Peracetic acid or Ethaneperoxoic acid or Peroxyacetic acid Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Peracetic acid or Ethaneperoxoic acid or Peroxyacetic acid, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc.

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Peracetic acid or Ethaneperoxoic acid or Peroxyacetic acid: CAS Number: 79-21-0, EINECS EC Number: 201-186-8, Molecular Formula: C2H4O3 or CH3COOOH, Molecular Weight: 76.05, HS Code 29159070 or 29152990

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SDS MSDS Sheet of Peracetic acid or Ethaneperoxoic acid or Peroxyacetic acid Manufacturers

Peracetic acid
Ethaneperoxoic acid or Peroxyacetic acid Pure Suppliers
Peracetic acid

Peracetic acid or Ethaneperoxoic acid or Peroxyacetic acid is a colorless liquid with a strong, pungent acrid odor. Used as a bactericide and fungicide, especially in food processing; as a reagent in making caprolactam and glycerol; as an oxidant for preparing epoxy compounds; as a bleaching agent; a sterilizing agent; and as a polymerization catalyst for polyester resins. Peracetic acid is also used in dairy and cheese processing plants, on food processing equipment, and in pasteurizers in breweries, wineries, and beverage plants. It is generally offered as a solution in acetic acid.

General Properties and Specifications of Peracetic acid or Peroxyacetic acid or Ethaneperoxoic acid:
Appearance: Colorless liquid.
Odor: Acrid.
Melting point: around 0C literature.
Boiling point: 110C literature.
Flash point: 40C literature.
Autoignition temperature: 200C literature.
Relative density: around 1.23 literature.


Typical Composition of Peracetic Acid 5% solution:
Appearance: Colorless liquid.
Odor: Pungent
Color 15 maximum.
Peracetic Acid: 5.0 % minimum. (Other concentrations available).
Relative Density: 1.01 to 1.03
H2O2: 20 % minimum.
Active Oxygen: 9% minimum.
Acetic Acid: 11% minimum.
pH: 1.0 to 2.0


METHOD OF ANALYSIS:
Weight accurately 0.2 gm sample of Per Acetic Acid in 250 ml iodine flash containing 50 ml distilled water and add 2 gm Sodium Bicarbonate AR and 3 gm of potassium iodide AR and stopper the flash and keep in dark for 15 minutes. Add slowly 10 ml of 5N Sulfuric Acid to acidify and liberated iodine with 0.1 N sodium thiosulphate to the end point and 1 ml starch as indicator. Perform titration till solution become colorless. Note the titration value (BR)

Calculation:
Per Acetic Acid = (BR x normality of Sodium thiosulphate x 15.2)/ (Weight of sample taken)

We also manufacture and supply as under:

Acetylacetone Peroxide

Glacial Acetic Acid

Cyanoacetic Acid

Carbamide Peroxide

Benzoyl Peroxide

Hydrogen Peroxide

Magnesium Perchlorate

Periodic Acid.

Manufacturers:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30

e-mail: info@mubychem.com

USA, Canada, Mexico and other American
neighbouring buyers may
e-mail: us@mubychem.com
Call toll-free 1-844-682-9243 (1-844-MUBYCHEM)

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Copyright and Usual Disclaimer is Applicable.
Last 27 August, 2022

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Peracetic acid or Ethaneperoxoic acid or Peroxyacetic acid, SDS GHS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet
04-Nov-20

1. Product Identification

Product Name/Synonyms: Peracetic acid or Ethaneperoxoic acid or Peroxyacetic acid.
CAS No.: 79-21-0
EINECS EC No.: 201-186-8
Molecular Formula: C2H4O3 or CH3COOO
Molecular Weight: 76.05
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Supplier: As per letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP)
:

Flammable liquids (Category 3) H226
Organic peroxides (Type F), H242
Acute toxicity, Oral (Category 4) H302
Acute toxicity, Inhalation (Category 4) H332
Skin corrosion (Category 1C), H314

Labeling according to Regulation (EC) No 1272/2008

GHS Label Elements
Corrosive
Corrosive

GHS Label Elements
Flammable
Flammable

GHS Label Elements
irritant.png
Irritant

Signal Words: Danger

Hazard statements:
H226: Flammable liquid and vapor.
H242: Heating may cause a fire.
H302: Harmful if swallowed.
H332: Harmful if inhaled
H314: Causes severe skin burns and eye damage.

Precautionary statements:
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/light/…/equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P330: Rinse mouth.
P362: Take off contaminated clothing and wash before reuse.
P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P309 + P310 IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.
P370+378: In case of fire: Use Water spray, Carbon dioxide (CO2), Foam, Dry powder, and Sand for extinction.
P403+233+235: Store in a well-ventilated place. Keep container tightly closed. Keep cool.
P410: Protect from sunlight.
P501: Dispose of contents/container to authorized agents only.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard symbols:
O = Oxidizing R7
C = Corrosive R34
Xn = Harmful R20/21/22
Flammable: R10
R-phrases:
R7 May cause fire.
R 10 Flammable.
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R34 Causes burns.
R41 Risk of serious damage to eyes.

3. Composition/Information on Ingredients

Product Name/Synonyms: Peracetic acid or Ethaneperoxoic acid or Peroxyacetic acid.
CAS No.: 79-21-0
EINECS EC No.: 201-186-8
Solution in Acetic Acid and Water.

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to physicians: Product is a corrosive material.

5. Fire Fighting Measures

Flammability of the Product: Flammable.
Flash Points: 40C
Products of Combustion: Carbon dioxide, Carbon monoxide, fumes.
Fire: Inflammable.
Explosion: Explosive in presence of heat.
Fire Extinguishing Media: Use Water spray, Carbon dioxide (CO2), Foam, Dry powder, and Sand for extinction. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Water spray or fog is preferred, if water not available use dry chemical, CO2, or regular foam. Flammable liquid and vapor. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas. Never direct a water jet in the container to prevent any splashing of the product which could cause spreading of the fire. Cool containing vessels with water jet to prevent pressure build-up, auto-ignition, or explosion.
Extinguishing Media Not recommended: Avoid using solid water jet as it may scatter the fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures it may produce toxic or irritating fumes. These substances will accelerate burning when involved in a fire. Some may burn rapidly with flare burning effect. Some may decompose explosively when heated or involved in a fire. May ignite combustibles (wood paper, oil, clothing, etc.). Thermal decomposition can lead to release of irritating and toxic gases and vapors.

6. Accidental Release Measures

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage:
Small Spill: Avoid mist formation. Avoid breathing mist. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Remove all sources of ignition. Provide proper ventilation. Absorb the material on a porous, inert material such as earth, sand, or vermiculite. Carefully sweep solid/powder up the material without causing dust. Dispose of in accordance with local regulations. The spillage should be transferred to a suitable container and recovered or disposed of in accordance with local regulations. Because of the danger of spontaneous combustion, any combustible material, such as cloth, used for cleaning spillages, should be saturated with water, and disposed of promptly, preferably by incineration.

7. Handling and Storage

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Provide appropriate exhaust ventilation at places where dust/mist/vapor is formed. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Do not ingest. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces. If you feel unwell, seek medical attention.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, strong reducing agents, strong acids, strong bases, powdered metals, and organic materials.
Keep the product in its original container well sealed, in a dry and ventilated area, away from potential sources of ignition and protected from light. Protect against physical damage. Recommended storage is refrigeration. Avoid heating above: 30C.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: Not Established. Keep it below 0.2 ppm. Provide adequate ventilation.
Ventilation System
: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance Colorless liquid.
Odor: Acrid.
Odor threshold: Not available.
pH: Not available.
Relative density: around 1.23 literature.
Melting point/freezing point: around 0C literature.
Initial boiling point and boiling range: 110C literature.
Flash point: 40C literature.
Auto-ignition temperature: 200C literature.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility(ies): Not available.
Viscosity: Not available.
Molecular Formula: C2H4O3 or CH3COOO
Molecular Weight: 76.05

10. Stability and Reactivity

Stability: Stable under ordinary conditions of use and storage. Vapor/air-mixtures are explosive at intense warming. Violent reactions possible with: Strong acids, alkalis, reducing agents.
Hazardous Decomposition Products: It emits Carbon dioxide, Carbon monoxide & Toxic Fumes.
Hazardous Polymerization: Will not occur.
Incompatibilities: Heat, strong oxidizing agents, strong reducing agents, strong acids, strong bases. Powdered metals, Organic materials.
Conditions to Avoid: Incompatibles, heat, flame, sparks & light.

11. Toxicological Information

Toxicity data
LD50 Oral Rat = 50 -500 mg/kg/ (35% Peracetic acid)
LD50 Oral Rat = 1026-1780 mg/kg/ (15% Peracetic acid)
LD50 Oral Rat = 185-3622 mg/kg/ (2.6-6.11% Peracetic acid).
LD50 Dermal Rat = 1957 mg/kg/ (15% Peracetic acid)
LD50 Dermal Rat = 1147 mg/kg/ (5% Peracetic acid)
LD50 Dermal Rat = >2000 mg/kg/ (Peracetic acid 0.15%-0.89%)
Carcinogenicity: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: No information found.

12. Ecological Information

Toxicity to fish: No information available.
Persistence and Degradability
: Soluble in water Persistence is unlikely.
Bioaccumulation/ Accumulation: No information available.
Mobility: Will likely be mobile in the environment due to its water solubility.
Results of PBT and vPvB assessment: No data available for assessment.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state, and local requirements.

14. Transport Information

DOT USA, TDG Canada & ADR/RID Europe:
UN Number: UN3105
Shipping Name: ORGANIC PEROXIDE TYPE D, LIQUID ((Acetic acid, Peroxyacetic acid))
Hazard Class: 5.2; Packing Group: II.
IMDG/IMO & IATA:
UN Number: UN3105
Shipping Name: ORGANIC PEROXIDE TYPE D, LIQUID ((Acetic acid, Peroxyacetic acid))
Hazard Class: 5.2; Packing Group: II.

15. Regulatory Information

USA:
SARA 311/312 Hazards: Fire Hazard: Yes, Immediate Health Hazard: Acute Yes.

16. Other Information

European Labeling in Accordance with EC Directives:
H226: Flammable liquid and vapor.
H242: Heating may cause a fire.
H302: Harmful if swallowed.
H332: Harmful if inhaled
H314: Causes severe skin burns and eye damage.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard symbols:
O = Oxidizing R7
C = Corrosive R34
Xn = Harmful R20/21/22
Flammable: R10
R-phrases:
R7 May cause fire.
R 10 Flammable.
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R34 Causes burns.
R41 Risk of serious damage to eyes.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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