Zinc Undecenoate or Zinc Undecylenate BP Ph Eur EP USP IP and Pure Grade Manufacturers, SDS GHS MSDS Sheet
Supplier, Manufacturer, Exporter of Zinc Undecenoate or Zinc Undecylenate BP Ph Eur EP USP IP and Pure Grade, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.
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Zinc Undecenoate Undecylenate: CAS Number: 557-08-4, EINECS EC Number: 209-155-0, Molecular Formula: C22H38O4Zn, Molecular Weight: 431.92, HS Code ---**
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SDS MSDS Sheet of Zinc Undecenoate ManufacturersZinc Undecenoate
Zinc Undecylenate Pure BP Ph Eur EP IP USP Grade Suppliers
Zinc Undecylenate is a fungistatic fatty acid, antifungal. Zinc Undecylenate is used topically in creams against fungal infections, eczemas, ringworm, and other cutaneous conditions.
Zinc Undecenoate BP Ph Eur Grade Specifications
Ph Eur
C22H38O4Zn -- 431.9 -- 557-08-4
Action and use: Used topically in treatment of fungal infections.DEFINITION
Zinc di(undec-10-enoate).
Content: 98.0 per cent to 102.0 per cent (dried substance).CHARACTERS
Appearance: White or almost white, fine powder.
Solubility: Practically insoluble in water and in ethanol (96 per cent).
mp: 116C to 121C, it may leave a slight solid residue.IDENTIFICATION
A. To 2.5 g add 10 ml of water and 10 ml of dilute sulphuric acid. Shake with 2 quantities, each of 10 ml, of ether. Reserve the aqueous layer for identification test C. Wash the combined ether layers with water and evaporate to dryness. To the residue add 2 ml of freshly distilled aniline and boil under a reflux condenser for 10 min. Allow to cool and add 30 ml of ether. Shake with 3 quantities, each of 20 ml, of dilute hydrochloric acid and then with 20 ml of water. Evaporate the organic layer to dryness on a water-bath.
The residue, after recrystallisation twice from ethanol (70 per cent V/V) R and drying in vacuo for 3 h, melts at 66C to 68C.
B. Dissolve 0.1 g in a mixture of 2 ml of dilute sulphuric acid and 5 ml of glacial acetic acid. Add drop-wise 0.25 ml of potassium permanganate solution. The colour of the potassium permanganate solution is discharged.
C. A mixture of 1 ml of the aqueous layer obtained in identification test A and 4 ml of water gives the reaction of zinc.TESTS
Alkalinity: Mix 1.0 g with 5 ml of ethanol (96 per cent) and 0.5 ml of phenol red solution. Add 50 ml of carbon dioxide-free water and examine immediately. No reddish colour appears.
Alkali and alkaline-earth metals: Maximum 2.0 per cent.
To 1.0 g add 25 ml of water and 5 ml of hydrochloric acid and heat to boiling. Filter whilst hot. Wash the filter and the residue with 25 ml of hot water. Combine the filtrate and washings and add concentrated ammonia until alkaline. Add 7.5 ml of thioacetamide solution and heat on a water-bath for 30 min. Filter and wash the precipitate with 2 quantities, each of 10 ml, of water. Combine the filtrate and washings, evaporate to dryness on a water-bath and ignite. The residue weighs a maximum of 20 mg.
Sulphates: Maximum 500 ppm.
Loss on drying: Maximum 1.5 per cent, determined on 0.500 g by drying in an oven at 105C.
Degree of un-saturation: Dissolve 0.100 g in a mixture of 5 ml of dilute hydrochloric acid R and 30 ml of glacial acetic acid. Using 0.05 ml indigo carmine solution, added towards the end of the titration as indicator. Titrate with 0.0167 M bromide-bromate until the colour changes from blue to yellow.
9.1 ml to 9.4 ml of 0.0167 M bromide-bromate is required. Carry out a blank titration.ASSAY
To 0.350 g add 25 ml of dilute acetic acid and heat to boiling. Carry out the complexometric titration of zinc.
1 ml of 0.1 M sodium edetate is equivalent to 43.19 mg of C22H38O4Zn.STORAGE
Protected from light.Zinc Undecylenate USP Grade Specifications
C22H38O4Zn 431.92
10-Undecenoic acid, zinc(2+) salt.
Zinc 10-undecenoate CAS 557-08-4Zinc Undecylenate contains not less than 98.0 percent and not more than 102.0 percent of C22H38O4Zn, calculated on the dried basis.
Identification—
A: Acidify about 5 g with 25 mL of 2 N sulfuric acid, add 20 mL of water, and extract in a separator with two 25-mL portions of ether. Evaporate the ether solution until the odor of ether no longer is perceptible. Add potassium permanganate drop-wise to a 1-mL portion of this residue: the permanganate color is discharged.
B: A 3-mL portion of the residue of undecylenic acid obtained in Identification test A responds to Identification test B under Undecylenic Acid.
C: Dissolve about 100 mg in a mixture of 10 mL of water and 1 mL of ammonium hydroxide, and add a few drops of sodium sulfide: a white, flocculent precipitate of zinc sulfide is formed.Loss on drying: Dry it at 105 for 2 hours: it loses not more than 1.25% of its weight.
Alkalies and alkaline earths: Boil 1.50 g with a mixture of 50 mL of water and 10 mL of hydrochloric acid, filter while hot, and wash the separated acid with about 50 mL of hot water. Render the combined filtrate and washings alkaline with 6 N ammonium hydroxide, add ammonium sulfide to precipitate the zinc completely, dilute with water to 200 mL, mix, and filter. To 100 mL of the clear filtrate add 0.5 mL of sulfuric acid, evaporate to dryness, and ignite over a low flame to constant weight: the weight of the residue does not exceed 7.5 mg (1.0%).Assay—
Zinc Undecenoate IP EP Grade
Boil 50.0 mL of 0.1 N sulfuric acid with about 1 g of Zinc Undecylenate, accurately weighed, for 10 minutes, or until the undecylenic acid layer is clear, adding water, as necessary, to maintain the original volume. Cool, and transfer the mixture, with the aid of water, to a 500-mL separator. Dilute with water to about 250 mL, and extract with two 100-mL portions of solvent hexane. Wash the combined extracts with water until the last washing is neutral to litmus, add the washings to the original water layer, and evaporate on a steam bath to about 100 mL. Cool, add 3 drops of methyl orange, and titrate the excess sulfuric acid with 0.1 N sodium hydroxide. Perform a blank determination. Each mL of 0.1 N sulfuric acid is equivalent to 21.60 mg of C22H38O4Zn.
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Zinc Undecenoate or Zinc Undecylenate SDS GHS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 24-Nov-20Section 1: Chemical Product and Company Identification
Product Name & Other Names: Zinc Undecenoate or Zinc Undecylenate.
CAS Number: 557-08-4
EINECS EC Code: 209-155-0
Chemical Formula: C22H38O4Zn
Molecular Weight: 431.92
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.Section 2: Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.Labeling according GHS & Regulation (EC) No 1272/2008
GHS Label Elements
NONESignal Word: None
Hazards not otherwise classified (HNOC):
Can be slightly harmful if swallowed.
May causes mild skin irritation.
May causes mild eye irritation.Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P270: Do not eat, drink or smoke when using this product.
P281: Use personal protective equipment as required.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.Section 3: Composition and Information on Ingredients
Product Name & Other Names: Zinc Undecenoate or Zinc Undecylenate.
CAS Number: 557-08-4
EINECS EC Code: 209-155-0Section 4: First Aid Measures
Always seek medical advice after the first aid treatment.
Skin: Rinse with water. Soap may be used. Seek Medical Aid.
Eyes: Wash eyes with plenty of water for at least 15 minutes, lifting lids occasionally. Seek Medical Aid.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Ingestion: If swallowed, induce vomiting immediately after giving two glasses of water. Never give anything by mouth to an unconscious person.
Notes to Physician: Treat symptomatically.Section 5: Fire and Explosion Data
Flammability of the Product: Non-flammable in ordinary handling. May be combustible at high temperature.
Flash Points: Not applicable.
Products of Combustion: Zinc oxide, Fumes and Oxides of carbon.
Fire Fighting Media and Instructions: Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.Section 6: Accidental Release Measures
Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to legal requirements.
Large Spill: Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.Section 7: Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents and acids.Section 8: Exposure Controls/Personal Protection
Exposure Limits:
USA OSHA --- OSHA PEL (TWA) (mg/m³) --- 15 mg/m³ nuisance dust.
Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume, or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.Section 9: Physical and Chemical Properties
Physical state and appearance: Solid white powder or granules.
Odor: Odorless.
Odor threshold: Not available.
pH: Not available.
Relative density: Not available.
Melting Point: 118 to 121C.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility(ies): Not available.
Viscosity: Not available.
Chemical Formula: C22H38O4Zn
Molecular Weight: 431.92Section 10: Stability and Reactivity Data
Stability: It is stable.
Conditions to Avoid: Heat, Flame, Sparks, other ignition sources and Incompatible materials
Incompatibility with various substances: Heat, light, strong oxidizing agents, acids.
Hazardous decomposition products: Carbon oxides & Zinc oxides are expected.
Polymerization: Will not occur.Section 11: Toxicological Information
Toxicity to Animals: Oral Rat LD50: 2500 mg/kg.
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Teratogenic Effects: Not available.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.Section 12: Ecological Information
Toxicity to fish: No information available.
Persistence and Degradability: No information available.
Mobility: No information available.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.Section 13: Disposal Considerations
Waste Disposal: Waste must be disposed of in accordance with federal, state, and local environmental control regulations.
Section 14: Transport Information
DOT USA, TDG Canada & ADR/RID Europe: Not dangerous goods.
IMDG/IMO: Not dangerous goods.
IATA/ICAO: Not dangerous goods.Section 15: Other Regulatory Information
USA Regulations:
Section 16 - Additional Information
SARA 313: Not applicable
SARA 311/312 Hazardous Categorization: None
California Proposition 65: This product does not contain any Proposition 65 chemicalsDISCLAIMER: The information and recommendations set forth herein are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.