Diglyme or Diethylene glycol dimethyl ether or 2-Methoxyethyl ether or Bis(2-methoxyethyl) ether or Dimethyldiglycol Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Diglyme or Diethylene glycol dimethyl ether, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Diglyme or Diethylene glycol dimethyl ether or 2-Methoxyethyl ether or Bis(2-methoxyethyl) ether or Dimethyldiglycol: CAS Number: 111-96-6, EINECS EC Number: 203-924-4, Molecular Formula: C6H14O3 or (CH3OCH2CH2)2O, Molecular Weight: 134.17, HS Code 2909 19 90

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SDS MSDS Sheet of Diglyme or Diethylene glycol dimethyl ether or 2-Methoxyethyl ether or Bis(2-methoxyethyl) ether or Dimethyldiglycol Manufacturers

Diglyme
Diethylene glycol dimethyl ether or 2-Methoxyethyl ether or Bis(2-methoxyethyl) ether or Dimethyldiglycol Pure Suppliers
Diglyme Diethylene glycol dimethyl ether

Diglyme or Diethylene glycol dimethyl ether or 2-Methoxyethyl ether or Bis(2-methoxyethyl) ether or Dimethyldiglycol is a solvent with a high boiling point. It is a colorless liquid with a slight ether-like odor. It is miscible with water as well as organic solvents. Diglyme is used as a solvent in hydroboration reactions.

General Properties and Specifications of Diglyme or Diethylene glycol dimethyl ether or 2-Methoxyethyl ether, Bis(2-methoxyethyl) ether, Dimethyldiglycol:
Appearance: Clear colorless liquid.
Odor: Mild odor.
Assay: 99.5%
pH: about 7
Water by KF: 0.005%
Residue on evaporation: 0.005%
Peroxide: 0.005% maximum.
Relative density: about 0.94
Melting point: -64C literature.
Flash point: 51C.
Boiling point: 162C literature.
Solubility: Miscible with water. Miscible with alcohol, ether, hydrocarbon solvents.
Air Sensitive, Hygroscopic.

For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.

We also manufacture and supply as under:

Butyl Diglycol

Diglyme

Dipropylene Glycol

Ethylene Glycol Monoethyl Ether

Ethylene Glycol Monostearate

Ethylene Glycol Distearate

Hexylene Glycol

Glycolic Acid

Monoglyme

Propylene Glycol.

Manufacturers:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30

e-mail: info@mubychem.com

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Last 21 April, 2024

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Diglyme or Diethylene glycol dimethyl ether or 2-Methoxyethyl ether or Bis(2-methoxyethyl) ether or Dimethyldiglycol SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 01-Mar-21

1. Product Identification

Product Name & Other Names: Diglyme or Diethylene glycol dimethyl ether or 2-Methoxyethyl ether or Bis(2-methoxyethyl) ether or Dimethyldiglycol.
CAS No.: 111-96-6.
EINECS EC Number: 203-924-4
Molecular Formula: C6H14O3 or (CH3OCH2CH2)2O
Molecular Weight: 134.17
Relevant uses and uses advised against (if any): Laboratory and Industrial Use.
Supplier: As per letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Flammable liquids Category 3, H226
Reproductive toxicity Category 1B, H360FD

Labeling according GHS USA & Regulation (EC) No 1272/2008

GHS Label Elements
flammable.png
Flammable

GHS Label Elements
healthhazard.png
Health Hazard

Signal Words: Danger

Hazard Statements:
H226: Flammable liquid and vapor.
H360D: May damage fertility. May damage the unborn child.

Precautionary Statements:
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/light/…/equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash contaminated parts thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+352: IF ON SKIN: Wash with plenty of soap and water.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P333+313: If skin irritation or a rash occurs: Get medical advice/attention.
P370+378: In case of fire: Use Water fog. Alcohol foam. Dry chemical. Polymer foam. Dry chemical powder. Carbon dioxide (CO2).  Do not use a solid water stream as it may scatter and spread fire.
P403+233+235: Store in a well-ventilated place. Keep container tightly closed. Keep cool.
P362: Take off contaminated clothing and wash before reuse.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/national regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
F Flammable
Xn Harmful
Risk Phrases:
R10 Flammable
R60 May impair fertility.
R61 May cause harm to the unborn child.

3. Composition/Information on Ingredients

Product Name & Other Names: Diglyme or Diethylene glycol dimethyl ether or 2-Methoxyethyl ether or Bis(2-methoxyethyl) ether or Dimethyldiglycol.
CAS No.: 111-96-6.
EINECS EC Number: 203-924-4

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do not use mouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Get medical attention.
Ingestion: Rinse mouth. Do not induce vomiting without medical advice. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Never give anything by mouth to a victim who is unconscious or is having convulsions. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Use a mild soap if available. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. For minor skin contact, avoid spreading material on unaffected skin.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

5. Fire Fighting Measures

Flammability of the Product: Flammable. Containers may explode when heated.
Products of Combustion: Carbon oxides and fumes.
Fire Extinguishing Media: Water fog. Alcohol foam. Dry chemical. Polymer foam. Dry chemical powder. Carbon dioxide (CO2). Do not use a solid water stream as it may scatter and spread fire. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes.
Special Information: Fire may produce irritating, corrosive, and/or toxic gases. In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.
Keep away from heat and sources of ignition. Flash back possible over considerable distance. Beware of vapors accumulating to form explosive concentrations .Vapors can accumulate in low areas.

6. Accidental Release Measures

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental  precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep up and remove to an approved disposal container. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Vapors can accumulate in low areas.
Dike the spilled material, where this is possible. Prevent entry into waterways, sewers, basements, or confined areas.

7. Handling and Storage

Precautions for safe handling: Do not handle or store near an open flame, heat, or other sources of ignition. All equipment used when handling the product must be grounded. Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Avoid prolonged exposure. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from heat, sources of ignition (spark or flame) and sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like oxidizing agents. Air Sensitive, Hygroscopic.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: Exposure guidelines have not been established for this product.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: Clear colorless liquid.
Odor: Mild odor.
Odor threshold: Not available.
pH: about 7.
Relative density: about 0.94
Flash Point: 51C.
Boiling point: 162C literature.
Melting point/Freezing point: -64C literature
Auto-ignition temperature: 440C.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility(ies): Miscible with water. Miscible with alcohol, ether, hydrocarbon solvents.
Viscosity: Not available.
Molecular Formula: C6H14O3 or (CH3OCH2CH2)2O
Molecular Weight: 134.17

10. Stability and Reactivity

Stability: It is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits carbon oxides and toxic fumes on decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Oxidizing agents.
Conditions to Avoid: Avoid heat, sparks, open flames, and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials.

11. Toxicological Information

Toxicity data:
LD50 Oral -Rat: 7500 mg/kg.
LC50 Inhalation -Rat: 11000 mg/m3 7 h.
Carcinogenicity: Not expected to be hazardous by OSHA ACGIH and NTP criteria.
Mutagenic Effects: Mutagenic effects have occurred in experimental animals
Developmental Toxicity: Not available.
Reproductive Effects: May damage fertility. May damage the unborn child.

12. Ecological Information

Toxicity to fish: LC50 - Pimephales promelas (fathead minnow) - 8.569 mg/l - 96 h.
Toxicity to daphnia and other aquatic invertebrates: semi-static test EC50 - Daphnia magna (Water flea) - 943 mg/l - 48 h.
Persistence and Degradability: Persistence is unlikely due to water solubility.
Mobility: Likely to be mobile.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with legal requirement.

14. Transport Information

DOT USA, TDG Canada & ADR/RID Europe:
Proper shipping name: ETHERS, N.O.S. (Bis(2-methoxyethyl)ether).
Class: 3; UN number: 3271; Packing group: III.
IATA & IMDG/IMO:
Proper shipping name: ETHERS, N.O.S. (Bis(2-methoxyethyl)ether).
Class: 3; UN number: 3271; Packing group: III.

15. Regulatory Information

USA:
SARA 302 Components
: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components: Does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels of SARA Title III, Section 313.
SARA 311/312 Hazards: Fire Hazard, Acute Health Hazard. See section 2.

Section 16 - Additional Information

European/International Regulations European Labeling in Accordance with EC Directives
H226: Flammable liquid and vapor.
H360D: May damage fertility. May damage the unborn child.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols
:
F Flammable
Xn Harmful
Risk Phrases:
R10 Flammable
R60 May impair fertility.
R61 May cause harm to the unborn child.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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