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Ferric Oxide (Iron III Oxide) USP NF BP Grade Manufacturers, SDS GHS MSDS Sheet
Ferric Oxide (Iron III Oxide): CAS Number: 1309-37-1, EINECS EC Number: 215-168-2, Molecular Formula: Fe2O3, Molecular Weight: 159.69, HS Code ---**
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SDS MSDS Sheet of Ferric Oxide (Iron III Oxide) Manufacturers
Pure BP USP NF Grade Iron III Oxide
Iron(III) oxide or ferric oxide is the inorganic compound with the formula Fe2O3. It is one of the three main oxides of iron, the other two being iron(II) oxide (FeO), which is rare, and iron(II,III) oxide (Fe3O4), which also occurs naturally as the mineral magnetite.
Ferric Oxide USP NF
Ferric Oxide contains not less than 97.0 percent and not more than 100.5 percent of Fe2O3, calculated on the ignited basis.
Packaging and storage: Preserve in well-closed containers.
Identification: Dissolve 0.5 g in 50 mL of hydrochloric acid, and dilute with water to 200 mL: the solution so obtained responds to the test for Ferric Salts under Iron..
Water-soluble substances: Digest 2.0 g in 100 mL of water on a boiling water bath for 2 hours, filter, and wash the filter with water. Evaporate the filtrate and washings, and dry the residue at 105 for 1 hour: the weight of the dried residue is not more than 20 mg (1.0%).
Acid-insoluble substances: Digest 2.0 g in 25 mL of hydrochloric acid by boiling for 20 minutes. Add 100 mL of hot water, and filter quantitatively through a tared filtering crucible, with the aid of hot wash water, until the filtrate tests negative for chloride. Dry the crucible and contents at 105 for 1 hour: the residue weighs not more than 6 mg (0.3%).
Organic colors and lakes: Place 1.0 g in each of 3 beakers, and add 25 mL of each of the following reagents, respectively: 1-chloronaphthalene, alcohol, and chloroform. Heat the beakers containing alcohol and chloroform just to boiling. Heat the other beaker on a boiling water bath for 15 minutes, with occasional swirling. Filter the contents of the beakers through retentive, solvent-resistant filter paper. If any of the filtrates shows visible turbidity, centrifuge for 15 minutes. Record the spectra against respective solvent blanks in 1-cm cells from 350 to 750 nm. No peak, above the noise level, with a slope greater than +0.001 absorbance unit per nm is found.
Mercury: The limit is 3 µg per g.
Limit of arsenic: The limit is 3 µg per g.
Limit of lead: The limit is 0.001%. (0.001%).
Assay: Digest about 1.5 g of Ferric Oxide, accurately weighed, in 25 mL of hydrochloric acid on a water bath until dissolved. Add 10 mL of hydrogen peroxide and evaporate on a water bath almost to dryness in order to volatilize all hydrogen peroxide. Dissolve the residue by warming with 5 mL of hydrochloric acid; add 25 mL of water; filter into a 250-mL volumetric flask, washing the filter with water; and add water to volume. Transfer a 50-mL aliquot to a glass-stoppered flask, add 3 g of potassium iodide and 5 mL of hydrochloric acid, and insert the stopper into the flask. Allow the mixture to stand for 15 minutes, add 50 mL of water, and titrate the liberated iodine with 0.1 N sodium thiosulfate, using starch as the indicator. Perform a blank test with the same quantities of reagents and in the same manner, and make any necessary corrections. Each mL of 0.1 N sodium thiosulfate is equivalent to 7.985 mg of Fe2O3. Ignite about 2 g of Ferric Oxide at 800 ± 25 to constant weight as directed under Loss on Ignition 733 , to enable calculation of the percentage of Fe2O3 on the ignited basis. [NOTE—Ignited Ferric Oxide is hygroscopic.]
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Last : 11 April, 2017
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Ferric Oxide or Iron III Oxide SDS MSDS Sheet, Material Safety Data Sheet
Section 1: Chemical Product and Identification
Product Name: Ferric Oxide or Iron III Oxide.
EINECS EC-No.: 215-168-2
Chemical Formula: Fe2O3
Molecular Weight: 159.69
Intended Use: Laboratory and Industrial Manufacturing.
SUPPLIER: As per letterhead.
Section 2: Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.
Labeling according to GHS & Regulation (EC) No 1272/2008
GHS Label Elements
Signal Word: None
Not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200)
Hazards not otherwise classified (HNOC):
May causes mild skin irritation.
May Causes mild eye irritation and mechanical damage.
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.
Section 3: Composition and Information on Ingredients
Composition: Ferric Oxide
EINECS EC-No.: 215-168-2
% by Weight: 100
Section 4: First Aid Measures
Always seek medical attention after first aid measures are provided.
Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention.
Skin Contact: In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Thoroughly clean shoes and clothes before reuse. Get medical attention.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately.
Section 5: Fire and Explosion Data
Flammability of the Product: Not applicable.
Auto-Ignition Temperature: Not applicable.
Products of Combustion: Some metallic oxides.
Explosion Hazards in Presence of Various Substances: Slightly explosive in presence of open flames and sparks. Non-explosive in presence of shocks.
Fire Fighting Media and Instructions: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Section 6: Accidental Release Measures
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to legal authority requirements.
Large Spill: Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow drain.
Section 7: Handling and Storage
Precautions: Keep away from heat. Keep away from sources of ignition. Do not breathe dust.
Storage: Keep in container tightly closed. Keep container in a cool, well-ventilated area.
Section 8: Exposure Controls/Personal Protection
Exposure Limits: United States OSHA: 10 mg/m3 TWA. United Kingdom, WEL - TWA: 5 mg/m3 TWA (fume, as Fe); 10 mg/m3.
Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Section 9: Physical and Chemical Properties
Physical state and appearance: Rust colored solid.
Taste: Not available.
Chemical Formula: Fe2O3
Molecular Weight: 159.69
pH (1% soln/water): Not available.
Melting Point: 1538 deg C
Specific Gravity: 5.2
Solubility: Insoluble in water.
Section 10: Stability and Reactivity Data
Stability: It is stable.
Incompatibility with various substances: Contact with incompatible materials. Heat, sparks, flames. Avoid dust formation.
Polymerization: Will not occur.
Section 11: Toxicological Information
Toxicity to Animals:
LD50/oral/rat = > 10,000 mg/kg(Diiron trioxide).
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as probable or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Environmental Toxicity: Not available.
Section 12: Ecological Information
Ecotoxicity: Not available.
Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Section 13: Disposal Considerations
Waste Disposal: Waste must be disposed of in accordance legal regulations.
Section 14: Transport Information
DOT (USA) & ADR/RID: Not dangerous goods
TDG/IMDG: Not dangerous goods
IATA: Not dangerous goods
Section 15: Other Regulatory Information
OSHA: Not considered hazardous by the OSHA Hazard Communication Standard
Section 313 (Specific toxic chemical listings): Substance is not listed.
TSCA (Toxic Substances Control Act): CAS# 1309-37-1 is listed on the TSCA Inventory.
Canada: CAS# 1309-37-1 is listed on Canada's DSL List
EINECS EC-No.: 215-168-2
Section 16 - Additional Information
Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.