Propylene Glycol BP Ph Eur IP EP JP USP FCC Food Grade Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Propylene Glyco BP Ph Eur IP EP JP USP FCC Food Gradel, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Propylene Glycol: CAS Number: 57-55-6, EINECS EC Number: 200-338-0, Molecular Formula: CH3CH(OH)CH2OH , Molecular Weight: 76.09, FEMA Number 2940, HS Code ---**

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Propylene Glycol.

Propylene glycol, also called propane-1,2-diol, is a viscous colorless hygroscopic liquid which is nearly odorless with a faintly sweet taste. It is used in food processing as the E-number E1520. The freezing point of water is depressed when mixed with propylene. In general, glycols are non-corrosive, have very low volatility and very low toxicity. Propylene glycol is used as a humectant (E1520), solvent and preservative in food and for tobacco products. It is also one of the major ingredients used in electronic. Propylene glycol is also used in various edible items such as coffee-based drinks, liquid sweeteners, ice cream, whipped dairy products and soda.

Propylene Glycol BP Ph Eur Grade
Ph Eur C3H8O2 -- 76.1 -- CAS 57-55-6
Action and use: Excipient.

CHARACTERS
A viscous, clear, colourless, hygroscopic liquid, miscible with water and with ethanol (96 per cent).

IDENTIFICATION
A. It complies with the test for relative density.
B. It complies with the test for refractive index.
C. Boiling point: 184C to 189C.
D. To 0.5 ml add 5 ml of pyridine and 2 g of finely ground nitrobenzoyl chloride. Boil for 1 min and pour into 15 ml of cold water with shaking. Filter, wash the precipitate with 20 ml of a saturated solution of sodium hydrogen carbonate and then with water and dry. Dissolve in boiling ethanol (80 per cent V/V) and filter the hot solution. On cooling, crystals are formed which, after drying at 100-105C, melt at 121C to 128C.

TESTS
Appearance: It is clear and colourless.
Relative density: 1.035 to 1.040.
Refractive index: 1.431 to 1.433.
Acidity: To 10 ml add 40 ml of water R and 0.1 ml of bromothymol blue solution. The solution is greenish-yellow. Not more than 0.05 ml of 0.1 M sodium hydroxide is required to change the colour of the indicator to blue.
Oxidising substances: To 10 ml add 5 ml of water, 2 ml of potassium iodide solution and 2 ml of dilute sulphuric acid and allow to stand in a ground-glass-stoppered flask protected from light for 15 min. Titrate with 0.05 M sodium thiosulphate, using 1 ml of starch solution as indicator. Not more than 0.2 ml of 0.05 M sodium thiosulphate is required.
Reducing substances: To 1 ml add 1 ml of dilute ammonia and heat in a water-bath at 60C for 5 min. The solution is not yellow. Immediately add 0.15 ml of 0.1 M silver nitrate and allow to stand for 5 min. The solution does not change its appearance.
Heavy metals: 5 ppm m/V.
Water: Not more than 0.2 per cent, determined on 5.00 g by the semi-micro determination of water.
Sulphated ash: Heat 50 g until it burns and ignite. Allow to cool. Moisten the residue with sulphuric acid and ignite; repeat the operations. The residue weighs not more than 5 mg (0.01 per cent).

Propylene Glycol USP Grade Specifications
C3H8O2 76.09
1,2-Propanediol.
1,2-Propanediol [CAS 57-55-6].
Propylene Glycol contains not less than 99.5 percent of C3H8O2.

Identification: Infrared Absorption 1on undried specimen.
Specific gravity: between 1.035 and 1.037.
Acidity: Add 1 mL of phenolphthalein to 50 mL of water, then add 0.1 N sodium hydroxide until the solution remains pink for 30 seconds. Then add 10 mL of Propylene Glycol, accurately measured, and titrate with 0.10 N sodium hydroxide until the original pink color returns and remains for 30 seconds: not more than 0.20 mL of 0.10 N sodium hydroxide is required.
Water: not more than 0.2%.
Residue on ignition: Heat 50 g in a tared 100-mL shallow dish until it ignites, and allow it to burn without further application of heat in a place free from drafts. Cool, moisten the residue with 0.5 mL of sulfuric acid, and ignite to constant weight: the weight of the residue does not exceed 3.5 mg.
Chloride: A 1-mL portion shows no more chloride than corresponds to 0.10 mL of 0.020 N hydrochloric acid (0.007%).
Sulfate: A 5.0-mL portion shows no more sulfate than corresponds to 0.30 mL of 0.020 N sulfuric acid (0.006%).
Heavy metals: Mix 4.0 mL with water to make 25 mL: the limit is 5 ppm.

DESCRIPTION
Polypropylene Glycol occurs as a clear, colorless or practically colorless, viscous liquid. It is an addition polymer of propylene glycol and water represented by the formula HO(C3H6O)n- C3H6OH, in which n represents the average number of oxypropylene groups. It is soluble in water and in such organic solvents as aliphatic ketones and alcohols, but it is insoluble in ether and in most aliphatic hydrocarbons.
Function: Defoaming agent.

REQUIREMENTS
Lead:Not more than 1 mg/kg.
Nominal Molecular Weight: Not less than 90.0% and not more than 110.0% of the labeled value.
pH: Between 6.0 and 9.0.
Propylene Oxide: Not more than 0.02%.
Residue on Ignition: Not more than 0.01%.
Viscosity: Passes test.

For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.

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Propylene Glycol SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 15-Nov-20

Product Name & Other Names: Propylene Glycol or 1,2-Propanediol.
CAS Number: 57-55-6
EINECS EC Number: 200-338-0
Molecular Weight: 76.09
Molecular Formula: CH3CH(OH)CH2OH
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Supplier: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP)

Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.

Hazards not otherwise classified (HNOC):
May causes mild skin irritation.
May causes mild eye irritation, if exposed in large quantity.

Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.

Product Name & Other Names: Propylene Glycol or 1,2-Propanediol.
CAS Number: 57-55-6
EINECS EC Number: 200-338-0

Emergency and First Aid Procedures:
Eyes - Flush with water for at least 15 minutes, raising and lowering eyelids occasionally. Get medical attention if irritation persists.
Skin - Thoroughly wash exposed area for at least 15 minutes. Remove contaminated clothing. Launder contaminated clothing before reuse. Get medical attention if irritation persists.
Ingestion - If it is swallowed, if conscious, give plenty of water. Immediately call a physician. Never give anything by mouth to an unconscious person.
Inhalation - Remove to fresh air. Give oxygen if breathing is difficult; give artificial respiration if breathing has stopped. Get medical attention.

Extinguisher Media: Use media suitable to extinguish surrounding fire. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Flammable Limits in Air % by Volume: N/A
Special hazards arising from the substance or mixture: Carbon oxides and fumes.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep up and remove to an approved disposal container.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like acid chlorides, acid anhydrides, oxidizing agents, chloroformates, reducing agents.

Respiratory Protection (Specify Type): None needed under normal conditions of use with adequate ventilation. NIOSH approved equipment should be worn if PELs are exceeded.
Exposure Limits: This product does not contain any hazardous materials with occupational exposure limits established by the region-specific regulatory bodies.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance and Odor: Clear viscous liquid. Odor not defined.
Odor: Not available.
Odor threshold: Not available.
pH: Not available.
Relative density: 1.04
Melting Point: -60C
Boiling Point: 187C
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility(ies): Soluble in water.
Viscosity: Not available.
Molecular Weight: 76.09
Molecular Formula: CH3CH(OH)CH2OH

Stability: It is stable
Conditions to Avoid: Heat, Dust generation.
Incompatibility (Materials to Avoid): Acid chlorides, Acid anhydrides, Oxidizing agents, Chloroformates, Reducing agents.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, fumes.
Hazardous Polymerization: Will not occur.

Acute toxicity:
LD50 Oral - Rat - 20,000 mg/kg
LD50 Dermal - Rabbit - 20,800 mg/kg
LD50 Intramuscular - Rat - 14 g/kg
LD50 Intravenous - Dog - 26 g/kg
Carcinogenicity: This product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC, NTP, ACGIH & OSHA.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

Toxicity to fish: mortality NOEC - Pimephales promelas (fathead minnow) - 52,930 mg/l - 96 h.
Toxicity to daphnia and other aquatic invertebrates: mortality NOEC - Daphnia (water flea) - 13,020 mg/l -48 h
EC50 - Daphnia magna (Water flea) - > 10,000 mg/l - 48 h
Bioaccumulative potential: Does not bioaccumulate.
Mobility: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

Waste Disposal Methods: Dispose in accordance with all applicable Federal, State and Local regulations.

DOT USA, TDG Canada & ADR/RID Europe: Not regulated.
IMDG/IMO: Not regulated.
IATA: Not regulated.

USA:
SARA 302: Not subject to the reporting requirements of SARA Title III, Section 302.
SARA 313: Not listed
SARA 311/312 Hazards: No SARA Hazards
California Prop. 65 Components: Not listed.

DISCLAIMER: The information and recommendations set forth herein are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

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