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Iron (II), Sulfate Ferrous Sulphate BP Ferrous Sulfate USP, Pure AR LR ACS Analytical Reagent FCC Food Grade Manufacturers, SDS MSDS Sheet

Ferrous Sulphate CAS Number 7720-78-7 (anhydrous), 17375-41-6 (monohydrate), 7782-63-0 (heptahydrate), EINECS EC Number 231-753-5, HS Code ---**; Molecular Weight 151.91 for Anhydrous, Molecular Formula: FeSO4

For MSDS Sheet Click
MSDS Sheet of Ferrous Sulphate Ferric Sulfate Manufacturers

Ferrous Sulphate
Dried Monohydrate & Heptahydrate, Commercial Pure BP LR AR ACS Analytical Reagent Grade
Dried Ferrous Sulphate Ferrous Sulphate

Iron (II) sulfate or iron (II) sulphate or ferrous sulfate is the chemical compound with the formula FeSO4. It is used medically to treat iron deficiency, and also for industrial applications. Known since ancient times as green vitriol, the blue-green heptahydrate is the most common form of this material.

Ferrous Sulphate BP Grade Ph Eur

Dried Ferrous Sulphate
General Notices
FeSO4 -- 151.9 -- 13463-43-9

DEFINITION
Hydrated ferrous sulphate from which part of the water of hydration has been removed by drying.
Content: 86.0 per cent to 90.0 per cent.

CHARACTERS
Appearance: Greyish-white powder.
Solubility: Slowly but freely soluble in water, very soluble in boiling water, practically insoluble in ethanol (96 per cent).
It is oxidized in moist air, becoming brown.

IDENTIFICATION
A. It gives the reactions of sulphates.
B. It gives reaction (a) of iron.
C. It complies with the limits of the assay.

TESTS
Solution S: Dissolve 2.00 g in a 5 per cent V/V solution of lead-free nitric acid R and dilute to 100.0 ml with the same acid.
pH: 3.0 to 4.0.
Chlorides: Maximum 300 ppm.
Chromium: Maximum 1.00 × 102 ppm.
Copper:Maximum 50.0 ppm.
Ferric ions: Maximum 0.50 per cent.
Manganese: Maximum 0.10 per cent.
Nickel: Maximum 1.00 × 102 ppm.
Zinc: Maximum 1.00 × 102 ppm.


Ferrous Sulfate FCC Food Grade

FeSO4·7H2O Formula weight 278.02
CAS: [7782-63-0]

DESCRIPTION
Ferrous Sulfate occurs as pale, blue-green crystals or granules that are efflorescent in dry air. In moist air, it oxidizes readily to form a brown-yellow, basic ferric sulfate. A 1:10 aqueous solution has a pH of about 3.7. One gram dissolves in 1.5 mL of water at 25° and in 0.5 mL of boiling water. It is insoluble in alcohol.
Function: Nutrient.

REQUIREMENTS
Identification: A sample gives positive tests for Ferrous Salts (Iron) and for Sulfate.
Assay: Not less than 99.5% and not more than 104.5% of FeSO4·7H2O.
Lead: Not more than 2 mg/kg.
Mercury: Not more than 1 mg/kg.


Ferrous Sulfate, Dried FCC Food Grade

FeSO4·xH2O Formula weight, anhydrous 151.91
CAS: [7720-78-7]

DESCRIPTION
Ferrous Sulfate, Dried, occurs as a gray-white to buff colored powder consisting primarily of FeSO4·H2O, with varying amounts of FeSO4·4H2O. It dissolves slowly in water, but is insoluble in alcohol.
Function: Nutrient.

REQUIREMENTS
Identification: A sample gives positive tests for Ferrous Salts (Iron) and for Sulfate.
Assay: Not less than 86.0% and not more than 89.0% of FeSO4.
Insoluble Substances: Not more than 0.05%.
Lead: Not more than 2 mg/kg.
Mercury: Not more than 1 mg/kg.


Ferrous Sulfate Heptahydrate ACS AR Analytical Reagent Grade
Iron (II) Sulfate Heptahydrate

FeSO4 . 7H2O
Formula weight 278.01
CAS Number 7782-63-0

NOTE: Due to inherent oxidation, ferric ion (Fe3+) content may increase on storage.

REQUIREMENTS
Assay ≥99.0% FeSO4 . 7H2O

MAXIMUM ALLOWABLE
Insoluble matter 0.01%
Chloride (Cl) 0.001%
Phosphate (PO4) 0.001%
Copper (Cu) 0.005%
Manganese (Mn) 0.05%
Zinc (Zn) 0.005%
Ferric ion (Fe3+) 0.1%
Substances not precipitated by ammonium hydroxide 0.05%

For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.

Manufacturers:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
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e-mail: info@mubychem.com

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Call toll-free 1-844-682-9243 (1-844-MUBYCHEM)

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Last 14 August, 2017

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Sodium Gluconate Sodium Hydroxide Pellets
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Ferrous Sulfate SDS GHS, MSDS Sheet, Material Safety Data Sheet

1. Product Identification

Synonyms: Ferrous Sulfate Heptahydrate, Ferrous Sulphate Heptahydrate. Other Hydrates also have the same CAS Number.
CAS No.: 7782-63-0
EINECS EC Number: 231-753-5
Molecular Weight: 278.01
Chemical Formula: FeSO4.7H2O (Other Hydrates also have the same CAS Number).
Recommended usage: Industrial Manufacturing.
Suppliers: As per letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Oral (Category 4), H302
Skin irritation (Category 2), H315
Eye irritation (Category 2), H319

Labeling according GHS & Regulation (EC) No 1272/2008

GHS Label Elements
Irritant
Irritant

Signal Words: Warning

Hazard statements:
H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.

Precautionary statements:
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P330: Rinse mouth.
P362: Take off contaminated clothing and wash before reuse.
P301+312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+352: IF ON SKIN: Wash with soap and water.
P332+313: If skin irritation occurs: Get medical advice/attention.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.
P501: Dispose of contents/container to authorized agents only.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Xn Harmful R22
Xi Irritant R36/38
For the full text of the H-statements & R-phrases mentioned in this Section, see Section 16.

OSHA Hazards: Not Hazardous as per OSHA
HMIS (Perceived): Health hazard: 2, Flammability: 0, Physical hazards: E
NFPA (Perceived): Health hazard: 2, Fire: 0, Reactivity Hazard: 0, Contact Rating: 3 - Severe, Protective Equip: Goggles, Lab Coat.
3. Composition/Information on Ingredients
Ingredient: Ferrous Sulfate
CAS No.: 7782-63-0
EINECS EC Number: 231-753-5
Percent: 97 - 100%

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

5. Fire Fighting Measures

Flammability of the Product: Non-flammable.
Products of Combustion: Sulfur oxides, Oxides of Iron etc.
Fire: Ferrous Sulfate is not considered to be a fire hazard.
Explosion: Not an Explosive item.
Fire Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Use means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes. On decomposition it may emit hydrogen iodide. Containers may explode on heating

6. Accidental Release Measures

Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Avoid touching the spilled material. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system.

7. Handling and Storage

Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment.
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Wash hands thoroughly after handling. Provide appropriate exhaust ventilation at places where dust is formed. If you feel unwell, seek medical attention.
Keep Ferrous Sulfate in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits:
Exposure Limit           Source
TWA 1 mg/m3           US. ACGIH Threshold Limit Values (2011)
REL 1 mg/m3            US. NIOSH: Pocket Guide to Chemical Hazards (2010)
TWA 1 mg/m3           US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: Ferrous Sulfate is bluish green powder or crystals.
Odor: It is odorless.
Solubility: It is freely soluble in water.
pH: 3-4.
Density: 1.9 g/mL at 20C (68F)
Molecular Weight:
278.01
Chemical Formula: FeSO4.7H2O (Other Hydrates also have the same CAS Number).
% Volatile by volume @ 21C (70F): -
Boiling Point: >300C
Melting Point: 64C

10. Stability and Reactivity

Stability: Ferrous Sulfate is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits toxic sulfur fumes and iron oxide when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents and alkalies.
Conditions to Avoid: Incompatibles heat, light and moisture.

11. Toxicological Information

Acute toxicity
Harmful if swallowed. Harmful if inhaled.
Toxicity data
LD50 Oral - Mouse - 1,520 mg/kg (Ferrous sulfate heptahydrate)
LD 50 Oral (Rat) - 319 mg/kg (Ferrous sulfate heptahydrate)
LD50 Intraperitoneal - Mouse - 245 mg/kg (Ferrous sulfate heptahydrate)
LD50 Intravenous - Mouse - 51 mg/kg (Ferrous sulfate heptahydrate)
Carcinogenic Effects: Not a reported carcinogen by IARC NTP ACGIH OSHA.

12. Ecological Information

Toxicity to fish: LC 50 (Brook trout (Salvelinus fontinalis), 96 h): 0.41 mg/l
Toxicity to daphnia and other aquatic invertebrates: EC 50 (Water flea (Daphnia magna), 48 h): 6.15 mg/l
Environmental Toxicity: This chemical is expected to cause little oxygen depletion in aquatic systems.
BOD5 and COD: Not available.
Toxicity of the Products of Biodegradation: The products of degradation and the product are not classed as toxic.
PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information

US DOT, ADR/RID Classification: Not regulated.
Canada TDG Classification: Not regulated.
IATA: Not regulated.

15. Regulatory Information

USA:
OSHA Hazards
: Not Hazardous as per OSHA
TSCA: Not listed
SARA 313 Components: No chemicals in this material are subject to the reporting requirements.
SARA 311/312 Hazards: Immediate (acute) health hazard Delayed (chronic) health hazard.
California Prop.65: Not Listed.
Massachusetts Right To Know Components: Listed.
Pennsylvania Right To Know Components: Listed.
New Jersey Right To Know Components: Listed.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.

Canada - WHMIS: Uncontrolled product; Disclosure at 1%.
Canada - DSL/NDSL: Listed on Canada's DSL List.

16. Other Information

EINECS: EC Number: 231-753-5
H302 = Harmful if swallowed.
H315 = Causes skin irritation.
H319 = Causes serious eye irritation.
Xn Harmful.
Xi = Irritant.
R22 Harmful if swallowed.
R36/38 Irritating to eyes and skin.
Safety Phrases:
S-2 Keep out of reach of children. S-24/25 Avoid contact with skin and eyes. S-26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S-46 If swallowed seek medical advice immediately.

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.