Cyclohexanone or Ketohexamethylene Pure & Reagent Grade Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Cyclohexanone or Ketohexamethylene Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc.

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Cyclohexanone or Ketohexamethylene: CAS Number: 108-94-1, EINECS EC Number: 203-631-1, Molecular Formula: C6H10O, Molecular Weight: 98.14, FEMA Number 3909, HS Code 2914 22 00

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SDS MSDS Sheet of Cyclohexanone or Ketohexamethylene Manufacturers

Cyclohexanone
Ketohexamethylene Reagent Grade Pure Suppliers
Cyclohexanone

Cyclohexanone or Ketohexamethylene is the organic compound with the formula (CH2)5CO. Cyclohexanone is slightly soluble in water and miscible with common organic solvents. Cyclohexanone is used in pharmaceutical industry and as a solvent in adhesives, rubber, plastics.

General Properties and Specifications of Cyclohexanone or Ketohexamethylene:
Appearance: Almost colorless liquid.
Odor: Pleasant odor.
Assay: 99.5%
Water by KF: 0.05% maximum.
Residue on evaporation: 0.05% maximum.
Relative density: 0.95
Malting point: -47C literature.
Boiling point: 155C literature.
Flash point: 44C literature.
Auto-ignition temperature: 420C.
Solubility: Slightly soluble in water.


Cyclohexanone Analytical Reagent Grade Specifications:
C6H10O --- Formula Weight 98.14
CAS Number 108-94-1

REQUIREMENTS
Assay: 99% C6H10O

MAXIMUM ALLOWABLE
Color (APHA): 10
Residue after evaporation: 0.05%
Water (H2O): 0.05%

We also manufacture and supply as under:

Acetone

Acetophenone

Acetylacetone

Cycloheximide

Cyclohexane

Cyclohexene

Cyclohexanol

Cyclohexanone

Kojic Acid or 5-Hydroxy-2-Hydroxymethyl-4-Pyranone.

Manufacturers:

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30

e-mail: info@mubychem.com

USA, Canada, Mexico and other American
neighbouring buyers may
e-mail: us@mubychem.com
Call toll-free 1-877-682-9243 (1-877-MUBYCHEM)

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Last 10 October, 2023

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Cyclohexanone or Ketohexamethylene SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 28-Feb-21

1. Product Identification

Product Name & Other Names: Cyclohexanone or Ketohexamethylene.
CAS No.: 108-94-1
EINECS EC Number: 203-631-1
FEMA Number: 3909
Molecular Formula: C6H10O
Molecular Weight: 98.14
Relevant uses and uses advised against (if any): Laboratory and Industrial Use.
Supplier: As per letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Flammable liquids Category 3, H226
Acute toxicity, oral Category 4, H302
Acute toxicity, dermal Category 4, H312
Acute toxicity, inhalation Category 4, H332
Skin irritation Category 2, H315
Serious eye damage Category 1, H318

Labeling according to GHS USA & Regulation (EC) No 1272/2008

GHS Label Elements
flammable.png
Flammable

GHS Label Elements
corrosive.png
Corrosive

Signal Words: Danger

Hazard Statements:
H226: Flammable liquid and vapor.
H302 + H312 + H332: Harmful if swallowed, in contact with skin or if inhaled
H315 Causes skin irritation.
H318 Causes serious eye damage.

Precautionary Statements:
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/light/…/equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash contaminated parts thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P301+P310: IF SWALLOWED: Immediately call a POSION CENTER or doctor/physician.
P302+352: IF ON SKIN: Wash with plenty of soap and water.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P333+313: If skin irritation or a rash occurs: Get medical advice/attention.
P370+378: In case of fire: Use Water fog. Alcohol foam. Dry chemical. Polymer foam. Dry chemical powder. Carbon dioxide (CO2).  Do not use a solid water stream as it may scatter and spread fire.
P403+233+235: Store in a well-ventilated place. Keep container tightly closed. Keep cool.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/national regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
F Flammable
Xn Harmful
C Corrosive
Risk Phrases:
R10 Flammable.
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R38 Irritating to skin.
R41 Risk of serious damage to eyes.

3. Composition/Information on Ingredients

Product Name & Other Names: Cyclohexanone or Ketohexamethylene.
CAS No.: 108-94-1
EINECS EC Number: 203-631-1
FEMA Number: 3909
Molecular Formula: C6H10O
Molecular Weight: 98.14

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do not use mouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Get medical attention.
Ingestion: Rinse mouth. Do not induce vomiting without medical advice. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Never give anything by mouth to a victim who is unconscious or is having convulsions. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Use a mild soap if available. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. For minor skin contact, avoid spreading material on unaffected skin.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

5. Fire Fighting Measures

Flammability of the Product: Flammable. Containers may explode when heated.
Products of Combustion: Carbon oxides and fumes.
Fire Extinguishing Media: Water fog. Alcohol foam. Dry chemical. Polymer foam. Dry chemical powder. Carbon dioxide (CO2). Do not use a solid water stream as it may scatter and spread fire. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes.
Special Information: Fire may produce irritating, corrosive and/or toxic gases. In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.
Keep away from heat and sources of ignition. Flash back possible over considerable distance. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas.

6. Accidental Release Measures

Personal precautions: Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering. Keep out of low areas.
Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not contaminate water.
Methods for containment: Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Vapors can accumulate in low areas.
Dike the spilled material, where this is possible. Prevent entry into waterways, sewers, basements, or confined areas.
Methods for cleaning up: Clean up in accordance with all applicable regulations. Should not be released into the environment.
Small Spill: Avoid dust/mist formation. Avoid breathing dust/mist. Ensure adequate ventilation. Wipe up with absorbent material (e.g., cloth, fleece). Clean contaminated surface thoroughly.
Large Spill: Dike far ahead of liquid spill for later disposal. Use a non-combustible material like vermiculite, sand, or earth to soak up the product and place into a container for later disposal.

7. Handling and Storage

Precautions for safe handling: Do not handle or store near an open flame, heat, or other sources of ignition. All equipment used when handling the product must be grounded. Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces. Avoid prolonged exposure.
Conditions for safe storage, including any incompatibilities: Keep away from heat and sources of ignition (spark or flame). Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like oxidizing agents.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: Exposure guidelines have not been established for this product. Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: Almost colorless liquid.
Odor: Pleasant odor.
Odor threshold: Not available.
pH: around 2.
Relative density: 0.95
Boiling  point: 155C literature.
Melting  point/Freezing  point: -47C literature.
Flash Point: 44C
Auto-ignition temperature: 420C.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility(ies): Miscible with water, alcohols, ethers, and chloroform.
Viscosity: Slightly soluble in water. Miscible with common organic solvents.
Molecular Formula: C6H10O
Molecular Weight: 98.14

10. Stability and Reactivity

Stability: It is stable under ordinary conditions of use and storage. Vapor/air-mixtures are explosive at intense warming.
Hazardous Decomposition Products: It emits toxic fumes when heated to decomposition.
Hazardous Polymerization: Polymerization is not reported.
Incompatibilities: Oxidizing agents.
Conditions to Avoid: Avoid heat, sparks, open flames, and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials.

11. Toxicological Information

Toxicity data:
LD50 Oral – Rat: 1620 mg/kg.
LD50 Dermal - Rabbit: 1,100 mg/kg.
LC50 Inhalation - Rat: > 6.2 mg/l; 4 h; vapor
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Teratogenic Effects: Not available.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

12. Ecological Information

Toxicity to fish: flow-through test LC50 - Pimephales promelas (fathead minnow) - 527 - 732 mg/l - 96 h.
Toxicity to daphnia and other aquatic invertebrates: static test EC50 - Daphnia magna (Water flea) - 800 mg/l - 24 h.
Persistence and Degradability: Unlikely to persist due to water solubility.
Mobility: Likely to be mobile due to water solubility.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state, and local requirements.

14. Transport Information

Department of Transportation DOT USA, TDG Canada & ADR RID Europe:
Proper shipping name: CYCLOHEXANONE.
Class: 3
UN number: 1915
Packing group: III
IMDG/IMO & IATA/ICAO:
Proper shipping name: CYCLOHEXANONE.
Class: 3
UN number: 1915
Packing group: III

15. Regulatory Information

USA:
SARA 302 Components
: Not subject to the reporting of SARA Title III, Section 302.
SARA 313 Components: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards: Fire Hazard, Acute Health Hazard
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

Section 16 - Additional Information

European/International Regulations European Labeling in Accordance with EC Directives
H226: Flammable liquid and vapor.
H302 + H312 + H332: Harmful if swallowed, in contact with skin or if inhaled
H315 Causes skin irritation.
H318 Causes serious eye damage.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
F Flammable
Xn Harmful
C Corrosive
Risk Phrases:
R10 Flammable.
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R38 Irritating to skin.
R41 Risk of serious damage to eyes.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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