is not greater than 1.0 mL; and NMT 100 ppm, calculated as hydrogen peroxide, is found.
Limit of Vinyl Acetate: To pass the test.
Fats and Fixed Oils: To pass the test --- The acid value is NMT 0.5.
Fats and Fixed Oils: To pass the test --- The ester value, calculated from the Saponification Value and the Acid Value, is between 615 and 675.
Loss on Drying: Dry 1.5 g at 100C for 2 h in a vacuum: it loses NMT 1.0% of its weight.
Average Molecular Weight and Molecular Weight Distribution: To pass the test --- The values of weight-average molecular weight and polydispersity are, respectively, NLT 85% and NMT 115% of their respective values as stated on the label.
For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.
Please see Polyvinyl Acetate Dispersion.
We also manufacture and supply as under:
Manufacturers:
MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
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e-mail: info@mubychem.com
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Last
22 March, 2024
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Polyvinyl Acetate SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 13-Nov-20
1. PRODUCT DESCRIPTION
Product Name & Other Names: Polyvinyl acetate, Vinyl acetate polymer
CAS Number: 9003-20-7
EINECS EC Number: NA
Molecular Weight: -
Molecular Formula: [CH2CH(O2CCH3)]n
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.
2. HAZARD IDENTIFICATION
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.
Labeling according to GHS & Regulation (EC) No 1272/2008
GHS Label Elements None |
Signal Words: None
Hazards not otherwise classified (HNOC):
May causes mild skin irritation.
May causes mild eye irritation.
Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Product Name & Other Names: Polyvinyl acetate, Vinyl acetate polymer
CAS Number: 9003-20-7
EINECS EC Number: NA
4. FIRST AID MEASURES
Always get medical attention after the first aid is over.
Emergency and First Aid Procedures:
Eyes - Flush with water for at least 15 minutes, raising and lowering eyelids occasionally. Get medical attention if irritation persists.
Skin - Thoroughly wash exposed area for at least 15 minutes. Remove contaminated clothing. Launder contaminated clothing before reuse. Get medical attention if irritation persists.
Ingestion - If Polyvinyl Acetate is swallowed, if conscious, give plenty of water. Immediately call a physician. Never give anything by mouth to an unconscious person.
Inhalation - Remove to fresh air. Give oxygen if breathing is difficult; give artificial respiration if breathing has stopped. Get medical attention.
5. FIREFIGHTING PROCEDURES
Auto ignition Temperature: 426C / 798.8F
Extinguisher Media: Water spray. Carbon dioxide (CO 2). Dry chemical. alcohol-resistant foam.
Flammable Limits in Air % by Volume: N/A
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.
6. SPILL OR LEAK PROCEDURES
Personal precautions, protective equipment, and emergency procedures: Ventilate area of leak or spill. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container. Small amounts of residue may be flushed to sewer with plenty of water or as per law.
7. SPECIAL PRECAUTIONS
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Keep Polyvinyl Acetate in a well closed container stored under cold to warm conditions, 2 to 40 C, (36 to 104F) in a ventilated area and protected from sunlight. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing. Protect against physical damage. Containers of this material may be hazardous when empty since they retain product residues.
8. SPECIAL PROTECTION INFORMATION
Exposure Guidelines: This product does not contain any hazardous materials with occupational exposure limits established by the region-specific regulatory bodies.
Respiratory Protection (Specify Type): None needed under normal conditions of use with adequate ventilation. NIOSH approved equipment should be worn if PELs are exceeded.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.
9. PHYSICAL DATA
Appearance and Odor: Solid clear material. Odorless.
Odor: Not available.
Odor threshold: Not available.
pH: Not available.
Relative density: 1.18
Melting point/freezing point: Not available.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility(ies): Not available.
Viscosity: Not available.
Molecular Formula: [CH2CH(O2CCH3)]n
10. REACTIVITY DATA
Stability: Polyvinyl Acetate is stable
Conditions to Avoid: Heat.
Incompatibility (Materials to Avoid): Strong oxidizing.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide
Hazardous Polymerization: Will not occur.
11. TOXICITY DATA
Oral LD50: LD50 Oral - rat - > 2,000 mg/kg
Oral LD50 Based on ATE data, the classification criteria are not met. ATE > 2000 mg/kg.
Dermal LD50 Based on ATE data, the classification criteria are not met. ATE > 2000 mg/kg.
Carcinogenicity: This product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC, NTP, ACGIH & OSHA.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.
12. ECOLOGICAL DATA
Toxicity: Avoid release into the environment.
Persistence and Degradability: No information available.
Mobility: No information available.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.
13. DISPOSAL INFORMATION
Waste Disposal Methods: Dispose Polyvinyl Acetate in accordance with all applicable Federal, State and Local regulations.
14. TRANSPORT INFORMATION
DOT USA, TDG Canada & ADR/RID Europe: Not regulated.
IMDG & IATA: Not regulated.
15. REGULATORY INFORMATION
USA:
SARA 302 Components: SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards: No SARA Hazards
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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