Piperazine Anhydrous & Hydrate Hexahydrate Flakes Crystals Powder or Diethylenediamine or 1,4-Diazacyclohexane Manufacturers, with SDS GHS MSDS Sheet

Supplier, Manufacturer, Exporter of Piperazine Anhydrous and Hydrate, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc.

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Piperazine Anhydrous & Hydrate or Diethylenediamine or 1,4-Diazacyclohexane: CAS Number: 110-85-0 for anhydrous and 142-63-2 for hydrate, EINECS EC Number: 203-808-3, Molecular Formula: C4H10N2 anhydrous, Molecular Weight: 86.14 anhydrous, HS Code ---**

Specifications, Safety Data Sheet, Manufacturing process details, Wholesale retail buy sell prices, Uses etc available on line in these pages for Piperazine Anhydrous & Hydrate or Diethylenediamine or 1,4-Diazacyclohexane.

Piperazine is an organic compound that consists of a six-membered ring containing two nitrogen atoms at opposite positions in the ring.

General Properties and Specifications of Piperazine Anhydrous or Diethylenediamine or 1,4-Diazacyclohexane:
Appearance: White flakes or crystals.
Assay: 99.8% minimum.
Water: 0.1% maximum.
pH: around 12
Relative density: 1.1
Melting point: 109C-113C.
Boiling point: 146C.
Flash point: 66C.
Auto ignition temperature: 320C.
Solubility: Freely soluble in water.

Specifications of Piperazine USP NF Grade:
C4H10N2 --- 86.14 CAS 110-85-0.
Piperazine contains not less than 98.0 percent and not more than 101.0 percent of C4H10N2, calculated on the anhydrous basis.
Packaging and storage: Preserve in tight containers, protected from light.

USP Piperazine RS:
Color of solution: Dissolve 10.0 g in water, and dilute with water to 50.0 mL: the solution has no more color than a standard solution prepared by adding 2.0 mL of ferric chloride CS to water and diluting with water to 50.0 mL, when compared in matched color-comparison tubes.
Identification:
A: Infrared Absorption
B: In the test for Chromatographic purity, the principal spot in the chromatogram of Test solution 2, observed after spraying with the ninhydrin solutions, corresponds in R F value, color, and size to that in the chromatogram of Standard solution 1.
Melting range: between 109C and 113C.
Water Determination: not more than 2.0%.
Chromatographic purity:
To pass the test.
Assay: Weigh accurately about 150 mg of Piperazine, and dissolve in 75 mL of glacial acetic acid. Titrate potentiometrically with 0.1 N perchloric acid, using a silver-glass electrode system. As the endpoint is approached, warm the solution to 60C to 70C, then complete the titration. Perform a blank determination and make any necessary correction. Each mL of 0.1 N perchloric acid is equivalent to 4.307 mg of C4H10N2.

Specifications of Piperazine Hydrate BP Ph Eur Grade:
C4H10N2-6H20 --- 194.2 --- CAS 142-63-2
Action and use: Anthelminthic.

DEFINITION
Piperazine hexahydrate.
Content: 98.0 per cent to 101.0 per cent.

CHARACTERS
Appearance: Colourless, deliquescent crystals.
Solubility: Freely soluble in water and in ethanol (96 per cent).
Melting point: About 43C.

For Original Monographs of IP Indian Pharmacopoeia BP British Pharmacopoeia USP US Pharmacopoeia FCC Food Grade product, please check with the respective web-pages or books.

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Piperazine Anhydrous & Hydrate or Diethylenediamine or 1,4-Diazacyclohexane SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 13-Nov-20

Product Name & Other Names: Piperazine Anhydrous & Hydrate or Diethylenediamine or 1,4-Diazacyclohexane.
CAS No.: 110-85-0 for anhydrous and 142-63-2 for hydrate
EINECS EC Number: 203-808-3
Chemical Formula: C4H10N2 anhydrous
Molecular Weight: 86.14 anhydrous
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Flammable Solids Category 1, H228
Skin corrosion/irritation Category 1A, B, C H314
Respiratory sensitization Category 1, H334
Skin sensitization Category 1, H317
Reproductive toxicity Category 2, H361fd

Hazard statements:
H228 Flammable solid.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H361fd Suspected of damaging fertility. Suspected of damaging the unborn child.

Precautionary statements:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P220: Keep/Store away from clothing/…/combustible materials.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P362: Take off contaminated clothing and wash before reuse.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342+311: If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P308+313: IF exposed or concerned: Get medical advice/attention.
P391: Collect spillage.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/regional/national/international regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
C Corrosive
F Highly flammable
Xn Harmful.
Risk Phrases:
R10 flammable.
R34 Causes burns.
R41 Risk of serious damage to eyes.
R42 May cause sensitization by inhalation.
R43 May cause sensitization by skin contact.
R60 May impair fertility.
R61 May cause harm to the unborn child.

Product Name & Other Names: Piperazine Anhydrous & Hydrate or Diethylenediamine or 1,4-Diazacyclohexane.
CAS No.: 110-85-0 for anhydrous and 142-63-2 for hydrate
EINECS EC Number: 203-808-3

Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin: Immediately flush skin with plenty of water for at least 15 minutes. Remove and wash contaminated clothing and shoes before reuse. Get medical attention if irritation develops.
Eyes: Immediately flush eyes with plenty of water for 15 minutes, occasionally lifting upper and lower eyelids. Hold eyelids apart during irrigation. Get medical attention.
Inhalation: Remove person to fresh air. If breathing is difficult, give oxygen. If not breathing administer artificial respiration. Get medical attention.

Flash Point: N/A
Fire/Explosion: The product is flammable and oxidizer.
Extinguishing Medium: Water spray, alcohol-resistant foam, sand, dry chemical, or carbon dioxide. Use water spray to cool unopened containers.
Special hazards arising from the substance or mixture: Poisonous fume, carbon dioxide, carbon monoxide, nitrogen oxides (NOx).
Fire Fighting Instructions: Use suitable protective equipment for surrounding fire. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. In case of fire in the surroundings: Keep containers cool by spraying with water. Eliminate all ignition sources if safe to do so.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Personal precautions, protective equipment, and emergency procedures: Ventilate area of leak or spill. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container. Do not touch or walk through this product. Stop leak if safe to do so. Prevent entry into waterways, drains, confined areas. Prevent dust cloud. Use personal protective equipment. Keep people away from and upwind of spill/leak. Entry to non-involved personnel should be controlled around the leakage area by roping off, etc. Use spark-proof tools and explosion-proof equipment. Ensure all leaks are completely removed to prevent subsequent ignition.

Hazardous material. Hygroscopic.
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, Strong oxidizing agents, strong acids, acid anhydrides, acid chlorides. Protect against physical damage. Keep away from heat, sparks, and flame. Isolate from all combustibles and incompatible substances.

Exposure Limits: ACGIH TLV TWA: 0.03 ppm.
Engineering Controls: Use adequate exhaust ventilation to keep airborne concentrations below the allowable exposure limit.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: White flakes or crystals.
Odor: Not available.
Odor threshold: Not available.
pH: around 12.
Relative density: 1.1
Melting point/freezing point: 109C-113C.
Initial boiling point and boiling range: 146C.
Flash point: 66C.
Auto-ignition temperature: 320C.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility(ies): Freely soluble in water.
Viscosity: Not available.
Chemical Formula: C4H10N2 anhydrous
Molecular Weight: 86.14 anhydrous.

Chemical Stability: Stable under recommended temperatures and pressures.
Incompatibility (Materials to Avoid): Strong oxidizing agents, strong acids, acid anhydrides, acid chlorides.
Conditions to Avoid: Incompatible materials, direct sunlight, heat shock, friction.
Hazardous Decomposition Products: Poisonous fume, carbon dioxide, carbon monoxide, nitrogen oxides (NOx).
Hazardous Polymerization: Will not occur.

Toxicity to Animals: LD50 Oral: 2600 mg/kg (Rat). LD50 Dermal: 4 mL/kg (Rabbit)
Carcinogenicity: Not a reported carcinogen by any agency.
Teratogenicity: No information found
Reproductive Effects: Suspected of damaging fertility. Suspected of damaging the unborn child.
Mutagenicity: No information found
Neurotoxicity: No information found.

Toxicity to fish: LC50 - Poecilia reticulata (guppy) - > 1.800 mg/l - 96,0 h.
Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna (Water flea) - 21 mg/l - 48 h.
Persistence and Degradability: No information found.
Bioaccumulative potential: No information found.
Mobility in soil: No information found.
Results of PBT and vPvB assessment: No information found.
Environmental Precautions: DO NOT DISCHARGE into drains and rivers.

Dispose of in accordance with all applicable local, state, and federal regulations at an approved waste disposal facility.

DOT USA, TDG Canada & ADR/RID Europe:
UN number: 2579 Class: 8 Packing group: III
Proper shipping name: PIPERAZINE
IMDG/IMO
UN number: 2579 Class: 8 Packing group: III
Proper shipping name: PIPERAZINE
IATA:
UN number: 2579 Class: 8 Packing group: III
Proper shipping name: PIPERAZINE

USA:
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components: Listed.
SARA 311/312: Reactivity Hazard; Acute Health Hazard; Chronic Health Hazard.
California Prop.65: Listed.

European Labeling in Accordance with EC Directives:
H228 Flammable solid.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H361fd Suspected of damaging fertility. Suspected of damaging the unborn child.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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