1,2,3-Benzotriazole or 1H-Benzotriazole Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of 1,2,3-Benzotriazole or 1H-Benzotriazole, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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1,2,3-Benzotriazole or 1H-Benzotriazole: CAS Number: 95-14-7, EINECS EC Number: 202-394-1, Molecular Formula: C6H5N3, Molecular Weight: 119.12, HS Code ---**

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for 1,2,3-Benzotriazole or 1H-Benzotriazole.

1,2,3 Benzotriazole or 1H-Benzotriazole is a hetrocyclic compound containing three nitrogen atoms, with the chemical formula C6H5N3. This aromatic compound is colorless and polar and can be used in various fields. Benzotriazole is a complexing agent and as such is a useful a corrosion inhibitor, e.g. for silver protection in dishwashing detergents and an anti-fog agent in photographic development. It is used in aircraft deicer and anti-ice fluid. Benzotriazole derivatives are found in pharmaceuticals such as antifungal, antibacterial, and anthelmintic drugs.

General Properties and Specifications of 1, 2, 3-Benzotriazole or 1H-Benzotriazole:
CAS Number: 95-14-7
Appearance: White needle like powder.
Assay: 99.8%
pH: around 5.7
Water: 0.05% maximum.
Residue on ignition: 0.05% maximum.
Relative density: 1.36
Melting point: 98C.
Boiling point: 350C, will ignite in ambient condition.
Flash point: 170C.
Autoignition Temperature: 201C.
Solubility: Slightly soluble in water. Soluble in alcohol, benzene, toluene, chloroform and N,N-dimethylformamide.

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1,2,3-Benzotriazole or 1H-Benzotriazole SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 03-Oct-20

Product Name & Other Names: 1,2,3-Benzotriazole or 1H-Benzotriazole.
CAS No.: 95-14-7
EINECS EC Number: 202-394-1
Molecular Formula: C6H5N3
Molecular Weight: 119.12
Relevant uses and uses advised against (if any): Laboratory and Industrial Use.
Supplier: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, oral Category 4, H302
Acute toxicity, inhalation Category 4, H332
Skin corrosion/irritation Category 2, H315
Eye Damage/Irritation Category 2A, H319

Hazard Statements:
H302 + H332: Harmful if swallowed or if inhaled
H315: Causes skin irritation.
H319: Causes serious eye irritation.

Precautionary Statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P264: Wash contaminated parts thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P301+P310: IF SWALLOWED: Immediately call a POSION CENTER or doctor/physician.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P302+352: IF ON SKIN: Wash with plenty of soap and water.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/national regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
Xn = Harmful
Xi = Irritant.
Risk Phrases:
R20/22 Harmful by inhalation and if swallowed.
R36/38 Irritating to eyes and skin.

Product Name & Other Names: 1,2,3-Benzotriazole or 1H-Benzotriazole.
CAS No.: 95-14-7
EINECS EC Number: 202-394-1
Molecular Formula: C6H5N3

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do not use mouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Get medical attention.
Ingestion: Rinse mouth. Do not induce vomiting without medical advice. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Never give anything by mouth to a victim who is unconscious or is having convulsions. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Use a mild soap if available. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. For minor skin contact, avoid spreading material on unaffected skin.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Flash point: 170C.
Autoignition Temperature: 201C.
Products of Combustion: Carbon oxides, nitrogen oxides, hydrogen cyanide and fumes.
Fire Extinguishing Media: Water fog. Alcohol foam. Dry chemical. Polymer foam. Dry chemical powder. Carbon dioxide (CO2). Do not use a solid water stream as it may scatter and spread fire. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes.
Special Information: Fire may produce irritating, corrosive, and/or toxic gases. In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air on intense heating.

Personal precautions, protective equipment, and emergency procedures: Ventilate area of leak or spill. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Prevent entry into waterways, sewers, basements, or confined areas. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container.
Small Spill: Avoid dust/mist formation. Avoid breathing dust/mist. Ensure adequate ventilation. Wipe up with absorbent material (e.g. cloth, fleece). Clean contaminated surface thoroughly.
Large Spill: Use a non-combustible material like vermiculite, sand, or earth to cover up the product and place into a container for later disposal.

Precautions for safe handling: Do not handle or store near an open flame, heat, or other sources of ignition. Use only with adequate ventilation. Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces. Hygroscopic and sensitive to moisture.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents.

Airborne Exposure Limits: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. Use chemical fume hood designed for hazardous chemicals.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Physical state: White needle like crystals or powder.
Odor: Not available.
Odor threshold: Not available.
pH: around 5.7
Relative density: around 1.36
Boiling point: 350C, will ignite in ambient condition.
Melting point/Freezing point: 98C.
Flash point: 170C.
Auto-ignition temperature: 201C.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility (water): Slightly soluble in water. Soluble in alcohol, benzene, toluene, chloroform, and N,N-dimethylformamide.
Viscosity: Not available.
Molecular Formula: C6H5N3
Molecular Weight: 119.12

Stability: It is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits Carbon oxides, nitrogen oxides, hydrogen cyanide and toxic fumes when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents.
Conditions to Avoid: Avoid light, heat, sparks, open flames, and other ignition sources. Contact with incompatible materials.

Toxicity data:
LD50 Oral Rat: 560 mg/kg.
LD50 Dermal Rabbit: > 2,000 mg/kg
LC50 Inhalation Rat: 1.4 mg/l; 4 h ; dust/mist.
Carcinogenicity: Not expected to be hazardous by IARC, OSHA, NTP criteria.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

Toxicity to fish: LC50: = 39 mg/L, 96h (Oncorhynchus mykiss).
Persistence and degradability: Not available.
Bioaccumulative potential: Not available.
Mobility: Not available.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state, and local requirements.

Department of Transportation (DOT USA): Not dangerous goods.
ADR/RID Europe: Not dangerous goods
IATA and IMDG: Not dangerous goods.

USA:
SARA 302 Components: No subject to the reporting of SARA Title III, Section 302.
SARA 313 Components: Does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels of SARA Title III, Section 313.
SARA 311/312 Hazards: Acute Health Hazard. See section 2.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

European Labeling in Accordance with EC Directives:
H302 + H332: Harmful if swallowed or if inhaled
H315: Causes skin irritation.
H319: Causes serious eye irritation.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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