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Heavy Bismuth Subnitrate BP USP Grade Manufacturers, SDS GHS MSDS Sheet

Heavy Bismuth Subnitrate: CAS Number: 1304-85-4, EINECS EC Number: 215-136-8, Molecular Formula: Bi5O(OH)9(NO3)4 , Molecular Weight: 1461.99, HS Code ---**

For SDS MSDS Sheet Click
SDS MSDS Sheet of Heavy Bismuth Subnitrate Manufacturers

Heavy Bismuth Subnitrate
Pure BP USP Grade
Heavy bismuth subnitrate

Heavy Bismuth Subnitrate BP
Ph Eur
4[BiNO3(OH)2],BiO(OH) -- 1462 -- 1304-85-4

DEFINITION
Content: 71.0 per cent to 74.0 per cent of Bi (Ar 209.0) (dried substance).

CHARACTERS
Appearance: White or almost white powder.
Solubility: Practically insoluble in water and in ethanol (96 per cent). It dissolves in mineral acids with decomposition.

IDENTIFICATION
A. Dilute 1 ml of solution S1 (see Tests) to 5 ml with water and add 0.3 ml of potassium iodide solution. A black precipitate is formed which dissolves into an orange solution with the addition of 2 ml of potassium iodide solution.
B. It gives reaction (b) of bismuth.
C. It gives the reaction of nitrates.
D. pH: maximum 2.0 for solution S2 (see Tests).

TESTS
Solution S1: Shake 5.0 g by gently heating in 10 ml of water and add 20 ml of nitric acid. Heat until dissolution, cool and dilute to 100 ml with water.
Solution S2: Place 1.00 g in a 20 ml volumetric flask and add 2.0 ml of lead-free nitric acid. Allow acid attack to take place without heating and if necessary warm slightly at the end to completely dissolve the test sample. Add 10 ml of water, shake and add, in small fractions, 4.5 ml of lead-free ammonia; shake and allow to cool. Dilute to 20.0 ml with water, shake again is required to change the colour of the indicator to pink.
Chlorides: Maximum 200 ppm.
Copper: Maximum 50.0 ppm.
Lead: Maximum 20.0 ppm.
Silver: Maximum 25.0 ppm.
Substances not precipitated by ammonia: Maximum 1.0 per cent.
To 20 ml of solution S1, add concentrated ammonia until an alkaline reaction is produced and filter. Wash the residue with water and evaporate the combined filtrate and washings to dryness on a water-bath. To the residue, add 0.3 ml of dilute sulphuric acid R and ignite.
The residue weighs a maximum of 10 mg.
Loss on drying: Maximum 3.0 per cent, determined on 1.000 g by drying in an oven at 105C.
ASSAY: Dissolve with heating 0.250 g in 10 ml of a mixture of 2 volumes of perchloric acid and 5 volumes of water. To the hot solution, add 200 ml of water and 50 mg of xylenol orange triturate. Titrate with 0.1 M sodium edetate until a yellow colour is obtained.
1 ml of 0.1 M sodium edetate is equivalent to 20.90 mg of Bi.


Bismuth Subnitrate USP
Bi5O(OH)9(NO3)4 1461.99
Bismuth hydroxide nitrate oxide Bi5O(OH)9(NO3)4 [1304-85-4].
Bismuth Subnitrate is a basic salt that contains the equivalent of not less than 79.0 percent of bismuth trioxide (Bi2O3), calculated on the dried basis.

Packaging and storage: Preserve in well-closed containers.

Identification: It responds to the tests for Bismuth and for Nitrate.
Loss on drying: Dry it at 105 for 2 hours: it loses not more than 3.0% of its weight.
Carbonate: Add 3 g to 3 mL of warm nitric acid: no effervescence occurs. Pour the solution into 100 mL of water: a white precipitate forms. Filter, evaporate the filtrate on a steam bath to 30 mL, again filter the liquid, divide the latter filtrate into portions of 5 mL each, and use these several portions in the tests for Chloride, Sulfate, Copper, Lead, and Silver.
Chloride: A 10-mL portion of the test liquid retained in the test for Carbonate shows no more chloride than corresponds to 0.50 mL of 0.020 N hydrochloric acid (0.035%).
Sulfate: To a 5-mL portion of the test liquid retained in the test for Carbonate add 5 drops of barium nitrate: no turbidity is produced immediately.
Limit of ammonium salts: Boil about 100 mg with 5 mL of 1 N sodium hydroxide: the vapor does not turn moistened red litmus paper blue.
Arsenic, Method: Mix 375 mg with 5 mL of water, cautiously add 2 mL of sulfuric acid, and heat the mixture until fumes of sulfur trioxide are copiously evolved. Cool, cautiously add 10 mL of water, and again evaporate to strong fuming, repeating, if necessary, to remove any trace of nitric acid. The limit is 8 ppm.
Copper: To a 5-mL portion of the test liquid retained in the test for Carbonate add a slight excess of 6 N ammonium hydroxide: the liquid does not exhibit a bluish color.
Lead: Mix a 5-mL portion of the test liquid retained in the test for Carbonate with an equal volume of 2 N sulfuric acid: the liquid does not become cloudy.
Silver: To a 5-mL portion of the test liquid retained in the test for Carbonate add hydrochloric acid, dropwise: no precipitate is formed that is insoluble in a slight excess of hydrochloric acid, but that is soluble in 6 N ammonium hydroxide.
Limit of alkalies and alkaline earths: Boil 1.0 g with 20 mL of a mixture of equal volumes of 6 N acetic acid and water, cool, and filter. Add 2 mL of 3 N hydrochloric acid, precipitate the bismuth by the addition of hydrogen sulfide, boil the mixture, and filter it. Add 5 drops of sulfuric acid to the filtrate, evaporate to dryness, and ignite to constant weight: the weight of the residue does not exceed 5 mg (0.5%).
Assay: Transfer about 400 mg of Bismuth Subnitrate, accurately weighed, to a 250-mL beaker. Add 5 mL of water, then add 2 mL of nitric acid, and warm, if necessary, to effect solution. Dilute with water to 100 mL, add 0.3 mL of xylenol orange and titrate with 0.05 M edetate disodium VS to a yellow endpoint. Each mL of 0.05 M edetate disodium is equivalent to 11.65 mg of Bi2O3.

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Last : 11 April, 2017

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Heavy Bismuth Subnitrate SDS MSDS Sheet, Material Safety Data Sheet

1. Product Identification

Synonyms: Bismuth(III) nitrate basic, Bismuthyl nitrate, Bismuth(III) oxynitrate, Bismuth(III) subnitrate
CAS No.: 1304-85-4
EINECS EC Number: 215-136-8
Molecular Weight: 1461.99
Chemical Formula: Bi5O(OH)9(NO3)4
Recommended usage: Industrial Manufacturing.
Suppliers: As per letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Oxidizing solids Category 3
Hazardous to the aquatic environment, acute hazard Category 3
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2A
Specific target organ toxicity - single exposure Category 3, Respiratory system
Hazardous to the aquatic environment, acute hazard Category 3

Labeling according GHS & Regulation (EC) No 1272/2008

GHS Label Elements
Oxidizing solid
Oxidizing Solid

GHS Label Elements
Irritant
Irritant

Signal Word: Warning

Hazard Statements:
H272: May intensify fire; oxidizer.
H315 : Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H402: Harmful to aquatic life.

Precautionary Statements
P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P220: Keep/Store away from clothing/other combustible materials.
P221: Take any precaution to avoid mixing with combustibles.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash ... thoroughly after handling.
P273: Avoid release to the environment.
P280-Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P337+313: If eye irritation persists get medical advice/attention.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P370+378: In case of fire: Use Dry chemical, carbon dioxide, Halon, water spray, or fog for extinction.. If water is used, apply from as far a distance as possible.
P362: Take off contaminated clothing and wash before reuse.
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
O Oxidising
Xi Irritant
R8 Contact with combustible material may cause fire
R36/37/38 Irritating to eyes, respiratory system and skin
For the full text of the S-statement & R-phrases mentioned in this Section, see Section 16.

3. Composition/Information on Ingredients

Ingredient: Heavy Bismuth Subnitrate
CAS No.: 1304-85-4
EINECS EC Number: 215-136-8
Percent: 99 - 100%

4. First Aid Measures

Inhalation: If Heavy Bismuth Subnitrate is inhaled, remove to fresh air. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention.

5. Fire Fighting Measures

Fire: Heavy Bismuth Subnitrate is not combustible, but substance is a strong oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition.
Explosion: Some nitrates may explode when shocked, exposed to heat or flame, or by spontaneous chemical reaction. Sealed containers may rupture when heated. Sensitive to mechanical impact.
Fire Extinguishing Media: Dry chemical, carbon dioxide, Halon, water spray, or fog. If water is used, apply from as far a distance as possible. Water spray may be used to keep fire exposed containers cool. Do not allow water runoff to enter sewers or waterways.
Special Information: Wear full protective clothing and breathing equipment for high-intensity fire or potential explosion conditions. This oxidizing material can increase the flammability of adjacent combustible materials.

6. Accidental Release Measures

Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill:
Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal.

7. Handling and Storage

Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage and moisture. Isolate from any source of heat or ignition. Avoid storage on wood floors. Separate from incompatibles, combustibles, organic or other readily oxidizable materials. Containers of may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.
Keep away from sources of ignition - No smoking.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.

9. Physical and Chemical Properties

Appearance: Solid.
Odor: Odorless.
Solubility: Insoluble in water
Specific Gravity: 4.93
pH: NA
% Volatiles by volume @ 21C (70F): 0
Boiling Point: NA
Melting Point: 500C
Vapor Density (Air=1): NA
Vapor Pressure (mm Hg): Negligible @ 20C

10. Stability and Reactivity

Stability: Heavy Bismuth Subnitrate is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Oxides of bismuth and nitrogen and toxic metal fumes may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Alkaline bicarbonates, soluble iodides, gallic acid, calomel, tannins, salicylic acid.
Conditions to Avoid: Heat, flames, ignition sources and incompatibles.

11. Toxicological Information

Oral rat LD50: Not available.
This product is not classifiable as to its carcinogenicity based on its IARC, ACGIH, NTP, or EPA classification.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.

12. Ecological Information

Ecology - water: Not available.
Bioaccumulative potential: No data available

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. Dispose of container and unused contents in accordance legal requirements.

14. Transport Information

Domestic (Land, D.O.T.)
Proper Shipping Name: Nitrates, inorganic, n.o.s.
Hazard Class: 5.1
UN/NA: UN1477
Packing Group: II
International (Water, I.M.O.)
Proper Shipping Name: Nitrates, inorganic, n.o.s.
Hazard Class: 5.1
UN/NA: UN1477
Packing Group: II
International (Air, I.C.A.O.)
Proper Shipping Name: Nitrates, inorganic, n.o.s.
Hazard Class: 5.1
UN/NA: UN1477
Packing Group: II

15. Regulatory Information

USA:
TSCA
: Yes
SARA 302: No
SARA 313: No
SARA 311/312: Acute: No; Chronic: No; Fire; Yes; Pressure: No; Reactivity: No  (Pure / Solid)
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
TSCA 8(b) inventory: No
TSCA 12(b): No
Canada WHMIS: CLASS C: Oxidizing material.

Section 16 - Additional Information

EINECS EC Number: 231-818-8
H272 = May intensify fire; oxidizer.
H315 = Causes skin irritation.
H319 = Causes serious eye irritation.
H335 = May cause respiratory irritation.
H402 = Harmful to aquatic life.
O Oxidising
Xi Irritant
R8 Contact with combustible material may cause fire
R36/37/38 Irritating to eyes, respiratory system and skin

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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