Methyl Acetoacetate or 3-Oxobutanoic acid methyl ester or Acetoacetic acid methyl ester or MAA Manufacturers, with SDS GHS MSDS Sheet |
Supplier, Manufacturer, Exporter of Methyl Acetoacetate or 3-Oxobutanoic acid methyl ester, Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Mubychem Group has several manufacturing facilities spread across Western India and world wide contacts and toll manufacturers. We are exporting globally to countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Cameroon, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Dubai, Korea, Vietnam, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, Italy, Portugal, Bangladesh, etc. The products are offered as per required specifications and in correct shape and size in mm or meshs or microns as specified by the buyer. The participating units have one or more accreditations like FDA - cGMP and GLP approval, ISO-9001 Certified, "REACH" Registered, ISO-14001, ISO/IEC 17025, ISO-22000, FSSC 22000, ISO 45001, Kosher Certified, Halal Certified, HACCP, FSSAI. We offer Commercial Pure & IP BP EP Ph Eur USP NF JP FCC Food Grade Analytical Reagent Grades of Chemicals |
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Methyl Acetoacetate or 3-Oxobutanoic acid methyl ester or Acetoacetic acid methyl ester or MAA: CAS Number: 105-45-3, EINECS EC Number: 203-299-8, Molecular Formula: C5H8O3 or CH3COCH2COOCH3, Molecular Weight: 116.12, HS Code ---**
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SDS MSDS Sheet of Methyl Acetoacetate or 3-Oxobutanoic acid methyl ester or Acetoacetic acid methyl ester or MAA Manufacturers
Methyl Acetoacetate
3-Oxobutanoic acid methyl ester or Acetoacetic acid methyl ester or MAA Pure Suppliers
General Properties and Specifications of Methyl Acetoacetate or 3-Oxobutanoic acid methyl ester or Acetoacetic acid methyl ester or MAA:
Appearance: Colorless liquid.
Odor: Agreeable odor.
Assay: 99% minimum.
pH: around 4 for 863 g/l in water @ 20C.
Relative density: around 1.08
Melting point: -80C literature.
Boiling point: 169C to 171C literature.
Flash point: 67C.
Auto-ignition temperature: 375C
Solubility: Soluble in water. Miscible with alcohol and ether.
We manufacture and supply as under:
Methyl 3-oxo-2-phenylpropanoate
Para Hydroxy Phenyl Acetic Acid Methyl Ester.
Manufacturers:
MUBY CHEMICALS
Ambernath Mumbai, Ankleshwar Gujarat, India
TEL: (OFFICE) +912223770100, +912223726950
Current Date Time in India GMT+5:30
e-mail: info@mubychem.com
USA, Canada, Mexico and other American
neighbouring buyers may
e-mail: us@mubychem.com
Call toll-free 1-877-682-9243 (1-877-MUBYCHEM)
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4 December, 2024
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Methyl Acetoacetate or 3-Oxobutanoic acid methyl ester or Acetoacetic acid methyl ester or MAA SDS GHS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 04-Nov-20
1. PRODUCT AND COMPANY IDENTIFICATION
Product Name & Other Names: Methyl Acetoacetate or 3-Oxobutanoic acid methyl ester or Acetoacetic acid methyl ester or MAA.
CAS Number: 105-45-3
EINECS Number: 203-299-8
Molecular Weight: 116.12
Molecular Formula: C5H8O3 or CH3COCH2COOCH3
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead above.
2. HAZARDS IDENTIFICATION
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Serious eye damage/eye irritation Category 2A, H319
Flammable liquids Category 4, H227
Labeling according to GHS & Regulation (EC) No 1272/2008
GHS Label Elements  Irritant |
Signal Words: Warning
Hazard Statements:
H319 Causes serious eye irritation.
H227 Combustible liquid.
Precautionary Statements:
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink, or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P302+352: IF ON SKIN: Wash with soap and water.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.
CLASSIFICATION ACCORDING TO Directive 67/548/EEC or Directive 1999/45/EC:
Hazard Symbol:
Xi; Irritant
Risk Phrases:
R36: Irritating to eyes.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Product Name & Other Names: Methyl Acetoacetate or 3-Oxobutanoic acid methyl ester or Acetoacetic acid methyl ester or MAA.
CAS Number: 105-45-3
EINECS Number: 203-299-8
4. FIRST-AID MEASURES
Always seek medical attention after first aid measures are provided.
Eye Contact: Rinse immediately with plenty of water for 10 minutes at least. Contact a physician if symptoms persist.
Skin Contact: Wash thoroughly with soap and water; flush with plenty of water. Take off spoilt clothes. Contact physician if symptoms persist.
Ingestion: Wash the mouth with water; seek medical advice immediately.
Inhalation: Remove from exposure site to fresh air and keep at rest. Obtain medical advice.
5. FIRE-FIGHTING MEASURES
Extinguishing Media Recommended: CO2, foam, dry chemicals.
Non-Recommended: Do not use direct water jet on burning material.
Extinguishing Procedures: Closed containers may build up pressure at elevated temperatures. If possible, containers should be cooled with a water spray.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material. Prevent any contact with hot surfaces.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep up and remove to an approved disposal container. Avoid open flames or other sources of ignition.
7. HANDLING AND STORAGE
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong acids, alkali, oxidizing agents and reducing agents. Keep air contact to a minimum. Keep away from ignition sources and naked flame.
8. EXPOSURE CONTROL
Exposure Guidelines: This product does not contain any hazardous materials with occupational exposure limits established by the region-specific regulatory bodies.
Respiratory Protection: Avoid to breath directly on the product. Apply local ventilations when appropriate.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Colorless liquid.
Odor: Agreeable odor.
Odor threshold: Not available.
pH: around 4 for 863 g/l in water @ 20C.
Relative density: around 1.08
Melting point/freezing point: -80C literature.
Initial boiling point and boiling range: 169C to 171C literature.
Flash Point (C): 67C (lowest reported).
Auto-ignition temperature: 375C.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility(ies): Soluble in water. Miscible with alcohol and ether.
Viscosity: Not available.
Molecular Weight: 116.12
Molecular Formula: C5H8O3 or CH3COCH2COOCH3
10. STABILITY AND REACTIVITY
Reactivity: It presents no significant reactivity hazards, by itself or in contact with water. Avoid contact with strong acids, alkali, oxidizing agents and reducing agents. Avoid Heat, flames, and sparks.
Decomposition: Carbon monoxide and unidentified organic compounds may be formed during combustion.
11. TOXICOLOGICAL INFORMATION
LD 50 ORAL/RAT (mg/Kg) 2800.
LD 50 DERMAL/RABBIT (ml/Kg) 10.
Carcinogenicity: This product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC, NTP, ACGIH & OSHA.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.
12. ECOLOGICAL INFORMATION
Toxicity to fish: LC50 (Pimephales promelas (fathead minnow)): 111.4 mg/l.
Toxicity to daphnia and other aquatic invertebrates: EC50 (Daphnia magna (Water flea)): 100 mg/l, 48 h
Persistence and Degradability: No information available. Persistence is not expected.
Mobility: No information available. However, likely to be mobile due to water solubility.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.
13. DISPOSAL CONSIDERATIONS
In accordance with local environmental laws. Avoid disposing into drainage systems and into the environment.
14. TRANSPORT REGULATIONS
DOT USA, TDG Canada & ADR/RID Europe: Not dangerous goods.
IMDG/IMO & IATA: Not dangerous goods.
15. REGULATORY INFORMATION
USA:
SARA 302: Not subject to the reporting requirements of SARA Title III, Section 302.
SARA 311/312 Hazards: Immediate health hazard. Fire hazard. See section 2.
California Prop. 65 Components: Not present or none in reportable amounts for occupational exposure as per OSHA's approval of the California Hazard Communication Standard.
Section 16 - Additional Information
European Labeling in Accordance with EC Directives:
H319 = Causes serious eye irritation.
H226 = Flammable liquid and vapor.
Hazard Symbol:
Xi; Irritant
Risk Phrases:
R36: Irritating to eyes.
Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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