Iron (II) Sulfate Ferrous Sulphate BP Ferrous Sulfate USP, Pure Analytical Reagent FCC Food Grade Manufacturers, with SDS MSDS Sheet

Supplier, Manufacturer, Exporter of Iron Sulphate or Ferrous Sulfate, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc.

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Ferrous Sulphate CAS Number 7720-78-7 (anhydrous), 17375-41-6 (monohydrate), 7782-63-0 (heptahydrate), EINECS EC Number 231-753-5, HS Code ---**; Molecular Weight 151.91 for Anhydrous, Molecular Formula: FeSO4

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Iron (II) Sulfate or Ferrous Sulphate monohydrate heptahydrate and anhydrous.

Iron (II) sulfate or iron (II) sulphate or ferrous sulfate is the chemical compound with the formula FeSO4. It is used medically to treat iron deficiency, and also for industrial applications. Known since ancient times as green vitriol, the blue-green heptahydrate is the most common form of this material.

DEFINITION
Hydrated ferrous sulphate from which part of the water of hydration has been removed by drying.
Content: 86.0 per cent to 90.0 per cent.

CHARACTERS
Appearance: Greyish-white powder.
Solubility: Slowly but freely soluble in water, very soluble in boiling water, practically insoluble in ethanol (96 per cent).
It is oxidized in moist air, becoming brown.

IDENTIFICATION
A. It gives the reactions of sulphates.
B. It gives reaction (a) of iron.
C. It complies with the limits of the assay.

TESTS
Solution S: Dissolve 2.00 g in a 5 per cent V/V solution of lead-free nitric acid R and dilute to 100.0 ml with the same acid.
pH: 3.0 to 4.0.
Chlorides: Maximum 300 ppm.
Chromium: Maximum 1.00 × 102 ppm.
Copper:Maximum 50.0 ppm.
Ferric ions: Maximum 0.50 per cent.
Manganese: Maximum 0.10 per cent.
Nickel: Maximum 1.00 × 102 ppm.
Zinc: Maximum 1.00 × 10² ppm.

Ferrous Sulfate USP Grade
FeSO4.7H2O 278.02
Sulfuric acid, iron(2+) salt (1:1), heptahydrate.
Iron(2+) sulfate (1:1) heptahydrate [CAS 7782-63-0].
Anhydrous 151.91 [CAS 7720-78-7].

Ferrous Sulfate contains an amount of FeSO4 equivalent to not less than 99.5 percent and not more than 104.5 percent of FeSO4.7H2O.

Identification: It responds to the tests for Ferrous Salts 191 and for Sulfate 191 .
Arsenic: Transfer 1.0 g to a round-bottom, 100-mL flask fitted with a glass joint, add 40 mL of 9 N sulfuric acid and 2 mL of potassium bromide solution (3 in 10), and immediately connect the flask to a condenser having a matching glass joint and a reservoir with a water jacket that is cooled by ice-water. Heat the flask gently over a low flame until the solid dissolves, then distill until 25 mL of distillate collects in the reservoir. Transfer this distillate to the arsine generator flask, and wash the condenser and the reservoir with several small portions of water, adding the washings to the generator flask. Swirl to mix, add bromine until the color of the solution is slightly yellow, and dilute with water to 35 mL. The limit is 3 ppm.
Lead: the limit is 0.001%.
Mercury: It meets the requirement.

Dried Ferrous Sulfate USP Grade
FeSO4.xH2O
Sulfuric acid, iron(2+) salt (1:1), hydrate.
Iron(2+) sulfate (1:1) hydrate [CAS 13463-43-9].
Anhydrous 151.91 [CAS 7720-78-7].

Dried Ferrous Sulfate contains not less than 86.0 percent and not more than 89.0 percent of anhydrous ferrous sulfate (FeSO4).

DESCRIPTION
Ferrous Sulfate occurs as pale, blue-green crystals or granules that are efflorescent in dry air. In moist air, it oxidizes readily to form a brown-yellow, basic ferric sulfate. A 1:10 aqueous solution has a pH of about 3.7. One gram dissolves in 1.5 mL of water at 25° and in 0.5 mL of boiling water. It is insoluble in alcohol.
Function: Nutrient.

REQUIREMENTS
Identification: A sample gives positive tests for Ferrous Salts (Iron) and for Sulfate.
Assay: Not less than 99.5% and not more than 104.5% of FeSO4·7H2O.
Lead: Not more than 2 mg/kg.
Mercury: Not more than 1 mg/kg.

DESCRIPTION
Ferrous Sulfate, Dried, occurs as a gray-white to buff colored powder consisting primarily of FeSO4·H2O, with varying amounts of FeSO4·4H2O. It dissolves slowly in water, but is insoluble in alcohol.
Function: Nutrient.

REQUIREMENTS
Identification: A sample gives positive tests for Ferrous Salts (Iron) and for Sulfate.
Assay: Not less than 86.0% and not more than 89.0% of FeSO4.
Insoluble Substances: Not more than 0.05%.
Lead: Not more than 2 mg/kg.
Mercury: Not more than 1 mg/kg.

Ferrous Sulfate Heptahydrate Analytical Reagent Grade
Iron (II) Sulfate Heptahydrate

NOTE: Due to inherent oxidation, ferric ion (Fe3+) content may increase on storage.

We also manufacture and supply micro-encapsulated Iron Sulfate or Ferrous Sulphate.

For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.

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Ferrous Sulfate or Ferrous Sulphate SDS GHS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 21-Oct-20

Product Name & Other Names: Ferrous Sulfate Heptahydrate, Ferrous Sulphate Heptahydrate.
CAS No.: 7782-63-0
EINECS EC Number: 231-753-5
Molecular Weight: 278.01
Chemical Formula: FeSO4.7H2O
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Oral (Category 4), H302
Skin irritation (Category 2), H315
Eye irritation (Category 2), H319

Hazard statements:
H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.

Precautionary statements:
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P330: Rinse mouth.
P362: Take off contaminated clothing and wash before reuse.
P301+312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+352: IF ON SKIN: Wash with soap and water.
P332+313: If skin irritation occurs: Get medical advice/attention.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.
P501: Dispose of contents/container to authorized agents only.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
Xn Harmful.
Xi = Irritant.
Risk Phrases:
R22 Harmful if swallowed.
R36/38 Irritating to eyes and skin.

Product Name & Other Names: Ferrous Sulfate Heptahydrate, Ferrous Sulphate Heptahydrate.
CAS No.: 7782-63-0
EINECS EC Number: 231-753-5

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Flammability of the Product: Non-flammable.
Products of Combustion: Sulfur oxides, Oxides of Iron etc.
Fire: Not considered to be a fire hazard.
Explosion: Not an Explosive item.
Fire Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Use means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. Containers may explode on heating.

Personal precautions, protective equipment, and emergency procedures: Ventilate area of leak or spill. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents and alkalis.

Airborne Exposure Limits:
TWA 1 mg/m3: USA ACGIH Threshold Limit Values (2011)
REL 1 mg/m3: USA NIOSH: Pocket Guide to Chemical Hazards (2010)
TWA 1 mg/m3: USA OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Bluish green powder or crystals.
Odor: It is odorless.
Odor threshold: Not available.
pH: 3-4.
Relative density: around 1.9
Boiling Point: >300C.
Melting Point: 64C.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: It is freely soluble in water.
Viscosity: Not available.
Molecular Weight: 278.01
Chemical Formula: FeSO4.7H2O (Other Hydrates also have the same CAS Number).

Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits toxic sulfur fumes and iron oxide when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents and alkalies.
Conditions to Avoid: Incompatibles heat, light and moisture.

Toxicity data
LD50 Oral - Mouse - 1,520 mg/kg (Ferrous sulfate heptahydrate)
LD 50 Oral (Rat) - 319 mg/kg (Ferrous sulfate heptahydrate)
LD50 Intraperitoneal - Mouse - 245 mg/kg (Ferrous sulfate heptahydrate)
LD50 Intravenous - Mouse - 51 mg/kg (Ferrous sulfate heptahydrate)
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

Toxicity to fish: LC 50 (Brook trout (Salvelinus fontinalis), 96 h): 0.41 mg/l
Toxicity to daphnia and other aquatic invertebrates: EC 50 (Water flea (Daphnia magna), 48 h): 6.15 mg/l
Environmental Toxicity: This chemical is expected to cause little oxygen depletion in aquatic systems.
PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state, and local requirements.

DOT USA, ADR/RID Europe: Not regulated.
Canada TDG Classification: Not regulated.
IATA: Not regulated.

USA:
OSHA Hazards: Not Hazardous as per OSHA
SARA 313 Components: No chemicals in this material are subject to the reporting requirements.
SARA 311/312 Hazards: Immediate (acute) health hazard Delayed (chronic) health hazard.
California Prop.65: Not Listed.

European Labeling in Accordance with EC Directives:
H302 = Harmful if swallowed.
H315 = Causes skin irritation.
H319 = Causes serious eye irritation.

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

Insoluble matter	0.01%
Chloride (Cl)	0.001%
Phosphate (PO4)	0.001%
Copper (Cu)	0.005%
Manganese (Mn)	0.05%
Zinc (Zn)	0.005%
Ferric ion (Fe3+)	0.1%
Substances not precipitated by ammonium hydroxide	0.05%

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