Chromium picolinate USP & Pure Grade Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Chromium Picolinate, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Peru, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal etc.

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Chromium Picolinate: CAS Number: 14639-25-9, EINECS EC Number: ---, Molecular Formula: Cr(C6H4NO2)3, Molecular Weight: 418.33 HS Code ---**

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Chromium Picolinate.

Chromium (III) picolinate (CrPic3) is a pinkish-red compound sold as a nutritional supplement to treat type 2 diabetes and promote weight loss. Small quantities of chromium are needed for glucose utilization by insulin in normal health, but deficiency is extremely rare and has only been observed in hospital patients on long-term defined diets.

Chromium Picolinate USP Grade
C18H12N3O6Cr -- 418.31
Chromium Tripicolinate.
Chromium Picolinate contains not less than 98.0 percent and not more than 102.0 percent of C18H12N3O6Cr, calculated on the dried basis.
Packaging and storage: Preserve in tight containers.

Identification—
A: Infrared Absorption.
B: To 5 mL of a solution (1 in 250) in a test tube add 1 mL of 5 N sodium hydroxide and 10 drops of 30% hydrogen peroxide, and heat gently for about 2 minutes: a yellow color develops.
Loss on drying: Dry it at 105C for 4 hours: it loses not more than 4.0% of its weight.
Chloride: Dissolve 30 mg of Chromium Picolinate in 30 to 40 mL of water, and heat to 70C. Cool overnight, and filter to remove the precipitate. Add 1 mL each of nitric acid and silver nitrate TS, and add sufficient water to make 50 mL. Mix, and allow to stand for 5 minutes, protected from direct sunlight: any turbidity formed is not greater than that produced in a similarly treated control solution containing 0.25 mL of 0.002 N hydrochloric acid (0.06%).
Sulfate: Dissolve 100 mg of Chromium Picolinate in 30 to 40 mL of water, and heat to 90C. Cool overnight, and filter to remove the precipitate. Add 1 mL of 3 N hydrochloric acid, 3 mL of barium chloride, and sufficient water to make 50 mL. Mix, and allow to stand for 10 minutes: any turbidity formed is not greater than that produced in a similarly treated control solution containing 0.2 mL of 0.02 N sulfuric acid (0.2%).

Assay—
Standard stock solution: Transfer about 0.283 g of potassium dichromate, previously dried at 120C for 4 hours and accurately weighed, to a 1000-mL volumetric flask, dissolve in and dilute with water to volume to obtain a solution having a known concentration of about 100 µg of chromium per mL, and mix. Store in a polyethylene bottle.
Standard preparations: Separately transfer 1.0 mL and 2.0 mL of the Standard stock solution to 100-mL volumetric flasks, and transfer 1.5 mL and 2.0 mL of the Standard stock solution to separate 50-mL volumetric flasks. Add 1.0 mL of nitric acid to each flask, dilute the contents of each flask with water to volume, and mix. These Standard preparations contain 1.0, 2.0, 3.0, and 4.0 µg of chromium per mL, respectively.
Assay preparation: Transfer about 200 mg of Chromium Picolinate, accurately weighed, to a 500-mL volumetric flask, and add 25 mL of water. Slowly add 10 mL of nitric acid, and boil for 10 minutes with constant swirling. Cool the solution, dilute with water to volume, and mix. Filter a portion of the solution, and transfer 5 mL of the filtrate to a 100-mL volumetric flask. Add 1 mL of nitric acid, dilute with water to volume, and mix.
Procedure: Concomitantly determine the absorbances of the Standard preparations and the Assay preparation at the chromium emission wavelength of 357.9 nm, with a suitable atomic absorption spectrophotometer equipped with a chromium hollow-cathode lamp and an air–acetylene flame, using diluted nitric acid as the blank. Plot the absorbances of the Standard preparations versus chromium concentration, in µg per mL, and draw the straight line best fitting the four plotted points. From the graph so obtained, determine the chromium concentration, in µg per mL, in the Assay preparation. Calculate the quantity, in mg, of C18H12N3O6Cr in the portion of Chromium Picolinate taken by the formula:
(418.31 / 51.996)(10C)
in which C is the concentration, in µg per mL, of chromium in the Assay preparation; 418.31 is the molecular weight of chromium picolinate; and 51.996 is the atomic weight of chromium.

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Chromium Picolinate GHS SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 10-Oct-20

Product Name & Other Names: Chromium Picolinate or Chromium Tripicolinate.
CAS No.: 14639-25-9
EINICS EC-No.: --
Molecular Weight: 418.33
Chemical Formula: Cr(C6H4NO2)3
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Skin corrosion/irritation Category 2, H315
Serious eye damage/eye irritation Category 2A, H319
Specific target organ toxicity, single exposure; Respiratory tract irritation Category 3, H335

Hazard statements:
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.

Precautionary statements:
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash skin thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P362: Take off contaminated clothing and wash before reuse.
P302+ P352 - IF ON SKIN: Wash with plenty of soap and water.
P332+313: If skin irritation occurs: Get medical advice/attention.
P305+ P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P501: Dispose of contents/container to authorized agents only.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xi Irritant
Risk Phrases:
R36/37/38 = Irritating to eyes, respiratory system, and skin.

Product Name & Other Names: Chromium Picolinate or Chromium Tripicolinate.
CAS No.: 14639-25-9
Percent: 100%

Inhalation: If Chromium Picolinate is inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen and get medical attention immediately.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing and shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Fire: Not a fire hazard.
Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill: Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law. Eliminate all ignition sources.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, reducing agents, acids, and bases.

Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Chromium Picolinate is dark violet crystals or powder.
Odor: Not available.
Odor threshold: Not available.
pH: Not available.
Relative density: Not available.
Melting point/freezing point: > 300C literature
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Very slightly soluble in water.
Viscosity: Not available.
Molecular Weight: 418.33
Chemical Formula: Cr(C6H4NO2)3

Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Carbon dioxide and monoxide, Nitrogen oxides, Chromium oxide may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Excessive heat, strong oxidizers & reducing agents, acids and bases.
Conditions to Avoid: Heat, dusting and incompatibles.

LD50 Skin-Rabbit-450mg/kg
LD50 Oral-Rat-3250mg/kg
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Teratogenic Effects: Not available.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

Toxicity
Toxicity to fish: No information available.
Persistence and Degradability: No information available.
Mobility: No information available.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused Chromium Picolinate in accordance with legal requirements.

DOT USA: Not regulated
TDG Canada: Not regulated
IATA: Not regulated
IMDG/IMO: Not regulated
ADR/RID Europe: Not regulated.

USA:
SARA 313: Not applicable
OSHA: Hazardous by the definition of Hazard Communication Standard (29 CFR 1910.1200).
California Proposition 65: This product does not contain any Proposition 65 chemicals.

European Labeling in Accordance with EC Directives:
H315 = Causes skin irritation.
H319 = Causes serious eye irritation.
H335 =May cause respiratory irritation.

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

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