Tolytriazole or Methyl-1H-benzotriazole or Tolutriazole Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Tolytriazole or Methyl-1H-benzotriazole, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Tolytriazole or Methyl-1H-benzotriazole or Tolutriazole: CAS Number: 29385-43-1, EINECS EC Number: 249-596-6, Molecular Formula: C7H7N3, Molecular Weight: 133.15, HS Code ---**

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Tolytriazole or Methyl-1H-benzotriazole or Tolutriazole.

Tolytriazole or Methyl-1H-benzotriazole or Tolutriazole and its related Na salts do belong to the most effective corrosion inhibitors for copper and copper alloys. It does further show positive effects in protection of steel, gray iron, cadmium and nickel. It is used in cooling water or boiler systems by the industrial water treatment industry. Tolyltriazole can be also used in coolants or antifreeze products. Another application is the use as an additive in industrial lubricants, like e.g. drilling and cutting fluids. It does also work to protect silver ware in dishwashing tablets and can be further used in metal detergents.

General Properties and Specifications of Tolytriazole or Methyl-1H-benzotriazole or Tolutriazole:
Appearance: White solid, granule or powder.
Chroma: 40 maximum.
Assay: 99.5% minimum.
pH: 5 to 6
Ash: 0.05% maximum.
Loss on drying: 0.1% maximum.
Relative density: around 1.13
Melting Point: 80C to 86C.
Boiling Point: 317C.
Solubility: Practically insoluble in water. Soluble in methanol.

MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
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Tolytriazole or Methyl-1H-benzotriazole or Tolutriazole SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 22-Nov-20

Product Name & Other Names: Tolytriazole or Methyl-1H-benzotriazole or Tolutriazole
CAS No.: 29385-43-1
EINECS EC Number: 249-596-6
Molecular Formula: C7H7N3
Molecular Weight: 133.15
Relevant uses and uses advised against (if any): Laboratory and Industrial Use.
Supplier: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, oral (Category 4) H302
Acute toxicity, dermal (Category 4) H312
Serious eye damage/eye irritation (Category 2A) H319
Acute toxicity, Inhalation (Category 4) H332
Long-term (chronic) aquatic hazard (Category 3) H412

Hazard Statements:
H302+H312+H332: Harmful if swallowed, in contact with skin or if inhaled.
H319: Causes serious eye irritation.
H412: Harmful to aquatic life with long lasting effects.

Precautionary Statements:
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash contaminated parts thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340+P312: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P403+233+235: Store in a well-ventilated place. Keep container tightly closed. Keep cool.
P391: Collect spillage.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/national regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
Xi Irritant.
Xn Harmful.
Risk Phrase:
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R36 Irritating to eyes.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Product Name & Other Names: Tolytriazole or Methyl-1H-benzotriazole or Tolutriazole
CAS No.: 29385-43-1
EINECS EC Number: 249-596-6

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do not use mouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Get medical attention.
Ingestion: Rinse mouth. Do not induce vomiting without medical advice. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Never give anything by mouth to a victim who is unconscious or is having convulsions. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Use a mild soap if available. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. For minor skin contact, avoid spreading material on unaffected skin.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Products of Combustion: Carbon oxides, Nitrogen oxides, and Fumes.
Fire Extinguishing Media: Water spray. Alcohol foam. Polymer foam. Dry chemical powder. Carbon dioxide (CO2). Avoid a solid water stream as it may scatter and spread fire. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.Dust/air mixtures may ignite or explode.

Personal precautions: Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering. Keep out of low areas.
Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not contaminate water.
Methods for cleaning up: Clean up in accordance with all applicable regulations. Should not be released into the environment.
Small Spill: Avoid dust/mist formation. Avoid breathing dust/mist/gas. Ensure adequate ventilation. Wipe up with absorbent material (e.g. cloth, fleece). Clean contaminated surface thoroughly.
Large Spill: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep up and remove to an approved disposal container.

Precautions for safe handling: Keep away from sources of ignition - No smoking. Take measures to prevent the build-up of electrostatic charge. Do not handle or store near an open flame, heat or other sources of ignition. All equipment used when handling the product must be grounded. Use only under a chemical fume hood. Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid contact with skin, eyes and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Prevent any contact with hot surfaces. Avoid prolonged exposure. Do not empty into drains. Avoid release to the environment.
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, alkalis, amines, nitrites, and sulfites.

Airborne Exposure Limits: Contains no substances with occupational exposure limit values.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice.

Appearance: White solid, granule or powder.
Odor: Not available.
Odor threshold: Not available.
pH: 5 to 6
Relative density: around 1.13
Boiling point: 317C.
Melting point/Freezing point: 80C to 86C.
Flash Point: Not available
Auto-ignition Temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Practically insoluble in water. Soluble in methanol.
Viscosity: Not available.
Molecular Formula: C7H7N3
Molecular Weight: 133.15

Stability: It is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits Carbon oxides, Nitrogen oxides, and Fumes when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: strong oxidizing agents, alkalis, amines, nitrites, and sulfites.
Conditions to Avoid: Avoid light, heat, sparks, open flames and other ignition sources. Contact with incompatible materials.

Toxicity data:
LD50 Oral - Rat: 675 mg/kg.
LC50 Inhalation - Rat: >1.73 mg/L 1 Hour.
LD50 Dermal - Rabbit: >4000 mg/kg.
Carcinogenicity: Not expected to be hazardous by IARC, NTP, ACGIH and OSHA criteria.
Mutagenic Effects: No information available.
Reproductive Effects: No information available.
Developmental Effects: No information available.
Teratogenicity: No information available.

Toxicity to fish: LC50: approx. 64 mg/l Exposure time: 96 h Species: Zebra barbell (Danio rerio).
Persistence and degradability: Not available.
Mobility in soil: Not available.
Results of PBT and vPvB assessment: Not available.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with law.

DOT USA, TDG Canada & ADR/RID Europe: Not regulated.
IMDG/IMO & IATA/ICAO: Not regulated.

USA:
SARA 302 Components: Not subject to the reporting requirements of SARA 302.
SARA 313 Components: Does not contain any chemical components that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards: Acute Health Hazard. See section 2.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

European Labeling in Accordance with EC Directives:
H302+H312+H332: Harmful if swallowed, in contact with skin or if inhaled.
H319: Causes serious eye irritation.
H412: Harmful to aquatic life with long lasting effects.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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